Arylation with Diaryliodonium Salts

2015 ◽  
pp. 135-166 ◽  
Author(s):  
Berit Olofsson
Keyword(s):  
Diaryliodonium Salts

One-Pot Synthesis and Conformational Analysis of 6-Membered Cyclic Iodonium Salts

2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim
Keyword(s):  
Conformational Analysis ◽  
Bronsted Acids ◽  
One Pot ◽  
Benzyl Alcohols ◽  
Iodonium Salts ◽  
Efficient Approach ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>

Cu-Catalyzed Cascade Reaction of Isoxazoles with Diaryliodonium Salts for the Synthesis of Acridines

2020 ◽  
Vol 17 (12) ◽  
pp. 944-950
Author(s):  
Shangrong Zhu ◽  
Xuechen Lu ◽  
Qiuneng Xu ◽  
Jian Li ◽  
Shenghu Yan
Keyword(s):  
Cascade Reaction ◽  
Efficient Synthesis ◽  
Acridine Derivatives ◽  
Diaryliodonium Salts

A straightforward and efficient synthesis of acridine derivatives via a copper-catalyzed cascade reaction among isoxazoles and diaryliodonium salts is achieved. Various mono-, multi-substituted and 9-substituted acridine derivatives could be obtained in moderate to good yields. The process has gone through tandem double arylation and Friedel-Crafts reactions.

ChemInform Abstract: A Simple and Facile Heck-Type Arylation of Alkenes with Diaryliodonium Salts Using Magnetically Recoverable Pd-Catalyst.

ChemInform ◽  
2012 ◽  
Vol 43 (50) ◽  
pp. no-no
Author(s):  
Buchi Reddy Vaddula ◽  
Amit Saha ◽  
John Leazer ◽  
Rajender S. Varma
Keyword(s):  
Pd Catalyst ◽  
Diaryliodonium Salts

scholarly journals Copper-Catalyzed Synthesis of Axially Chiral Biaryls with Diaryliodonium Salts as Arylation Reagents

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3223
Author(s):  
Ji-Wei Zhang ◽  
Shao-Hua Xiang ◽  
Shaoyu Li ◽  
Bin Tan
Keyword(s):  
Amino Alcohols ◽  
Sigmatropic Rearrangement ◽  
Synthetic Route ◽  
Mild Conditions ◽  
Good Substrate ◽  
Diaryliodonium Salts ◽  
Axially Chiral

NOBIN and BINAM derivatives harboring biaryl frameworks are recognized as a class of important atropisomers with versatile applications. Here, we present an efficient synthetic route to access such compounds through copper-catalyzed domino arylation of N-arylhydroxylamines or N-arylhydrazines with diaryliodonium salts and [3,3]-sigmatropic rearrangement. This reaction features mild conditions, good substrate compatibility, and excellent efficiency. The practicality of this protocol was further extended by the synthesis of biaryl amino alcohols.

ChemInform Abstract: Iridium(III)-Catalyzed Direct Arylation of C-H Bonds with Diaryliodonium Salts.

ChemInform ◽  
2016 ◽  
Vol 47 (9) ◽  
pp. no-no
Author(s):  
Pan Gao ◽  
Wei Guo ◽  
Jingjing Xue ◽  
Yue Zhao ◽  
Yu Yuan ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Diaryliodonium Salts

ChemInform Abstract: C-H Arylation of Azaheterocycles: A Direct Ligand-Free and Cu-Catalyzed Approach Using Diaryliodonium Salts.

ChemInform ◽  
2014 ◽  
Vol 46 (3) ◽  
pp. no-no
Author(s):  
Dalip Kumar ◽  
Meenakshi Pilania ◽  
V. Arun ◽  
Savita Pooniya
Keyword(s):  
Diaryliodonium Salts ◽  
Ligand Free

Covalent Grafting of Glassy Carbon Electrodes with Diaryliodonium Salts:  New Aspects

Langmuir ◽  
2007 ◽  
Vol 23 (7) ◽  
pp. 3786-3793 ◽  
Author(s):  
Karina Højrup Vase ◽  
Allan Hjarbæk Holm ◽  
Kion Norrman ◽  
Steen Uttrup Pedersen ◽  
Kim Daasbjerg
Keyword(s):  
Glassy Carbon ◽  
Carbon Electrodes ◽  
Glassy Carbon Electrodes ◽  
Diaryliodonium Salts ◽  
Covalent Grafting

ChemInform Abstract: One-Pot C-H Functionalization of Arenes by Diaryliodonium Salts.

ChemInform ◽  
2016 ◽  
Vol 47 (49) ◽  
Author(s):  
Marcus Reitti ◽  
Piret Villo ◽  
Berit Olofsson
Keyword(s):  
One Pot ◽  
Diaryliodonium Salts

Ionic liquid-accelerated N-arylation of 5-arylidene-2,4-thiazolidinediones with diaryliodonium salts

2008 ◽  
Vol 2008 (12) ◽  
pp. 686-687 ◽  
Author(s):  
De-Hong Yang ◽  
Hong-Liang Gao ◽  
Ben-Yong Yang ◽  
Zhen-Chu Chen
Keyword(s):  
Ionic Liquid ◽  
Diaryliodonium Salts
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