Passive Sampling for Determination of the Dissolved Concentrations and Chemical Activities of Organic Contaminants in Soil and Sediment Pore Waters

Author(s):  
Kilian E. C. Smith
2020 ◽  
Author(s):  
Nina Mali ◽  
Anja Koroša ◽  
Primož Auersperger

<p>Micro-organic (MO) compounds have been recognized as an important factor in environmental pollution. Developments in a range of analytical techniques are expanding the number of MOs that can be detected in groundwater. They may not be new contaminants, but recently detected using improved sampling and analytical methods. Monitoring programmes for groundwater are largely based on the collection of grab (spot) samples. One of the methods to determine the presence of organic compounds in groundwater v can also be passive sampling. Contrary to grab sampling, passive sampling is less sensitive to accidental extreme variations of the organic compounds concentrations in groundwater and it also allows determination of a large range of contaminants at once. A passive sampler can cover a long sampling period, integrating the pollutant concentration over time. This paper presents the application of the passive sampling technique for monitoring organic pollutants within the four major alluvial aquifers in Slovenia used for water supply. Passive samples were analyzed by gas chromatography mass spectrometry (GC-MS). For the interpretation of chromatograms, the AMDIS deconvolution was used. The deconvolution was covered by the GC-MS library with retention times for 921 organic contaminants from Agilent USA, as well as by the NIST 2008 library of mass spectra. Most frequently detected MO substances were classified in different pollutant groups with respect to their origin (urban source, agriculture or industry). Based on the results, a comparison of the presence of MOs in the present aquifers was made. Passive sampling with active carbon fibres was proved to be an appropriate method for monitoring micro-organic pollutants in groundwater.</p>


2012 ◽  
Vol 722 ◽  
pp. 8-20 ◽  
Author(s):  
Víctor Matamoros ◽  
Diana Calderón-Preciado ◽  
Carmen Domínguez ◽  
Josep M. Bayona

2009 ◽  
Vol 60 (2) ◽  
pp. 243-257
Author(s):  
Darija Kožul ◽  
Snježana Romanić

Analysis of Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans in Soil and SedimentThis review presents methods for the analysis of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs), called dioxins, in soil and sediment. These compounds are produced as by-products of different combustion processes, and because of their persistency and toxicity they present a threat for animal and human health. Due to their high organic matter content, soil and sediment can accumulate dioxins and have become important secondary emission sources. Determining dioxins in these samples is complex because dioxins are present in trace levels and have to be separated from interferences whereas other classes of organic contaminants are present in higher concentrations. After sampling, follows extraction of compounds with a suitable solvent, extract clean-up from unwanted compounds, and qualitative and quantitative analysis. At the end of this review, we gave levels of PCDD/PCDFs found in soil and sediment samples.


2004 ◽  
Vol 378 (5) ◽  
pp. 1251-1264 ◽  
Author(s):  
Stephen A. Wise ◽  
Dianne L. Poster ◽  
Michele M. Schantz ◽  
John R. Kucklick ◽  
Lane C. Sander ◽  
...  

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