Metal Complexes as Structure-Directing Agents for Zeolites and Related Microporous Materials

2017 ◽  
pp. 179-200 ◽  
Author(s):  
Abigail E. Watts ◽  
Alessandro Turrina ◽  
Paul A. Wright
Keyword(s):  
Metal Complexes ◽  
Microporous Materials ◽  
Structure Directing Agents

Supramolecular Chemistry in the Structure Direction of Microporous Materials from Aromatic Structure-Directing Agents

2008 ◽  
Vol 130 (40) ◽  
pp. 13274-13284 ◽  
Author(s):  
Luis Gómez-Hortigüela ◽  
Fernando López-Arbeloa ◽  
Furio Corà ◽  
Joaquín Pérez-Pariente
Keyword(s):  
Supramolecular Chemistry ◽  
Microporous Materials ◽  
Aromatic Structure ◽  
Structure Directing Agents

ChemInform Abstract: Synthesis of Microporous Materials Using Macrocycles as Structure Directing Agents

ChemInform ◽  
2008 ◽  
Vol 39 (14) ◽  
Author(s):  
Paul A. Wright ◽  
Russell E. Morris ◽  
Paul S. Wheatley
Keyword(s):  
Microporous Materials ◽  
Structure Directing Agents

Molecular Sieve Synthesis using Metallocenes as Structure Directing Agents

1994 ◽  
Vol 368 ◽  
Author(s):  
Kenneth J. Balkus ◽  
Alexei G. Gabrielov ◽  
Netanya Sandler
Keyword(s):  
Metal Complex ◽  
Metal Complexes ◽  
Molecular Sieves ◽  
Molecular Sieve ◽  
Microporous Materials ◽  
Synthesis And Characterization ◽  
Bifunctional Catalysts ◽  
Large Pore ◽  
High Silica

ABSTRACTWe have been exploring molecular sieve synthesis using metal complexes as templates. Our objectives were to affect the crystallization of new structures as well as prepare bifunctional catalysts via the encapsulation of metal complexes during synthesis. In this paper the results for the synthesis of SiO2, AlPO4 and SAPO molecular sieves in the presence of metallocenes will be presented. In particular, Cobalticinium ion, Cp2Co+, was found to be a template for Nonasil, AlPO4−5, AlPO4−16, SAPO−16 and CoAPO−16 which are known phases but require templates. The larger decamethyl derivative, CP*2Co+ has produced a novel high silica zeolite molecular sieve, UTD-1 as well as a new SAPO phase UTD-2 which appear to be large pore materials. In all cases, the metal complex is occluded intact and cannot be extracted. Aspects of the synthesis and characterization of these microporous materials are presented below.

ChemInform Abstract: Structure-Directed Materials Syntheses: Metal Complexes as Structure-Directing Agents for Zeolite-Type Solids

ChemInform ◽  
2010 ◽  
Vol 29 (14) ◽  
pp. no-no
Author(s):  
P. BEHRENS ◽  
C. PANZ ◽  
V. HUFNAGEL ◽  
B. LINDLAR ◽  
C. FREYHARDT ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Zeolite Type ◽  
Abstract Structure ◽  
Structure Directing Agents
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