F-11 AND N2O in the North American troposphere and lower stratosphere

1978 ◽  
Vol 10 (4) ◽  
Author(s):  
W.D. Saunders ◽  
E. Robinson ◽  
D.R. Cronn ◽  
R.A. Ramussen ◽  
D. Pierotti
2021 ◽  
Author(s):  
Valentin Lauther ◽  
Bärbel Vogel ◽  
Johannes Wintel ◽  
Andrea Rau ◽  
Peter Hoor ◽  
...  

Abstract. Efficient transport pathways for ozone depleting very short-lived substances (VSLS) from their source regions into the stratosphere are a matter of current scientific debate, however they have yet to be fully identified on an observational basis. Understanding the increasing impact of chlorine containing VSLS (Cl-VSLS) on stratospheric ozone depletion is important in order to validate and improve model simulations and future predictions. We report on the first transport study using airborne in situ measurements of the Cl-VSLS dichloromethane (CH2Cl2) and trichloromethane (chloroform, CHCl3) to derive a detailed description of the two most efficient and fast transport pathways from (sub-)tropical source regions into the extratropical lower stratosphere (Ex-LS) in northern hemisphere (NH) late summer. The Cl-VSLS measurements were obtained in the upper troposphere and lower stratosphere (UTLS) above Western Europe and the mid latitude Atlantic Ocean in the frame of the WISE (Wave-driven ISentropic Exchange) aircraft campaign in autumn 2017 and are combined with the results from a three-dimensional simulation of a Lagrangian transport model as well as back-trajectory calculations. Compared to background measurements of similar age we find up to 150 % enhanced CH2Cl2 and up to 100 % enhanced CHCl3 mixing ratios in the Ex-LS. We link the measurements of enhanced mixing ratios to emissions in the region of southern and eastern Asia. Transport from this area to the Ex-LS at potential temperatures in the range of 370–400 K takes about 5–10 weeks via the Asian summer monsoon anticyclone (ASMA). Our measurements suggest anthropogenic sources to be the cause of these strongly elevated Cl-VSLS concentrations observed at the top of the lowermost stratosphere (LMS). A faster transport pathway into the Ex-LS is derived from particularly low CH2Cl2 and CHCl3 mixing ratios in the UTLS. These low mixing ratios reflect weak emission sources and a local seasonal minimum of both species in the boundary layer of Central America and the tropical Atlantic. We show that air masses uplifted by hurricanes, the North American monsoon, and general convection above Central America into the tropical tropopause layer to potential temperatures of about 360–370 K are transported isentropically within 1–5 weeks into the Ex-LS. This transport pathway linked to the North American monsoon mainly impacts the middle and lower part of the LMS with particularly low CH2Cl2 and CHCl3 mixing ratios. In a case study, we specifically analyze air samples directly linked to the uplift by the category 5 hurricane Maria that occurred during October 2017 above the Atlantic Ocean. Regionally differing CHCl3 : CH2Cl2 emission ratios derived from our UTLS measurements suggest a clear similarity between CHCl3 and CH2Cl2 when emitted by anthropogenic sources and differences between the two species mainly caused by additional, likely biogenic, CHCl3 sources. Overall, the transport of strongly enhanced CH2Cl2 and CHCl3 mixing ratios from southern and eastern Asia via the ASMA is the main factor for increasing the chlorine loading from the analyzed VSLS in the Ex-LS during NH late summer. Thus, further increases in Asian CH2Cl2 and CHCl3 emissions, as frequently reported in recent years, will further increase the impact of Cl-VSLS on stratospheric ozone depletion.


Author(s):  
Kai-Wei Chang ◽  
Kenneth P. Bowman ◽  
Leong Wai Siu ◽  
Anita D. Rapp

AbstractIn the upper troposphere and lower stratosphere (UTLS), large-scale anticyclones associated with monsoons play major roles in tropospheric and stratospheric transport and mixing. To understand the forcing of the North American Monsoon Anticyclone (NAMA), this study examines the connection between precipitation over the tropics and subtropics of the North American longitude sector and the variability of the troposphere and lower stratosphere. Using ERA5 reanalysis and outgoing longwave radiation (OLR) data from 1979 to 2019, we assess the relationship at the intraseasonal time scale using pentad-mean time series. We show that OLR anomalies are correlated with circulation anomalies northwest and northeast of the region of precipitation. Decreased OLR (increased precipitation) corresponds to increased geopotential heights and anticyclonic circulation anomalies in the 300 – 100 hPa layer and an opposite response in the lower tropospheric 850 – 600 hPa layer. The results are consistent with the established theory of the Rossby wave response to latent heating. The increase in height, which is strongest near 150 hPa, indicates that increased precipitation is associated with a strengthened NAMA. UTLS temperatures also have significant correlations with OLR, with cold (warm) anomalies occurring above (below) the core of the anticyclonic anomaly consistent with large-scale balance. The vertical structure of geopotential and temperature anomalies is compared to simulations using an idealized general circulation model, which shows that such a vertical structure is a consistent response to diabatic heating. Correlations at the interannual time scale resemble those at the intraseasonal time scale, demonstrating that precipitation is related to the NAMA at both time scales.


2006 ◽  
Vol 175 (4S) ◽  
pp. 511-512
Author(s):  
David G. McLeod ◽  
Ira Klimberg ◽  
Donald Gleason ◽  
Gerald Chodak ◽  
Thomas Morris ◽  
...  

2013 ◽  
Vol 74 (S 01) ◽  
Author(s):  
Pete Batra ◽  
Jivianne Lee ◽  
Samuel Barnett ◽  
Brent Senior ◽  
Michael Setzen ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document