Molecular orbital (SCF-X?-SW) theory of metal-metal charge transfer processes in minerals

1987 ◽  
Vol 14 (4) ◽  
pp. 355-363 ◽  
Author(s):  
David M. Sherman
Keyword(s):  
Charge Transfer ◽  
Molecular Orbital ◽  
Metal Charge ◽  
Transfer Processes ◽  
Metal Metal ◽  
Metal Charge Transfer

Metal–metal charge transfer and solvatochromism in cyanomanganese carbonyl complexes of ruthenium and osmium

2006 ◽  
pp. 3584-3596 ◽  
Author(s):  
Christopher J. Adams ◽  
Neil G. Connelly ◽  
Nicholas J. Goodwin ◽  
Owen D. Hayward ◽  
A. Guy Orpen ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Carbonyl Complexes ◽  
Metal Charge ◽  
Metal Metal ◽  
Metal Charge Transfer

scholarly journals Photoredox Reactions of Hg(CN)2/[Fe(CN)6]4- and [HgCo2(CN)10]6- Induced by Inner-Sphere Metal to Metal Charge Transfer Excitation

1989 ◽  
Vol 44 (2) ◽  
pp. 145-148 ◽  
Author(s):  
H. Kunkely ◽  
G. Stochel ◽  
A. Vogler
Keyword(s):  
Charge Transfer ◽  
Aqueous Mixtures ◽  
Strongly Coupled ◽  
Metal Charge ◽  
Weakly Coupled ◽  
Metal Metal ◽  
Inner Sphere ◽  
Charge Transfer Excitation ◽  
Metal Bonds ◽  
Metal Charge Transfer

Abstract Incomplexes of the type [(NC)2HgIIN CFeII(CN)5]4- which are formed in aqueous mixtures of Hg(CN)2 and [Fe(CN)6]4- both metals are weakly coupled. Optical metal to metal charge transfer (MMCT) excitation from FeII to HgIIleads to the reduction of HgII to Hg0 an the oxidation of [Fe(CN)6]4- to [Fe(CN)6]3-. In the complex [(NC)5CoI-HgII-CoI(CN)5]6- the m etals are strongly coupled by direct but polar metal metal bonds. MMCT (CoI ￫ HgII) excitation induces the photoredox reaction: [HgCo2(CN)10]6-￫Hg0 + 2[Co(CN)5]3-.

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