Delayed Action of Synthetic Polymers for Controlled Mineralization of Calcium Carbonate

2006 ◽  
pp. 119-154 ◽  
Author(s):  
Kensuke Naka
Keyword(s):  
Calcium Carbonate ◽  
Synthetic Polymers ◽  
Delayed Action

Delayed Action Micro-Emulsion Breaker and Its Applications to Improved Completions Operations – An NNPC/FEPDC JV Approach During Completions Operations

2021 ◽  
Author(s):  
Ebuka Ifeduba ◽  
Bernard Ainoje ◽  
Tunde Alabi ◽  
John Akadang ◽  
Ena Agbahovbe ◽  
...  
Keyword(s):  
Calcium Carbonate ◽  
Filter Cake ◽  
Drilling Process ◽  
Well Control ◽  
Drain Hole ◽  
Open Hole ◽  
Micro Emulsion ◽  
Delayed Action ◽  
Isolation Device ◽  
Mild Acid

Abstract In horizontal open hole wells, the formation of filter cake while drilling the open hole section of the well is desirable. This filter cake serves the purpose of forming a semi-impervious layer around the reservoir drain-hole. This layer helps reduce losses considering the overbalance required for well control during drilling. It also serves as an additional structural support to keep the open hole stable when the drilling bottom hole assembly (BHA) is pulled out of hole and the screens and lower completions accessories are being run in hole. However, when thewell is put into production, the filter cake becomes a contributor to skin and poor reservoir productivity. It is therefore required to get rid of the filter cake after running the screens and the lower completion. Having procured and prepared the sand screens for deployment after drilling the open hole section, it is important that they are run to the bottom successfully with minimal damage and plugging. Usually, the open hole section of the horizontal well is drilled with specially formulated drill-in-fluids (DIF). Since this section is drilled in over balanced mode, the exerted pressure keeps the hole open so that the sand screen can be run successfully. The DIF replaces the drilling mud used to drill the earlier hole section(s) but in addition to providing well control via overbalance and transporting cuttings from the hole to surface, it also minimizes invasion damage to the reservoir pay zone. A commonly used weighing material when densities up to 11.5ppg are required for well control is calcium carbonate (CaCO3). When densities above 11.5ppg are required (for deeper, abnormally pressured reservoirs), it becomes necessary to weight up the mud with a heavier material, usually barite + CaCO3. During the drilling process, this overbalance pressure exerted on the reservoir forces the CaCO3 out of the DIF solution and it forms a semi-impervious filter cake on the sand face of the reservoir. This desirable filter cake helps minimize excessive fluid losses into the reservoir hence limiting invasion and damage. It also contributes to the structural integrity of the open hole, keeping it stable prior to running of the screens. Depending on the weighting material used in the drilling of the reservoir drain-hole, the micro-emulsion breaker (MEB) can be designed to break down the filter cake and any undisolvedparticulates can be mobilized and water-wetted and can be then flowed during production or injection. The challenge is that depending on the lower completion configuration, it may take some time to get the wash pipe and work string out of the lower completion and close the formation isolation device. In some cases, it is possible for the formation isolation device to fail. If the Micro-emulsion Blend (MEB) is quick acting, any of these scenarios can lead to uncontrollable losses and serious difficulties in continuing the completion operation. This elucidates the need for a delayed acting MEB treatment. Lab tests and analysis involving the exact DIF /filter cake and various compositions of the MEB at downhole conditions to arrive at the required delay in action. It is critical to ensure that the delayed action does not result in reduced efficacy of the treatment. Hence, the MEB is not diluted for slow action but rather it is engineered combinatorially with a retarder and downhole mild acid generating microemulsion chemistry that gradually generates the necessary mild acid that will slowly dissolve the bridging materials (eg. calcium carbonate) in the mud withtime and allows the full strength of the MEB to take effect after the stipulated delay period. This paper will focus on the lab analysis and iterations to arrive at an optimal MEB blend.

A TEM study of the microstructure of avian eggshells

1992 ◽  
Vol 50 (2) ◽  
pp. 1102-1103
Author(s):  
S. Q. Xiao ◽  
S. Baden ◽  
A. H. Heuer
Keyword(s):  
Electron Microscope ◽  
Calcium Carbonate ◽  
Nucleation And Growth ◽  
Growth Mechanisms ◽  
Shell Surface ◽  
Thin Sections ◽  
Polycrystalline Metals ◽  
Transmission Electron ◽  
Nucleation And Growth Mechanisms

The avian eggshell is one of the most rapidly mineralizing biological systems known. In situ, 5g of calcium carbonate are crystallized in less than 20 hrs to fabricate the shell. Although there have been much work about the formation of eggshells, controversy about the nucleation and growth mechanisms of the calcite crystals, and their texture in the eggshell, still remain unclear. In this report the microstructure and microchemistry of avian eggshells have been analyzed using transmission electron microscope (TEM) and energy dispersive spectroscopy (EDS).Fresh white and dry brown eggshells were broken and fixed in Karnosky's fixative (kaltitanden) for 2 hrs, then rinsed in distilled H2O. Small speckles of the eggshells were embedded in Spurr medium and thin sections were made ultramicrotome.The crystalline part of eggshells are composed of many small plate-like calcite grains, whose plate normals are approximately parallel to the shell surface. The sizes of the grains are about 0.3×0.3×1 μm3 (Fig.l). These grains are not as closely packed as man-made polycrystalline metals and ceramics, and small gaps between adjacent grains are visible indicating the absence of conventional grain boundaries.

Extraction and identification of fillers and pigments from pyrolyzed rubber and tire samples

1996 ◽  
Vol 54 ◽  
pp. 174-175
Author(s):  
P. Sadhukhan ◽  
J. B. Zimmerman
Keyword(s):  
Zinc Oxide ◽  
Electron Microscope ◽  
Carbon Black ◽  
Natural Rubber ◽  
Transmission Electron Microscope ◽  
Rolling Resistance ◽  
Synthetic Polymers ◽  
Nitrogen Atmosphere ◽  
Transmission Electron ◽  
Curing Agents

Rubber stocks, specially tires, are composed of natural rubber and synthetic polymers and also of several compounding ingredients, such as carbon black, silica, zinc oxide etc. These are generally mixed and vulcanized with additional curing agents, mainly organic in nature, to achieve certain “designing properties” including wear, traction, rolling resistance and handling of tires. Considerable importance is, therefore, attached both by the manufacturers and their competitors to be able to extract, identify and characterize various types of fillers and pigments. Several analytical procedures have been in use to extract, preferentially, these fillers and pigments and subsequently identify and characterize them under a transmission electron microscope.Rubber stocks and tire sections are subjected to heat under nitrogen atmosphere to 550°C for one hour and then cooled under nitrogen to remove polymers, leaving behind carbon black, silica and zinc oxide and 650°C to eliminate carbon blacks, leaving only silica and zinc oxide.

Scaling risk assessment in a closed circuit recycled board mill by speciation methods

TAPPI Journal ◽  
2012 ◽  
Vol 11 (5) ◽  
pp. 53-61 ◽  
Author(s):  
PATRICK HUBER ◽  
SYLVIE NIVELON ◽  
PATRICE NORTIER
Keyword(s):  
Calcium Carbonate ◽  
Volatile Fatty Acids ◽  
Inorganic Carbon ◽  
Stability Index ◽  
Closed Circuit ◽  
Critical Problem ◽  
Local Scaling ◽  
Water Analyses ◽  
Closed Water ◽  
Speciation Calculation

Calcium carbonate scaling often is a critical problem for recycled board mills that have closed water circuits. The objective of this study was to determine local scaling risks throughout the production process. To predict scaling potential, we calculated several saturation indexes, based on speciation determined from detailed water analyses. Calculated scaling trends are in accordance with observed dissolution and precipitation of calcium carbonate in the process, when considering local aeration phenomena. The importance of volatile fatty acids (resulting from anaerobic bacterial activity) in calco-carbonic equilibriums is discussed, and taken into account in the speciation calculation. We also demonstrate the need to measure inorganic carbon instead of alkalinity in such conditions. This makes typical scaling indexes, such as the Ryznar Stability Index, irrelevant to predict scaling risk in closed circuit conditions; thus, it is necessary to use general speciation methods, as described in this paper.

A method for measuring the in-plane compressive strength and the compression behavior of coating layers

TAPPI Journal ◽  
2011 ◽  
Vol 10 (7) ◽  
pp. 29-34
Author(s):  
TEEMU PUHAKKA ◽  
ISKO KAJANTO ◽  
NINA PYKÄLÄINEN
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Calcium Carbonate ◽  
Coating Layer ◽  
Test Methods ◽  
Coating Films ◽  
Precipitated Calcium Carbonate ◽  
Coating Color ◽  
Mineral Coatings ◽  
Styrene Butadiene

Cracking at the fold is a quality defect sometimes observed in coated paper and board. Although tensile and compressive stresses occur during folding, test methods to measure the compressive strength of a coating have not been available. Our objective was to develop a method to measure the compressive strength of a coating layer and to investigate how different mineral coatings behave under compression. We used the short-span compressive strength test (SCT) to measure the in-plane compressive strength of a free coating layer. Unsupported free coating films were prepared for the measurements. Results indicate that the SCT method was suitable for measuring the in-plane compressive strength of a coating layer. Coating color formulations containing different kaolin and calcium carbonate minerals were used to study the effect of pigment particles’ shape on the compressive and tensile strengths of coatings. Latices having two different glass transition temperatures were used. Results showed that pigment particle shape influenced the strength of a coating layer. Platy clay gave better strength than spherical or needle-shaped carbonate pigments. Compressive and tensile strength decreased as a function of the amount of calcium carbonate in the coating color, particularly with precipitated calcium carbonate. We also assessed the influence of styrene-butadiene binder on the compressive strength of the coating layer, which increased with the binder level. The compressive strength of the coating layer was about three times the tensile strength.

The solubility of calcium carbonate  in green liquor handling systems

TAPPI Journal ◽  
2019 ◽  
Vol 18 (10) ◽  
pp. 595-602
Author(s):  
ALISHA GIGLIO ◽  
VLADIMIROS G. PAPANGELAKIS ◽  
HONGHI TRAN
Keyword(s):  
Calcium Carbonate ◽  
Systematic Study ◽  
Kraft Pulp ◽  
Thermodynamic Simulation ◽  
Solubility Data ◽  
Pulp Mills ◽  
Persistent Problem ◽  
Green Liquor ◽  
Kraft Pulp Mills ◽  
Salt Systems

The formation of hard calcite (CaCO3) scale in green liquor handling systems is a persistent problem in many kraft pulp mills. CaCO3 precipitates when its concentration in the green liquor exceeds its solubility. While the solubility of CaCO3 in water is well known, it is not so in the highly alkaline green liquor environment. A systematic study was conducted to determine the solubility of CaCO3 in green liquor as a function of temperature, total titratable alkali (TTA), causticity, and sulfidity. The results show that the solubility increases with increased temperature, increased TTA, decreased causticity, and decreased sulfidity. The new solubility data was incorporated into OLI (a thermodynamic simulation program for aqueous salt systems) to generate a series of CaCO3 solubility curves for various green liquor conditions. The results help explain how calcite scale forms in green liquor handling systems.

DC Partial Discharge Characteristics of Polyphenylenesulfide / Calcium Carbonate Composite Insulating Material

2017 ◽  
Vol 137 (9) ◽  
pp. 536-541
Author(s):  
Tomohiro Kawashima ◽  
Tomohiro Yamada ◽  
Yoshinobu Murakami ◽  
Masayuki Nagao ◽  
Sou Ozaki ◽  
...  
Keyword(s):  
Calcium Carbonate ◽  
Partial Discharge ◽  
Discharge Characteristics ◽  
Insulating Material
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