Model studies of the impact of chemical inhomogeneity on SO2 oxidation in warm stratiform clouds

1991 ◽  
Vol 13 (2) ◽  
pp. 109-129 ◽  
Author(s):  
Xing Lin ◽  
William L. Chameides
Author(s):  
Slawomir Blasiak

Noncontacting mechanical seals with various kinds of face surface modifications have established their position in the sealing technique. Over the last few years, a lot of works dedicated to the impact of various surface modifications on the dynamics of working rings have been created. This paper presents model studies regarding relatively unknown noncontacting impulse gas face seals. Here, a mathematical model of impulse gas face seals is developed including the nonlinear Reynolds equation and stator dynamics equations, which were solved simultaneously using numerical methods. An original computer software written in C + + language was developed. A number of numerical tests were conducted and the phenomena occurring in the radial gap during seal operation were analyzed. Final conclusions were drawn and several features were indicated characterizing impulse face seals. It should be emphasized that numerical research on this type of seals has not been published yet. The literature usually presents simplified models for the noncompressible medium, which can be solved with the use of analytical methods.


2016 ◽  
Author(s):  
Johannes Bieser ◽  
Franz Slemr ◽  
Jesse Ambrose ◽  
Carl Brenninkmeijer ◽  
Steve Brooks ◽  
...  

Abstract. Atmospheric chemistry and transport of mercury play a key role in the global mercury cycle. However, there are still considerable knowledge gaps concerning the fate of mercury in the atmosphere. This is the second part of a model inter-comparison study investigating the impact of atmospheric chemistry and emissions on mercury in the atmosphere. While the first study focused on ground based observations of mercury concentration and deposition, here we investigate the vertical distribution and speciation of mercury from the planetary boundary layer to the lower stratosphere. So far, there have been few model studies investigating the vertical distribution of mercury, mostly focusing on single aircraft campaigns. Here, we present a first comprehensive analysis based on various aircraft observations in Europe, North America, and on inter-continental flights. The investigated models proved to be able to reproduce the distribution of total and elemental mercury concentrations in the troposphere including inter-hemispheric trends. One key aspect of the study is the investigation of mercury oxidation in the troposphere. We found that different chemistry schemes were better at reproducing observed oxidized mercury (RM) patterns depending on altitude. High RM concentrations in the upper troposphere could be reproduced with oxidation by bromine while elevated concentrations in the lower troposphere were better reproduced by OH and ozone chemistry. However, the results were not always conclusive as the physical and chemical parametrizations in the chemistry transport models also proved to have a substantial impact on model results.


2017 ◽  
Author(s):  
Petros Vasilakos ◽  
Yong-Ηa Kim ◽  
Jeffrey R. Pierce ◽  
Sotira Yiacoumi ◽  
Costas Tsouris ◽  
...  

Abstract. Radioactive charging can significantly impact the way radioactive aerosols behave, and as a result their lifetime, but such effects are neglected in predictive model studies of radioactive plumes. The objective of this work is to determine the influence of radioactive charging on the vertical transport of radioactive aerosols in the atmosphere, through its effect on coagulation and deposition, as well as quantifying the impact of this charging on aerosol lifetime. The TwO-Moment Aerosol Sectional (TOMAS) microphysical model was extended to account for radioactive charging effects on coagulation in a computationally efficient way. The expanded model, TOMAS-RC (TOMAS with Radioactive Charging effects), was then used to simulate the microphysical evolution and deposition of radioactive aerosol (containing the isotopes 131I and 137Cs) in a number of idealized atmospheric transport experiments. Results indicate that radioactive charging can facilitate or suppress coagulation of radioactive aerosols, thus influencing the deposition patterns and total amount of radioactive aerosol mass available for long-range transport. Sensitivity simulations to uncertain parameters affirm the potential importance of radioactive charging effects. An important finding is that charging of neutral, coarse mode aerosol from background radiation can reduce coagulation rates and extend its lifetime in the atmosphere by up to a factor of 2.


2021 ◽  
Vol 21 (23) ◽  
pp. 17267-17289
Author(s):  
Mattia Righi ◽  
Johannes Hendricks ◽  
Christof Gerhard Beer

Abstract. A global aerosol–climate model, including a two-moment cloud microphysical scheme and a parametrization for aerosol-induced ice formation in cirrus clouds, is applied in order to quantify the impact of aviation soot on natural cirrus clouds. Several sensitivity experiments are performed to assess the uncertainties in this effect related to (i) the assumptions on the ice nucleation abilities of aviation soot, (ii) the representation of vertical updrafts in the model, and (iii) the use of reanalysis data to relax the model dynamics (the so-called nudging technique). Based on the results of the model simulations, a radiative forcing from the aviation soot–cirrus effect in the range of −35 to 13 mW m−2 is quantified, depending on the assumed critical saturation ratio for ice nucleation and active fraction of aviation soot but with a confidence level below 95 % in several cases. Simple idealized experiments with prescribed vertical velocities further show that the uncertainties on this aspect of the model dynamics are critical for the investigated effect and could potentially add a factor of about 2 of further uncertainty to the model estimates of the resulting radiative forcing. The use of the nudging technique to relax model dynamics is proved essential in order to identify a statistically significant signal from the model internal variability, while simulations performed in free-running mode and with prescribed sea-surface temperatures and sea-ice concentrations are shown to be unable to provide robust estimates of the investigated effect. A comparison with analogous model studies on the aviation soot–cirrus effect show a very large model diversity, with a conspicuous lack of consensus across the various estimates, which points to the need for more in-depth analyses on the roots of such discrepancies.


2015 ◽  
Vol 54 (9) ◽  
pp. 1944-1969 ◽  
Author(s):  
Xiaoqin Jing ◽  
Bart Geerts ◽  
Katja Friedrich ◽  
Binod Pokharel

AbstractThe impact of ground-based glaciogenic seeding on wintertime orographic, mostly stratiform clouds is analyzed by means of data from an X-band dual-polarization radar, the Doppler-on-Wheels (DOW) radar, positioned on a mountain pass. This study focuses on six intensive observation periods (IOPs) during the 2012 AgI Seeding Cloud Impact Investigation (ASCII) project in Wyoming. In all six storms, the bulk upstream Froude number below mountaintop exceeded 1 (suggesting unblocked flow), the clouds were relatively shallow (with bases below freezing), some liquid water was present, and orographic flow conditions were mostly steady. To examine the silver iodide (AgI) seeding effect, three study areas are defined (a control area, a target area upwind of the crest, and a lee target area), and comparisons are made between measurements from a treated period and those from an untreated period. Changes in reflectivity and differential reflectivity observed by the DOW at low levels during seeding are consistent with enhanced snow growth, by vapor diffusion and/or aggregation, for a case study and for the composite analysis of all six IOPs, especially at close range upwind of the mountain crest. These low-level changes may have been affected by natural changes aloft, however, as evident from differences in the evolution of the echo-top height in the control and target areas. Even though precipitation in the target region is strongly correlated with that in the control region, the authors cannot definitively attribute the change to seeding because there is a lack of knowledge about natural variability, nor can the outcome be generalized, because the sample size is small.


Mathematics ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 132 ◽  
Author(s):  
Awatif Jahman Alqarni ◽  
Azmin Sham Rambely ◽  
Ishak Hashim

In this paper, we study the interactions between microglia and neural stem cells and the impact of these interactions on the brain cells during a stroke. Microglia cells, neural stem cells, the damage on brain cells from the stroke and the impacts these interactions have on living brain cells are considered in the design of mathematical models. The models consist of ordinary differential equations describing the effects of microglia on brain cells and the interactions between microglia and neural stem cells in the case of a stroke. Variables considered include: resident microglia, classically activated microglia, alternatively activated microglia, neural stem cells, tissue damage on cells in the brain, and the impacts these interactions have on living brain cells. The first model describes what happens in the brain at the stroke onset during the first three days without the generation of any neural stem cells. The second model studies the dynamic effect of microglia and neural stem cells on the brain cells following the generation of neural stem cells and potential recovery after this stage. We look at the stability and the instability of the models which are both studied analytically. The results show that the immune cells can help the brain by cleaning dead cells and stimulating the generation of neural stem cells; however, excessive activation may cause damage and affect the injured region. Microglia have beneficial and harmful functions after ischemic stroke. The microglia stimulate neural stem cells to generate new cells that substitute dead cells during the recovery stage but sometimes the endogenous neural stem cells are highly sensitive to inflammatory in the brain.


2011 ◽  
Vol 366 (1582) ◽  
pp. 3210-3224 ◽  
Author(s):  
J. A. Pyle ◽  
N. J. Warwick ◽  
N. R. P. Harris ◽  
Mohd Radzi Abas ◽  
A. T. Archibald ◽  
...  

We present results from the OP3 campaign in Sabah during 2008 that allow us to study the impact of local emission changes over Borneo on atmospheric composition at the regional and wider scale. OP3 constituent data provide an important constraint on model performance. Treatment of boundary layer processes is highlighted as an important area of model uncertainty. Model studies of land-use change confirm earlier work, indicating that further changes to intensive oil palm agriculture in South East Asia, and the tropics in general, could have important impacts on air quality, with the biggest factor being the concomitant changes in NO x emissions. With the model scenarios used here, local increases in ozone of around 50 per cent could occur. We also report measurements of short-lived brominated compounds around Sabah suggesting that oceanic (and, especially, coastal) emission sources dominate locally. The concentration of bromine in short-lived halocarbons measured at the surface during OP3 amounted to about 7 ppt, setting an upper limit on the amount of these species that can reach the lower stratosphere.


2018 ◽  
Vol 121 ◽  
pp. 267-276
Author(s):  
Waldemar Mironiuk

Transport of large amounts of cargo, mining and exploiting natural mineral resources, carrying large number of passengers by sea are characterized by high risk, even if the latest technologies are employed. It is not a long time ago that thousands of people lost their lives in catastrophes of ships, off-shore oil rigs and other marine objects. It is estimated that around 80% of accidents at sea are caused by making wrong decisions by persons keeping watch on the bridge, especially during difficult navigational and weather conditions. Accidents can also be caused by lack of skills necessary for crews or absence of appropriate tools. Therefore, it is important that seafarers should be trained in accordance with the highest standards. The scope of crew research and training may include both static, dynamic and damage stability. This stand bad also enables the analysis of the influence of the free surface effect of the liquid occurring in the compartments or tanks after damage to the ship's hull and the analysis of the impact of cargo operation on the ship's initial stability. Experiences gained on the research stand lead to a better understanding of the phenomena occurring in the current operation of the ship and to improve the safety of swimming. The aim of this article is presentation selected scenarios for the model tests of vessels and to familiarize with the construction of selected types of ship models and the capabilities of stability test stands in the aspect of improving the safety at sea.


2017 ◽  
Vol 17 (11) ◽  
pp. 6925-6955 ◽  
Author(s):  
Johannes Bieser ◽  
Franz Slemr ◽  
Jesse Ambrose ◽  
Carl Brenninkmeijer ◽  
Steve Brooks ◽  
...  

Abstract. Atmospheric chemistry and transport of mercury play a key role in the global mercury cycle. However, there are still considerable knowledge gaps concerning the fate of mercury in the atmosphere. This is the second part of a model intercomparison study investigating the impact of atmospheric chemistry and emissions on mercury in the atmosphere. While the first study focused on ground-based observations of mercury concentration and deposition, here we investigate the vertical and interhemispheric distribution and speciation of mercury from the planetary boundary layer to the lower stratosphere. So far, there have been few model studies investigating the vertical distribution of mercury, mostly focusing on single aircraft campaigns. Here, we present a first comprehensive analysis based on various aircraft observations in Europe, North America, and on intercontinental flights. The investigated models proved to be able to reproduce the distribution of total and elemental mercury concentrations in the troposphere including interhemispheric trends. One key aspect of the study is the investigation of mercury oxidation in the troposphere. We found that different chemistry schemes were better at reproducing observed oxidized mercury patterns depending on altitude. High concentrations of oxidized mercury in the upper troposphere could be reproduced with oxidation by bromine while elevated concentrations in the lower troposphere were better reproduced by OH and ozone chemistry. However, the results were not always conclusive as the physical and chemical parameterizations in the chemistry transport models also proved to have a substantial impact on model results.


2015 ◽  
Vol 15 (11) ◽  
pp. 6549-6559 ◽  
Author(s):  
K. M. Hansen ◽  
J. H. Christensen ◽  
C. Geels ◽  
J. D. Silver ◽  
J. Brandt

Abstract. The Danish Eulerian Hemispheric Model (DEHM) was applied to investigate how projected climate changes will affect the atmospheric transport of 13 persistent organic pollutants (POPs) to the Arctic and their environmental fate within the Arctic. Three sets of simulations were performed, one with present day emissions and initial environmental concentrations from a 20-year spin-up simulation, one with present day emissions and with initial environmental concentrations set to zero and one without emissions but with initial environmental concentrations from the 20-year spin-up simulation. Each set of simulations consisted of two 10-year time slices representing the present (1990–2000) and future (2090–2100) climate conditions. DEHM was driven using meteorological input from the global circulation model, ECHAM/MPI-OM, simulating the SRES (Special Report on Emissions Scenarios) A1B climate scenario. Under the applied climate and emission scenarios, the total mass of all compounds was predicted to be up to 55 % lower across the Northern Hemisphere at the end of the 2090s than in the 1990s. The mass of HCHs within the Arctic was predicted to be up to 38 % higher, whereas the change in mass of the PCBs was predicted to range from 38 % lower to 17 % higher depending on the congener and the applied initial environmental concentrations. The results of this study also indicate that contaminants with no or a short emission history will be more rapidly transported to and build up in the arctic environment in a future warmer climate. The process that dominates the environmental behaviour of POPs in the Arctic under a future warmer climate scenario is the shift in mass of POPs from the surface media to the atmosphere induced by the higher mean temperature. This is to some degree counteracted by higher degradation rates also following the higher mean temperature. The more dominant of these two processes depends on the physical-chemical properties of the compounds. Previous model studies have predicted that the effect of a changed climate on the transport of POPs to the Arctic is moderate relative to the effect of proposed changes in emissions, which is confirmed in this study. However, the model studies do not agree on whether climate change acts to reduce or increase environmental concentrations of POPs in the Arctic, and further work is needed to resolve this matter.


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