parahydrogen Induced Polarization by Homogeneous Catalysis: Theory and Applications

Author(s):  
Lisandro Buljubasich ◽  
María Belén Franzoni ◽  
Kerstin Münnemann
Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 769 ◽  
Author(s):  
Fouzan A. Alfouzan ◽  
Abdulrahman M. Alotaibi ◽  
Leif H. Cox ◽  
Michael S. Zhdanov

The Saudi Arabian Glass Earth Pilot Project is a geophysical exploration program to explore the upper crust of the Kingdom for minerals, groundwater, and geothermal resources as well as strictly academic investigations. The project began with over 8000 km2 of green-field area. Airborne geophysics including electromagnetic (EM), magnetics, and gravity were used to develop several high priority targets for ground follow-up. Based on the results of airborne survey, a spectral induced polarization (SIP) survey was completed over one of the prospective targets. The field data were collected with a distributed array system, which has the potential for strong inductive coupling. This was examined in a synthetic study, and it was determined that with the geometries and conductivities in the field survey, the inductive coupling effect may be visible in the data. In this study, we also confirmed that time domain is vastly superior to frequency domain for avoiding inductive coupling, that measuring decays from 50 ms to 2 s allow discrimination of time constants from 1 ms to 5 s, and the relaxation parameter C is strongly coupled to intrinsic chargeability. We developed a method to fully include all 3D EM effects in the inversion of induced polarization (IP) data. The field SIP data were inverted using the generalized effective-medium theory of induced polarization (GEMTIP) in conjunction with an integral equation-based modeling and inversion methods. These methods can replicate all inductive coupling and EM effects, which removes one significant barrier to inversion of large bandwidth spectral IP data. The results of this inversion were interpreted and compared with results of drill hole set up in the survey area. The drill hole intersected significant mineralization which is currently being further investigated. The project can be considered a technical success, validating the methods and effective-medium inversion technique used for the project.


Author(s):  
Pramod Kumar ◽  
Animesh Das ◽  
Biplab Maji

The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...


ChemPhysChem ◽  
2021 ◽  
Author(s):  
Oleg G. Salnikov ◽  
Nikita V. Chukanov ◽  
Larisa M. Kovtunova ◽  
Valerii I. Bukhtiyarov ◽  
Kirill V. Kovtunov ◽  
...  
Keyword(s):  

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Ekaterina V. Pokochueva ◽  
Dudari B. Burueva ◽  
Oleg G. Salnikov ◽  
Igor V. Koptyug

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