Long Range Particle Transport in Liquid Crystal-alkane Mixtures

Author(s):  
Beate Ullrich ◽  
Ewa Ilska ◽  
Norbert Höhn ◽  
Doris Vollmer
2021 ◽  
Author(s):  
Ya-xin Li ◽  
Hong-fei Gao ◽  
Rui-bin Zhang ◽  
Kutlwano Gabana ◽  
Qing Chang ◽  
...  

Abstract Helical structures continue to inspire, and there is considerable temptation to attribute helicity to columnar liquid crystals (LC). While short isohelical sequences are undoubtedly present, and longer ones in chiral or chiral-doped compounds, the order is only short-range, equivalent to a paramagnet without or with field. However, here we report a confirmed example of a true LC phase of achiral compounds consisting of columns, each being a long-range homochiral helix. Long-range periodicity and isochirality are maintained by intercolumnar interaction. This orthorhombic LC, spacegroup Fddd, is discovered in compounds with either bent or straight rod-like pi-conjugated cores. There are 4 right and 4 left-handed ribbons or star-profiled columns per unit cell. The structure is equivalent to an antiferromagnet with twist replacing spins. A theory based on interacting quadrupoles confirms this structure as energetically favoured over alternatives. The findings open a new approach to homochirality in achiral compounds, with promising optical/chiroptical properties.


2017 ◽  
Vol 9 (7) ◽  
pp. 6228-6236 ◽  
Author(s):  
Nadine Tchamba Yimga ◽  
Charusheela Ramanan ◽  
Holger Borchert ◽  
Jürgen Parisi ◽  
Harald Untenecker ◽  
...  

1997 ◽  
Vol 78 (11) ◽  
pp. 2128-2131 ◽  
Author(s):  
F. Anderegg ◽  
X.-P. Huang ◽  
C. F. Driscoll ◽  
E. M. Hollmann ◽  
T. M. O'Neil ◽  
...  

2015 ◽  
Vol 54 (4) ◽  
pp. 912 ◽  
Author(s):  
Tuan Quoc Banh ◽  
Kohei Suzuki ◽  
Munehiro Kimura ◽  
Tatsutoshi Shioda

1997 ◽  
Vol 4 (5) ◽  
pp. 1552-1558 ◽  
Author(s):  
F. Anderegg ◽  
X.-P. Huang ◽  
E. M. Hollmann ◽  
C. F. Driscoll ◽  
T. M. O’Neil ◽  
...  

Soft Matter ◽  
2012 ◽  
Vol 8 (1) ◽  
pp. 173-179 ◽  
Author(s):  
Jonathan Milette ◽  
Stephen J. Cowling ◽  
Violeta Toader ◽  
Cyrille Lavigne ◽  
Isabel M. Saez ◽  
...  

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