Selective Transfer Hydrogenation of α,β-Unsaturated Carbonyl Compounds

2018 ◽  
pp. 193-224 ◽  
Author(s):  
Ronald A. Farrar-Tobar ◽  
Sergey Tin ◽  
Johannes G. de Vries
Keyword(s):  
Carbonyl Compounds ◽  
Transfer Hydrogenation ◽  
Selective Transfer

Highly Selective Transfer Hydrogenation of Carbonyl Compounds Using La2O3

2018 ◽  
Vol 91 (11) ◽  
pp. 1561-1569 ◽  
Author(s):  
Taufik Abdillah Natsir ◽  
Takayoshi Hara ◽  
Nobuyuki Ichikuni ◽  
Shogo Shimazu
Keyword(s):  
Carbonyl Compounds ◽  
Transfer Hydrogenation ◽  
Selective Transfer

Selective Transfer Hydrogenation of Carbonyl Compounds by Ruthenium Nanoclusters Supported on Alkali-Exchanged Zeolite β.

ChemInform ◽  
2007 ◽  
Vol 38 (5) ◽  
Author(s):  
M. Lakshmi Kantam ◽  
B. Purna Chandra Rao ◽  
B. M. Choudary ◽  
B. Sreedhar
Keyword(s):  
Carbonyl Compounds ◽  
Transfer Hydrogenation ◽  
Selective Transfer ◽  
Zeolite Β

Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols

2020 ◽  
Vol 22 (11) ◽  
pp. 3323-3357 ◽  
Author(s):  
Ronald A. Farrar-Tobar ◽  
Andrea Dell'Acqua ◽  
Sergey Tin ◽  
Johannes G. de Vries
Keyword(s):  
Carbonyl Compounds ◽  
State Of The Art ◽  
The State ◽  
Transfer Hydrogenation ◽  
Allylic Alcohols ◽  
Selective Transfer ◽  
Unsaturated Aldehydes ◽  
Aldehydes And Ketones ◽  
Metal Catalyzed

This review describes the state-of-the-art of metal-catalyzed selective transfer hydrogenation of α,β-unsaturated aldehydes and ketones to the allylic alcohols, covering the literature of the last 30 years.

Highly selective transfer hydrogenation of α,β-unsaturated carbonyl compounds using Cu-based nanocatalysts

2017 ◽  
Vol 7 (13) ◽  
pp. 2828-2837 ◽  
Author(s):  
Nazia Siddqui ◽  
Bipul Sarkar ◽  
Chandrashekar Pendem ◽  
Rubina khatun ◽  
L. N. Sivakumar Konthala ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Selective Transfer ◽  
Unsaturated Alcohols

Simultaneous dehydrogenation of cyclohexanol to cyclohexanone and hydrogenation of α,β-unsaturated carbonyl compounds to corresponding α,β-unsaturated alcohols was carried out in a single pot reaction without addition of any external hydrogen donor.

Selective Transfer Hydrogenation of Carbonyl Compounds by Ruthenium Nanoclusters Supported on Alkali-Exchanged Zeolite Beta

2006 ◽  
Vol 348 (14) ◽  
pp. 1970-1976 ◽  
Author(s):  
M. Lakshmi Kantam ◽  
B. Purna Chandra Rao ◽  
B. M. Choudary ◽  
B. Sreedhar
Keyword(s):  
Carbonyl Compounds ◽  
Zeolite Beta ◽  
Transfer Hydrogenation ◽  
Selective Transfer

A Hollow in Hollow Nanoreactor of H-PtCu@SiO2 for the Selective Transfer Hydrogenation

2021 ◽  
pp. 131417
Author(s):  
Rongxiu Guo ◽  
Xinyue Zhang ◽  
Ze-Nan Hu ◽  
Hong Li ◽  
Jianyi Gao ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Selective Transfer

Recyclable Covalent Triazine Framework-based Ru Catalyst for Transfer Hydrogenation of Carbonyl Compounds in Water

2019 ◽  
Vol 7 (9) ◽  
pp. 8893-8899 ◽  
Author(s):  
Sudakar Padmanaban ◽  
Gunniya Hariyanandam Gunasekar ◽  
Mearae Lee ◽  
Sungho Yoon
Keyword(s):  
Carbonyl Compounds ◽  
Transfer Hydrogenation ◽  
Ru Catalyst ◽  
Covalent Triazine Framework

scholarly journals Catalytic Activity of High-Surface-Area Amorphous MgO Obtained from Upsalite

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1338
Author(s):  
Marek Gliński ◽  
Ewa M. Iwanek (nee Wilczkowska) ◽  
Urszula Ulkowska ◽  
Agnieszka Czajka ◽  
Zbigniew Kaszkur
Keyword(s):  
Surface Area ◽  
Carbonyl Compounds ◽  
Main Product ◽  
High Surface ◽  
High Surface Area ◽  
Hydrogenation Reaction ◽  
Transfer Hydrogenation ◽  
Reaction Conditions ◽  
Synthesis Conditions ◽  
Transfer Hydrogenation Reaction

The first aim of the research was to synthesize a pure Upsalite, which is an amorphous form of MgCO3, by modifying a procedure described in the literature, so that it would be the precursor of a high-surface, amorphous magnesium oxide. The results indicate that within the studied reaction conditions, the type of alcohol used as the reactant has the most pronounced effect on the yield of reaction. From the two alcohols that led to the highest yield of Upsalite, methanol gave a substantially larger surface area (794 vs. 191 m2 g−1). The optimized synthesis conditions of Upsalite were used to obtain MgO via thermolysis, whose activity in the transfer hydrogenation reaction (THR) from ethanol, 2-propanol and 2-pentanol to various carbonyl compounds was determined. The optimal conditions for the thermolysis were as follows: vacuum, T = 673 K as the final temperature, and a heating rate of 2 deg min−1. The high-surface, amorphous magnesia (SBET = 488 m2 g−1) was found to be a very selective catalyst to 4-t-butylcyclohexanone in THR, which led to a diastereoselectivity of over 94% to the E-isomer of 4-t-butylcyclohexanol for more than 3 h, with conversions of up to 97% with either 2-propanol or 2-pentanol as the hydrogen donor. In the case of acrolein and 2-n-propylacrolein being used as the hydrogen acceptors, the unsaturated alcohol (UOL) was the main product of the reaction, with higher UOL yields noted for ethanol than 2-propanol.

scholarly journals Decreasing Coordinated N Atoms in Single-Atom Cu Catalyst to Achieve Selective Transfer Hydrogenation of Alkynes

2021 ◽  
Author(s):  
Xuge Zhang ◽  
He Lin ◽  
Jian Zhang ◽  
Yajun Qiu ◽  
Zedong Zhang ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Transfer Hydrogenation ◽  
Single Atom ◽  
Selective Transfer ◽  
Active Centers ◽  
Coordination Sites ◽  
Cu Catalyst

Single-atom (SA) catalysts have attracted broad attention for their distinctive catalytic properties in diverse reactions. Increasing unsaturated coordination sites of active centers is a valid and challenging approach to improve...

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