The pathway of carbon dioxide assimilation in rhodospirillum rubrum grown in turbidostat continuous-flow culture

1973 ◽  
Vol 92 (3) ◽  
pp. 235-244 ◽  
Author(s):  
J. Howard Slater ◽  
Ian Morris
1941 ◽  
Vol 139 (1) ◽  
pp. 365-376 ◽  
Author(s):  
H.G. Wood ◽  
C.H. Werkman ◽  
Allan Hemingway ◽  
A.O. Nier

1990 ◽  
Vol 82 (3) ◽  
pp. 451-459 ◽  
Author(s):  
H. F. Schnier ◽  
M. Dingkuhn ◽  
S. K. De Datta ◽  
K. Mengel ◽  
E. Wijangco ◽  
...  

2013 ◽  
Vol 9 ◽  
pp. 2886-2897 ◽  
Author(s):  
Phei Li Lau ◽  
Ray W K Allen ◽  
Peter Styring

The palladium metal catalysed Heck reaction of 4-iodoanisole with styrene or methyl acrylate has been studied in a continuous plug flow reactor (PFR) using supercritical carbon dioxide (scCO2) as the solvent, with THF and methanol as modifiers. The catalyst was 2% palladium on silica and the base was diisopropylethylamine due to its solubility in the reaction solvent. No phosphine co-catalysts were used so the work-up procedure was simplified and the green credentials of the reaction were enhanced. The reactions were studied as a function of temperature, pressure and flow rate and in the case of the reaction with styrene compared against a standard, stirred autoclave reaction. Conversion was determined and, in the case of the reaction with styrene, the isomeric product distribution was monitored by GC. In the case of the reaction with methyl acrylate the reactor was scaled from a 1.0 mm to 3.9 mm internal diameter and the conversion and turnover frequency determined. The results show that the Heck reaction can be effectively performed in scCO2 under continuous flow conditions with a palladium metal, phosphine-free catalyst, but care must be taken when selecting the reaction temperature in order to ensure the appropriate isomer distribution is achieved. Higher reaction temperatures were found to enhance formation of the branched terminal alkene isomer as opposed to the linear trans-isomer.


ChemInform ◽  
2009 ◽  
Vol 40 (8) ◽  
Author(s):  
Jin-Kyun Lee ◽  
Matthew J. Fuchter ◽  
Rachel M. Williamson ◽  
Gary A. Leeke ◽  
Edward J. Bush ◽  
...  

1997 ◽  
Vol 122 (6) ◽  
pp. 837-840 ◽  
Author(s):  
Matej Stopar ◽  
Brent L. Black ◽  
Martin J. Bukovac

The effects of NAA, BA, or Accel on CO2 assimilation of shoot leaves of mature bearing Redchief `Delicious' and `Empire' apple (Malus ×domestica Borkh.) trees were evaluated over two seasons. BA at 50 mg·L-1 did not significantly affect any of the gas-exchange parameters measured. NAA (15 mg·L-1) consistently suppressed CO2 assimilation rate (from ≈10% to 24% below that of the control). This suppression was NAA-concentration dependent, continued for >15 days after treatment, and was completely overcome in `Empire', but only partially or not at all in `Delicious' when BA was combined with NAA. These results are discussed in relation to fruit thinning and NAA-induced inhibition of fruit growth in spur-type `Delicious'. Chemical names used: 2-(1-napthyl) acetic acid (NAA); N-(phenyl)-1H-purine-6-amine (BA); BA + gibberellin A (GA)4+7 (Accel).


Sign in / Sign up

Export Citation Format

Share Document