A wall jet electrode reactor and its application to the study of electrode reaction mechanisms Part II: A general computational method for the mass transport problems involved

1995 ◽  
Vol 25 (11) ◽  
Author(s):  
P. Laevers ◽  
A. Hubin ◽  
H. Terryn ◽  
J. Vereecken
Keyword(s):  
Mass Transport ◽  
Reaction Mechanisms ◽  
Electrode Reaction ◽  
Computational Method ◽  
Wall Jet ◽  
Transport Problems

The wall-jet electrode and the study of electrode reaction mechanisms: the EC reaction

1990 ◽  
Vol 20 (6) ◽  
pp. 912-915 ◽  
Author(s):  
R. G. Compton ◽  
A. C. Fisher ◽  
G. P. Tyley
Keyword(s):  
Reaction Mechanisms ◽  
Electrode Reaction ◽  
Wall Jet

Automatically Identifying Electrode Reaction Mechanisms Using Deep Neural Networks

2019 ◽  
Vol 91 (19) ◽  
pp. 12220-12227 ◽  
Author(s):  
Gareth F. Kennedy ◽  
Jie Zhang ◽  
Alan M. Bond
Keyword(s):  
Neural Networks ◽  
Reaction Mechanisms ◽  
Deep Neural Networks ◽  
Electrode Reaction

Rotating disc electrodes: the theory of chronoamperometry and its use in mechanistic investigations

1988 ◽  
Vol 418 (1854) ◽  
pp. 113-154 ◽  
Keyword(s):  
Diffusion Coefficients ◽  
Reaction Mechanisms ◽  
Electrode Reaction ◽  
Rotating Disc ◽  
Potential Step ◽  
Wide Range ◽  
Mechanistic Investigations ◽  
Disc Electrodes ◽  
Theoretical Results ◽  
Computational Strategy

A general computational strategy is presented for the calculation of the chronoamperometric responses arising from potential-step experiments at rotating disc electrodes. The method is applicable to a wide range of electrode reaction mechanisms and theoretical results are given for single- and double-potential-step experiments for ECE, DISP1, DISP2, EC' and CE reactions. For the last, the treatment is extended to cover the case where reactants have grossly unequal diffusion coefficients. Steadystate behaviour is also deduced. The extent to which the various mechanistic pathways can be distinguished is identified and the necessary experiments defined.

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