The kinetics of the ester-interchange reaction of poly(ethylene terephthalate)

1981 ◽  
Vol 4 (4) ◽  
Author(s):  
Michael Dr�scher ◽  
Friedrich Georg Schmidt
Keyword(s):  
Ethylene Terephthalate ◽  
Ester Interchange ◽  
Poly Ethylene Terephthalate ◽  
Interchange Reaction ◽  
Poly Ethylene ◽  
Kinetics Of

Ethylene Glycol and Glycerin as the Solvent for Alkaline Treatment of Poly(ethylene Terephthalate) Fabrics

1997 ◽  
Vol 67 (10) ◽  
pp. 760-766 ◽  
Author(s):  
M.-C. Yang ◽  
H.-Y. Tsai
Keyword(s):  
Ethylene Glycol ◽  
Degradation Rate ◽  
Ethylene Terephthalate ◽  
Treatment Time ◽  
Alkaline Treatment ◽  
Aqueous System ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene ◽  
Kinetics Of ◽  
Scanning Electron

Poly(ethylene terephthalate) fabrics are treated with sodium hydroxide using ethylene glycol or glycerin as the solvent. Compared with conventional aqueous alkaline hydrolysis, the degradation rate in ethylene glycol increases tenfold. The kinetics of the alkaline-ethylene glycol treatment show that the weight loss is linear with respect to time. The moisture regain rate and tensile properties of the treated fabrics are measured; other tests include scanning electron microscopy and dyeing properties. The results show that the properties of the treated fabrics do not depend significantly on the solvent; therefore, using ethylene glycol can greatly shorten the treatment time to achieve results similar to those with the conventional aqueous system.

Kinetics of Mass Transfer in the Melt Polycondensation of Poly(Ethylene Terephthalate)

1985 ◽  
Vol 22 (10) ◽  
pp. 1413-1427 ◽  
Author(s):  
Gerald Rafler ◽  
Gerhard Reinisch ◽  
Eckhard Bonatz ◽  
Heinz Versaumer ◽  
Herbert Gajewski ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Ethylene Terephthalate ◽  
Melt Polycondensation ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene ◽  
Kinetics Of
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