Structure and Bonding in Heme–Nitrosyl Complexes and Implications for Biology

2013 ◽  
pp. 155-223 ◽  
Author(s):  
Nicolai Lehnert ◽  
W. Robert Scheidt ◽  
Matthew W. Wolf
Keyword(s):  
Nitrosyl Complexes ◽  
Structure And Bonding

STRUCTURE AND BONDING NATURE OF Pd-Si AMORPHOUS ALLOYS

1979 ◽  
Vol 40 (C2) ◽  
pp. C2-104-C2-106
Author(s):  
A. Matsuzaki ◽  
S. Nanao ◽  
H. Ino
Keyword(s):  
Amorphous Alloys ◽  
Structure And Bonding

ESR study of the structure and bonding situation in thiocyanatocopper(II) complexes with imidazole derivatives

1988 ◽  
Vol 53 (1) ◽  
pp. 56-60
Author(s):  
Anna Mašlejová ◽  
Reinhard Kirmse
Keyword(s):  
Unpaired Electron ◽  
Hyperfine Splitting ◽  
Esr Spectra ◽  
Ligand Field ◽  
Imidazole Derivatives ◽  
Bonding Parameters ◽  
Monomeric Complex ◽  
Structure And Bonding ◽  
Frozen Solutions ◽  
Planar Symmetry

ESR spectra of thianatocopper(II) complexes with imidazole derivatives were studied in ethanolic solutions at 295 and 123 K. Axialsymmetric spectra, attributed to the monomeric complex units, were obtained for the frozen solutions. The bonding parameters were interpreted by using calculated g, Cu-hyperfine, and 14N-ligand hyperfine splitting values. The Cu-N bond parameters indicate a considerable delocalization of the unpaired electron. The values of the isotropic Cu-hyperfine splitting suggest that the deviations from the planar symmetry of the CuN4 units are due to tetrahedral perturbation of the ligand field.

Nickel nitrosyl complexes

1960 ◽  
Vol 14 (3-4) ◽  
pp. 307-308 ◽  
Author(s):  
R.D. Feltham
Keyword(s):  
Nitrosyl Complexes
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