Viscometric studies: Interpolymer complex formation between poly(styrene-b-ethylene oxide) block copolymers and poly(acrylic acid)

1982 ◽  
Vol 7 (8) ◽  
Author(s):  
SarojKumar Chatterjee ◽  
G�rard Riess
Keyword(s):  
Block Copolymers ◽  
Complex Formation ◽  
Acrylic Acid ◽  
Ethylene Oxide ◽  
Interpolymer Complex ◽  
Poly Acrylic Acid

Nanosized Amorphous Calcium Carbonate Stabilized by Poly(ethylene oxide)-b-poly(acrylic acid) Block Copolymers

Langmuir ◽  
2006 ◽  
Vol 22 (4) ◽  
pp. 1875-1879 ◽  
Author(s):  
Baptiste Guillemet ◽  
Michael Faatz ◽  
Franziska Gröhn ◽  
Gerhard Wegner ◽  
Yves Gnanou
Keyword(s):  
Calcium Carbonate ◽  
Block Copolymers ◽  
Acrylic Acid ◽  
Ethylene Oxide ◽  
Amorphous Calcium Carbonate ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Poly Acrylic Acid

pH Effects in the Complex Formation and Blending of Poly(acrylic acid) with Poly(ethylene oxide)

Langmuir ◽  
2004 ◽  
Vol 20 (9) ◽  
pp. 3785-3790 ◽  
Author(s):  
Vitaliy V. Khutoryanskiy ◽  
Artem V. Dubolazov ◽  
Zauresh S. Nurkeeva ◽  
Grigoriy A. Mun
Keyword(s):  
Complex Formation ◽  
Acrylic Acid ◽  
Ethylene Oxide ◽  
Ph Effects ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Poly Acrylic Acid

scholarly journals Thermo-Responsive Behavior of Mixed Aqueous Solution of Hydrophilic Polymer with Pendant Phosphorylcholine Group and Poly(Acrylic Acid)

Polymers ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 148
Author(s):  
Hirokazu Fukumoto ◽  
Kazuhiko Ishihara ◽  
Shin-Ichi Yusa
Keyword(s):  
Aqueous Solution ◽  
Acrylic Acid ◽  
Solution Temperature ◽  
Interpolymer Complex ◽  
Mixed Aqueous Solution ◽  
Upper Critical Solution Temperature ◽  
Acidic Conditions ◽  
Decreasing Ph ◽  
Increasing Temperature ◽  
Poly Acrylic Acid

A mixed aqueous solution of hydrophilic poly(2-methacryloyloxyethyl phosphorylcholine) (PMPC) and poly(acrylic acid) (PAAc) becomes cloudy under acidic conditions at room temperature. The pendant carboxylic acid groups in PAAc form hydrogen bonds with the ester and phosphate groups in PMPC. While the polymers aggregate under acidic conditions, neither one associate under basic conditions because of the deprotonation of the pendant carboxy groups in PAAc. We observed that the interpolymer complex formed from PMPC, and PAAc was dissociated in aqueous solutions with increasing temperature, which is an upper critical solution temperature behavior. With increasing temperature, the molecular motion increased to dissociate the interpolymer complex. The phase transition temperature increased with increasing polymer and salt concentrations, and with decreasing pH.

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