scholarly journals Anthropogenic and Natural Constituents in PM10 at Urban and Rural Sites in North-Western Europe: Concentrations, Chemical Composition and Sources

2013 ◽  
pp. 239-258
Author(s):  
Ernie Weijers ◽  
Martijn Schaap
Keyword(s):  
Chemical Composition ◽  
Western Europe ◽  
Rural Sites ◽  
North Western

scholarly journals Airborne measurements of the spatial distribution of aerosol chemical composition across Europe and evolution of the organic fraction

2010 ◽  
Vol 10 (8) ◽  
pp. 4065-4083 ◽  
Author(s):  
W. T. Morgan ◽  
J. D. Allan ◽  
K. N. Bower ◽  
E. J. Highwood ◽  
D. Liu ◽  
...  
Keyword(s):  
Spatial Distribution ◽  
Chemical Composition ◽  
Ammonium Nitrate ◽  
Western Europe ◽  
Volatile Component ◽  
Organic Aerosol ◽  
Chemical Components ◽  
Airborne Measurements ◽  
North Western ◽  
Aerosol Chemical Composition

Abstract. The spatial distribution of aerosol chemical composition and the evolution of the Organic Aerosol (OA) fraction is investigated based upon airborne measurements of aerosol chemical composition in the planetary boundary layer across Europe. Sub-micron aerosol chemical composition was measured using a compact Time-of-Flight Aerosol Mass Spectrometer (cToF-AMS). A range of sampling conditions were evaluated, including relatively clean background conditions, polluted conditions in North-Western Europe and the near-field to far-field outflow from such conditions. Ammonium nitrate and OA were found to be the dominant chemical components of the sub-micron aerosol burden, with mass fractions ranging from 20–50% each. Ammonium nitrate was found to dominate in North-Western Europe during episodes of high pollution, reflecting the enhanced NOx and ammonia sources in this region. OA was ubiquitous across Europe and concentrations generally exceeded sulphate by 30–160%. A factor analysis of the OA burden was performed in order to probe the evolution across this large range of spatial and temporal scales. Two separate Oxygenated Organic Aerosol (OOA) components were identified; one representing an aged-OOA, termed Low Volatility-OOA and another representing fresher-OOA, termed Semi Volatile-OOA on the basis of their mass spectral similarity to previous studies. The factors derived from different flights were not chemically the same but rather reflect the range of OA composition sampled during a particular flight. Significant chemical processing of the OA was observed downwind of major sources in North-Western Europe, with the LV-OOA component becoming increasingly dominant as the distance from source and photochemical processing increased. The measurements suggest that the aging of OA can be viewed as a continuum, with a progression from a less oxidised, semi-volatile component to a highly oxidised, less-volatile component. Substantial amounts of pollution were observed far downwind of continental Europe, with OA and ammonium nitrate being the major constituents of the sub-micron aerosol burden. Such anthropogenically perturbed air masses can significantly perturb regional climate far downwind of major source regions.

scholarly journals Influence of aerosol chemical composition on N<sub>2</sub>O<sub>5</sub> uptake: airborne regional measurements in North-Western Europe

2014 ◽  
Vol 14 (13) ◽  
pp. 19673-19718 ◽  
Author(s):  
W. T. Morgan ◽  
B. Ouyang ◽  
J. D. Allan ◽  
E. Aruffo ◽  
P. Di Carlo ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Ammonium Nitrate ◽  
Water Content ◽  
Atmospheric Chemistry ◽  
Western Europe ◽  
Organic Aerosol ◽  
Atmospheric Composition ◽  
Airborne Measurements ◽  
North Western ◽  
Aerosol Chemical Composition

Abstract. Aerosol chemical composition was found to influence nighttime atmospheric chemistry during a series of airborne measurements in North-Western Europe in summer conditions, which has implications for regional air quality and climate. The uptake of dinitrogen pentoxide, γ (N2O5), to particle surfaces was found to be modulated by the amount of water content and ammonium nitrate present in the aerosol. The conditions prevalent in this study suggest that the net uptake rate of N2O5 to atmospheric aerosols was relatively efficient compared to previous studies, with γ (N2O5) values in the range 0.01–0.03. This is likely a consequence of the elevated relative humidity in the region, which promotes greater aerosol water content. Increased nitrate concentrations relative to particulate water were found to suppress N2O5 uptake. The results presented here contrast with previous ambient studies of N2O5 uptake, which have generally taken place in low-nitrate environments in the USA. Comparison of the N2O5 uptake derived from the measurements with a parameterised scheme that is based on the ratio of particulate water to nitrate yielded reasonably good agreement in terms of the magnitude and variation in uptake, provided the effect of chloride was neglected. An additional suppression of the parameterised uptake is likely required to fully capture the variation in N2O5 uptake, which could be achieved via the known suppression by organic aerosol. However, existing parameterisations representing the suppression by organic aerosol were unable to fully represent the variation in N2O5 uptake. These results provide important ambient measurement constraint on our ability to predict N2O5 uptake in regional and global aerosol models. N2O5 uptake is a potentially important source of nitrate aerosol and a sink of the nitrate radical, which is the main nocturnal oxidant in the atmosphere. The results further highlight the importance of ammonium nitrate in North-Western Europe as a key component of atmospheric composition in the region.

scholarly journals Enhancement of the aerosol direct radiative effect by semi-volatile aerosol components: airborne measurements in North-Western Europe

2010 ◽  
Vol 10 (4) ◽  
pp. 10653-10705 ◽  
Author(s):  
W. T. Morgan ◽  
J. D. Allan ◽  
K. N. Bower ◽  
M. Esselborn ◽  
B. Harris ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Chemical Composition ◽  
Vertical Distribution ◽  
Ammonium Nitrate ◽  
Sulphur Dioxide ◽  
Radiative Forcing ◽  
Western Europe ◽  
Aerosol Mass ◽  
Sulphur Dioxide Emissions ◽  
North Western

Abstract. A case study of atmospheric aerosol measurements exploring the impact of the vertical distribution of aerosol chemical composition upon the radiative budget in North-Western Europe is presented. Sub-micron aerosol chemical composition was measured by an Aerodyne Aerosol Mass Spectrometer (AMS) on both an airborne platform and a ground-based site at Cabauw in the Netherlands. The examined period in May 2008 was characterised by enhanced pollution loadings in North-Western Europe and was dominated by ammonium nitrate and Organic Matter (OM). Both ammonium nitrate and OM were observed to increase with altitude in the atmospheric boundary layer. This is primarily attributed to partitioning of semi-volatile gas phase species to the particle phase at reduced temperature and enhanced relative humidity. Increased ammonium nitrate concentrations in particular were found to strongly increase the ambient scattering potential of the aerosol burden, which was a consequence of the large amount of associated water as well as the enhanced mass. During particularly polluted conditions, increases in aerosol optical depth of 50–100% were estimated to occur due to the observed increase in secondary aerosol mass and associated water uptake. Furthermore, the single scattering albedo was also shown to increase with height in the boundary layer. These enhancements combined to increase the negative direct aerosol radiative forcing by close to a factor of two at the median percentile level. Such increases have major ramifications for regional climate predictions as semi-volatile components are often not included in aerosol models. The results presented here provide an ideal opportunity to test regional and global representations of both the aerosol vertical distribution and subsequent impacts in North-Western Europe. North-Western Europe can be viewed as an analogue for the possible future air quality over other polluted regions of the Northern Hemisphere, where substantial reductions in sulphur dioxide emissions have yet to occur. Anticipated reductions in sulphur dioxide in polluted regions will result in an increase in the availability of ammonia to form ammonium nitrate as opposed to ammonium sulphate. This will be most important where intensive agricultural practises occur. Our observations over North-Western Europe, a region where sulphur dioxide emissions have already been reduced, indicate that failure to include the semi-volatile behaviour of ammonium nitrate will result in significant errors in predicted aerosol direct radiative forcing. Such errors will be particularly significant on regional scales.

scholarly journals Airborne measurements of the spatial distribution of aerosol chemical composition across Europe and evolution of the organic fraction

2009 ◽  
Vol 9 (6) ◽  
pp. 27215-27265 ◽  
Author(s):  
W. T. Morgan ◽  
J. D. Allan ◽  
K. N. Bower ◽  
E. J. Highwood ◽  
D. Liu ◽  
...  
Keyword(s):  
Spatial Distribution ◽  
Chemical Composition ◽  
Ammonium Nitrate ◽  
Western Europe ◽  
Volatile Component ◽  
Organic Aerosol ◽  
Chemical Components ◽  
Airborne Measurements ◽  
North Western ◽  
Aerosol Chemical Composition

Abstract. The spatial distribution of aerosol chemical composition and the evolution of the Organic Aerosol (OA) fraction is investigated based upon airborne measurements of aerosol chemical composition in the planetary boundary layer across Europe. Sub-micron aerosol chemical composition was measured using a compact Time-of-Flight Aerosol Mass Spectrometer (cToF-AMS). A range of sampling conditions were evaluated, including relatively clean background conditions, polluted conditions in North-Western Europe and the near-field to far-field outflow from such conditions. Ammonium nitrate and OA were found to be the dominant chemical components of the sub-micron aerosol burden, with mass fractions ranging from 20–50% each. Ammonium nitrate was found to dominate in North-Western Europe during episodes of high pollution, reflecting the enhanced NOx and ammonia sources in this region. OA was ubiquitous across Europe and concentrations generally exceeded sulphate by 50–100%. A factor analysis of the OA burden was performed in order to probe the evolution across this large range of spatial and temporal scales. Two separate Oxygenated Organic Aerosol (OOA) components were identified; one representing an aged-OOA, termed Low Volatility-OOA and another representing fresher-OOA, termed Semi Volatile-OOA on the basis of their mass spectral similarity to previous studies. The factors derived from different flights were not chemically the same but rather reflect the range of OA composition sampled during a particular flight. Significant chemical processing of the OA was observed downwind of major sources in North-Western Europe, with the LV-OOA component becoming increasingly dominant as the distance from source and photochemical processing increased. The measurements suggest that the aging of OA can be viewed as a continuum, with a progression from a less oxidised, semi-volatile component to a highly oxidised, less-volatile component. Substantial amounts of pollution were observed far downwind of continental Europe, with OA and ammonium nitrate being the major constituents of the sub-micron aerosol burden. Such anthropogenically perturbed air masses can significantly perturb regional climate far downwind of major source regions.

scholarly journals Enhancement of the aerosol direct radiative effect by semi-volatile aerosol components: airborne measurements in North-Western Europe

2010 ◽  
Vol 10 (17) ◽  
pp. 8151-8171 ◽  
Author(s):  
W. T. Morgan ◽  
J. D. Allan ◽  
K. N. Bower ◽  
M. Esselborn ◽  
B. Harris ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Chemical Composition ◽  
Vertical Distribution ◽  
Ammonium Nitrate ◽  
Sulphur Dioxide ◽  
Radiative Forcing ◽  
Western Europe ◽  
Aerosol Mass ◽  
Sulphur Dioxide Emissions ◽  
North Western

Abstract. A case study of atmospheric aerosol measurements exploring the impact of the vertical distribution of aerosol chemical composition upon the radiative budget in North-Western Europe is presented. Sub-micron aerosol chemical composition was measured by an Aerodyne Aerosol Mass Spectrometer (AMS) on both an airborne platform and a ground-based site at Cabauw in the Netherlands. The examined period in May 2008 was characterised by enhanced pollution loadings in North-Western Europe and was dominated by ammonium nitrate and Organic Matter (OM). Both ammonium nitrate and OM were observed to increase with altitude in the atmospheric boundary layer. This is primarily attributed to partitioning of semi-volatile gas phase species to the particle phase at reduced temperature and enhanced relative humidity. Increased ammonium nitrate concentrations in particular were found to strongly increase the ambient scattering potential of the aerosol burden, which was a consequence of the large amount of associated water as well as the enhanced mass. During particularly polluted conditions, increases in aerosol optical depth of 50–100% were estimated to occur due to the observed increase in secondary aerosol mass and associated water uptake. Furthermore, the single scattering albedo was also shown to increase with height in the boundary layer. These enhancements combined to increase the negative direct aerosol radiative forcing by close to a factor of two at the median percentile level. Such increases have major ramifications for regional climate predictions as semi-volatile components are often not included in aerosol models. The results presented here provide an ideal opportunity to test regional and global representations of both the aerosol vertical distribution and subsequent impacts in North-Western Europe. North-Western Europe can be viewed as an analogue for the possible future air quality over other polluted regions of the Northern Hemisphere, where substantial reductions in sulphur dioxide emissions have yet to occur. Anticipated reductions in sulphur dioxide in polluted regions will result in an increase in the availability of ammonia to form ammonium nitrate as opposed to ammonium sulphate. This will be most important where intensive agricultural practises occur. Our observations over North-Western Europe, a region where sulphur dioxide emissions have already been reduced, indicate that failure to include the semi-volatile behaviour of ammonium nitrate will result in significant errors in predicted aerosol direct radiative forcing. Such errors will be particularly significant on regional scales.

Elucidating the Consequences of a Warming Climate for Common Bat Species in North-Western Europe

2020 ◽  
Vol 21 (2) ◽  
pp. 359
Author(s):  
Niamh Roche ◽  
Steve Langton ◽  
Tina Aughney ◽  
Deirdre Lynn ◽  
Ferdia Marnell
Keyword(s):  
Western Europe ◽  
Warming Climate ◽  
North Western

scholarly journals Against management: Auto-critique

Organization ◽  
2021 ◽  
pp. 135050842110209
Author(s):  
Martin Parker
Keyword(s):  
Business School ◽  
Western Europe ◽  
Business Schools ◽  
The Uk ◽  
North Western ◽  
Made In ◽  
Highly Cited

In this review I consider the 20 years that have passed since the publication of my book Against Management. I begin by locating it in the context of the expanding business schools of the UK in the 1990s, and the growth of CMS in north western Europe. After positioning the book within its time, and noting that the book is now simultaneously highly cited and irrelevant, I then explore the arguments I made in the final chapter. If the book is of interest for the next two decades, it because it gestures towards the importance of alternative forms of organization, which I continue to maintain are not reducible to ‘management’. Given the intensifying crises of climate, ecology, inequality and democracy, developing alternatives must be understood as the historical task of CMS within the business school and I propose a ten-point manifesto in support of that commitment.

scholarly journals Striking forest revival at the end of the Roman Period in north-western Europe

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
C. Lambert ◽  
A. Penaud ◽  
M. Vidal ◽  
C. Gandini ◽  
L. Labeyrie ◽  
...  
Keyword(s):  
North Atlantic ◽  
Western Europe ◽  
Anthropogenic Activities ◽  
Sedimentary Environment ◽  
Pollen Grains ◽  
Roman Period ◽  
Freshwater Microalgae ◽  
Environmental Signals ◽  
The North ◽  
North Western

AbstractThe Holocene period (last 11,700 years BP) has been marked by significant climate variability over decadal to millennial timescales. The underlying mechanisms are still being debated, despite ocean–atmosphere–land connections put forward in many paleo-studies. Among the main drivers, involving a cluster of spectral signatures and shaping the climate of north-western Europe, are solar activity, the North Atlantic Oscillation (NAO) varying atmospheric regimes and North Atlantic oceanic gyre dynamics. Over the last 2500 years BP, paleo-environmental signals have been strongly affected by anthropogenic activities through deforestation and land use for crops, grazing, habitations, or access to resources. Palynological proxies (especially pollen grains and marine or freshwater microalgae) help to highlight such anthropogenic imprints over natural variability. Palynological analyses conducted in a macro-estuarine sedimentary environment of north-western France over the last 2500 years BP reveal a huge and atypical 300 year-long arboreal increase between 1700 and 1400 years BP (around 250 and 550 years AD) that we refer to as the ‘1.7–1.4 ka Arboreal Pollen rise event’ or ‘1.7–1.4 ka AP event’. Interestingly, the climatic 1700–1200 years BP interval coincides with evidence for the withdrawal of coastal societies in Brittany (NW France), in an unfavourable socio-economic context. We suggest that subpolar North Atlantic gyre strengthening and related increasing recurrence of storminess extremes may have affected long-term coastal anthropogenic trajectories resulting in a local collapse of coastal agrarian societies, partly forced by climatic degradation at the end of the Roman Period.

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