Phase relationships of sursassite and other Mn-silicates in highly oxidized low-grade, high-pressure metamorphic rocks from Evvia and Andros islands, Greece

1986 ◽  
Vol 94 (1) ◽  
pp. 110-126 ◽  
Author(s):  
Thomas Reinecke
Keyword(s):  
High Pressure ◽  
Metamorphic Rocks ◽  
Low Grade ◽  
Phase Relationships

Deformational geometry and tectonic significance of a portion of the Chilliwack Group, northwestern Cascades, Washington

1988 ◽  
Vol 25 (3) ◽  
pp. 433-441 ◽  
Author(s):  
Moira Smith
Keyword(s):  
High Pressure ◽  
Volcanic Rocks ◽  
Ductile Deformation ◽  
Metamorphic Rocks ◽  
Low Grade ◽  
North Cascades ◽  
Clastic Rocks ◽  
Tectonic Significance ◽  
Group A ◽  
Event Based

The northwestern Cascades structural province can be interpreted as an accretionary complex comprising fault-bounded blocks of pre-Tertiary metamorphic rocks of diverse age and lithologic type. This paper documents the deformation in a portion of the Chilliwack Group, a unit in this complex. The Chilliwack Group is a thick sequence of volcaniclastic sedimentary rocks, calc-alkaline volcanic rocks, and limestone that is metamorphosed to low-grade blueschist facies. The rocks underwent ductile deformation during a Late Cretaceous orogenic event, producing a subhorizontal foliation and, in appropriate lithologies, subhorizontal stretching lineations that trend N20°W. Finite strain sustained by coarse clastic rocks produced RXZ values averaging 3.5. The deformation at least partially postdates the high pressure metamorphic event, based on the presence of bent and broken high-pressure mineral grains. Although early studies postulated west-vergent thrust imbrication of units in the northwest Cascades, the N20°W direction of apparent elongation in the Chilliwack Group, consistent with the direction of motion along segments of the Shuksan fault elucidated in other more recent studies, may reflect significant, highly oblique components of convergence during formation of the western North Cascades collisional orogen.

Two contrasting mineral assemblages in the Meliata blueschists, Western Carpathians, Slovakia

1999 ◽  
Vol 63 (4) ◽  
pp. 489-501 ◽  
Author(s):  
S. W. Faryad ◽  
G. Hoinkes
Keyword(s):  
High Pressure ◽  
Low Pressure ◽  
Greenschist Facies ◽  
Western Carpathians ◽  
Metamorphic Rocks ◽  
Low Grade ◽  
Mineral Assemblages ◽  
Compositional Variations ◽  
Si Content ◽  
End Members

AbstractLow-grade metamorphic rocks from the Meliata unit (Western Carpathians) are characterized by the presence of typical blueschist-facies minerals. In metabasalt, an early low-pressure assemblage (<0.5 GPa at 350°C characterized by muscovite and zoisite, is followed by high-pressure glaucophane, phengite, Na-pyroxene, chlorite, clinozoisite and Al-poor titanite, indicating pressures of >1.2 GPa at 450°C Na-pyroxene shows strong compositional variations between the end-members Jd4–70, Aeg10–49 and Q17–49, respectively. Phengite has high Si content of 3.5 a.p.f.u. The zoisite with Al2Fe (100[Fetot/(−2+Altot+Fetot)]) = 3–5%, is rimmed by clinozoisite, with a maximum of 75% Al2Fe, as well as being enclosed by glaucophane. The occurrence of clinozoisite, rimming zoisite, suggests that the transformation of orthorhombic to monoclinic epidote depends not only on the temperature but also on the pressure. In the studied metabasalt, retrograde phases reflecting greenschist-facies conditions are albite and chlorite. Some neighbouring metabasites may additionally contain actinolite and biotite.

Experimental Studies on Metamorphism of Crustal Rocks Under Mantle Pressures

1988 ◽  
Vol 52 (364) ◽  
pp. 1-26 ◽  
Author(s):  
Werner Schreyer
Keyword(s):  
High Pressure ◽  
Water Pressure ◽  
Experimental Studies ◽  
Temperature Stability ◽  
Model Systems ◽  
Metamorphic Rocks ◽  
Stability Field ◽  
Low Grade ◽  
Subsequent Increase ◽  
Crustal Rocks

AbstractMetamorphic rocks of undoubted crustal origin have been described in recent years, principally from Mediterranean collision zones that have been subjected to PT conditions along very low geothermal gradients (∼ 7°C/km) and have reached pressures up to 30 kbar. MgAl-rich metapelites develop particularly diagnostic high-pressure minerals and mineral assemblages that have been and are being studied experimentally in model systems involving the components K2O, MgO, Al2O3, TiO2, SiO2, P2O5, and H2O up to pressures of 50 kbar and temperatures of 1000°C.In the present review the following synthetic phases and phase assemblages are discussed, emphasizing their water-pressure-temperature stability fields (approximated in parentheses here), their reaction relationships, and their known or potential occurrences in metamorphic rocks. Sudoite (0 to ∼ 12 kbar, 150? to 380°C) occurs in very low-grade metapelites. Mg-carpholite (∼ 7 to ∼ 45 kbar, ∼ 200 to 600°C) is found in subducted metabauxites, metapelites, and related quartz veins. Mg-chloritoid (18 to 45 kbar?; 400 to 760°C) has not been found in nature as pure or nearly pure end-member; it requires silica-deficient environments. Yoderite, known in nature only from a single talc-kyanite schist occurrence, has only a small stability field (9 to 18 kbar?, 700 to 870°C?), cannot coexist with quartz, but may be stabilized by Fe3+. Pyrope (∼ 15 to at least 50 kbar, ∼ 700°C to melting), with or without relic coesite inclusions, occurs spectacularly in quartzites. Mg-staurolite (∼ 14 to some 90 kbar?, 700 to 1000°C), recently discovered as inclusions in pyrope, requires silica-deficiency. MgMgAl-pumpellyite is a new synthetic phase in which Mg totally replaces Ca of normal pumpellyite; because of its very high-pressure, low-temperature stability (∼ 37 to at least 55 kbar, < 400 to 780°C) it may not form within our globe. Ellenbergerite, the new high-pressure mineral forming inclusions in pyrope, apparently exhibits a rather composition-dependent stability with Ti-ellenbergerite, requiring higher pressures (> 20 kbar) than P-bearing, Ti-free members; a pure hydrous Mg-phosphate with ellenbergerite structure was synthesized at 10 kbar. Phengites, the widespread MgSi-substituted muscovites, require increasingly high water pressures (up to ∼ 20 kbar) for higher degrees of substitution, but the Al-celadonite end-member is not stable under any conditions; the compositions of phengites coexisting with limiting assemblages such as phlogopite, K-feldspar, and an SiO2 phase are useful geobarometers. The common assemblage Mg-chlorite + Al2SiO5 (mainly kyanite) has an extensive stability field ranging from near zero to 31 kbar at temperatures varying from some 320 to ∼ 760°C depending on pressure. The whiteschist assemblage talc + kyanite (6 to ∼ 45 kbar, 550 to 810°C) plays an important role in collision zone metamorphism as it forms from the greenschist assemblage chlorite + quartz at low grades but is also known to break down into pyrope + coesite at the highest grade observed thus far. The assemblage talc-phengite (11 to at least 35 kbar, 300? to 820°C depending on pressure), on the other hand, is well known from subducted metapelites. At pressures of 15–20 kbar and temperatures of 400–650°C a very K,Mg-rich, siliceous fluid forms as a consequence of the mutual reaction of the minerals K-feldspar and phlogopite (biotite) which are very common in crustal rocks including granites. Such fluids are bound to cause metasomatism in neighbouring mantle rocks which, upon subsequent increase of temperature, produce post-collisional ultrapotassic, lamproitic melts.

TEM/AEM characterization of fine-grained clay minerals in very-low-grade rocks: Evaluation of contamination by empa involving celadonite family minerals

1996 ◽  
Vol 54 ◽  
pp. 694-695
Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi
Keyword(s):  
Electron Microscopy ◽  
Volcanic Rocks ◽  
Analytical Electron Microscopy ◽  
Metamorphic Rocks ◽  
New Mineral ◽  
Chemical Compositions ◽  
Low Grade ◽  
Fine Grained ◽  
Depth Analysis ◽  
Mineral Aggregates

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.

The thermometric significance of magnetite in low grade metamorphic rocks

1964 ◽  
Vol 262 (7) ◽  
pp. 904-917 ◽  
Author(s):  
M. I. Abdullah ◽  
M. P. Atherton
Keyword(s):  
Metamorphic Rocks ◽  
Low Grade
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