Raman Spectra and Structure of sp 2 Carbon-Based Materials: Electron–Phonon Coupling, Vibrational Dynamics and Raman Activity

2006 ◽  
pp. 381-403 ◽  
Author(s):  
Chiara Castiglioni ◽  
Fabrizia Negri ◽  
Matteo Tommasini ◽  
Eugenio Di Donato ◽  
Giuseppe Zerbi
Keyword(s):  
Raman Spectra ◽  
Phonon Coupling ◽  
Vibrational Dynamics ◽  
Electron Phonon Coupling ◽  
Carbon Based

scholarly journals Resonance and antiresonance in Raman scattering in GaSe and InSe crystals

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
M. Osiekowicz ◽  
D. Staszczuk ◽  
K. Olkowska-Pucko ◽  
Ł. Kipczak ◽  
M. Grzeszczyk ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Temperature Effect ◽  
Band Gap ◽  
Raman Spectra ◽  
Quantum Interference ◽  
Optical Band Gap ◽  
Phonon Coupling ◽  
Phonon Modes ◽  
Electron Phonon Coupling ◽  
Resonant Raman

AbstractThe temperature effect on the Raman scattering efficiency is investigated in $$\varepsilon$$ ε -GaSe and $$\gamma$$ γ -InSe crystals. We found that varying the temperature over a broad range from 5 to 350 K permits to achieve both the resonant conditions and the antiresonance behaviour in Raman scattering of the studied materials. The resonant conditions of Raman scattering are observed at about 270 K under the 1.96 eV excitation for GaSe due to the energy proximity of the optical band gap. In the case of InSe, the resonant Raman spectra are apparent at about 50 and 270 K under correspondingly the 2.41 eV and 2.54 eV excitations as a result of the energy proximity of the so-called B transition. Interestingly, the observed resonances for both materials are followed by an antiresonance behaviour noticeable at higher temperatures than the detected resonances. The significant variations of phonon-modes intensities can be explained in terms of electron-phonon coupling and quantum interference of contributions from different points of the Brillouin zone.

Raman Scattering and Superconductivity of Alkali-Fullerene Materials

1992 ◽  
Vol 270 ◽  
Author(s):  
J. S. Lannin ◽  
M. G. Mitch ◽  
W. Bacsa ◽  
S. J. Chase
Keyword(s):  
Thin Films ◽  
Raman Scattering ◽  
Raman Spectra ◽  
Solid Solutions ◽  
Thick Films ◽  
Ultrathin Film ◽  
Phonon Coupling ◽  
Electron Phonon Coupling ◽  
Scattering Measurements ◽  
Different Thickness

ABSTRACTRaman scattering measurements in alkali—fullerene alloys in ultrathin and thin films provide evidence for variations in electron—phonon coupling. For x — 3similar behavior of Rb3 C60 films of different thickness support substantial electron—phonon induced damping of specific Hg(i) modes derived from intramolecular modes of C60. In 400A thick films a reduction of induced scattering from Raman inactive C60 modes substantiates the importance ofHg(2), but not Hg(3) modes for phonon—mediated superconductivity. In contrast to RbxC60 and KxC60 ultrathin film solid solutions, similar Raman spectra for NaxC60 indicate substantially reduced coupling consistent with the absence of superconductivity in this system.

Raman spectra and electron-phonon coupling in poly(p-phenylene)

1985 ◽  
Vol 32 (6) ◽  
pp. 4235-4236 ◽  
Author(s):  
Ivan Boović ◽  
Dejan Raković
Keyword(s):  
Raman Spectra ◽  
Phonon Coupling ◽  
Electron Phonon Coupling

scholarly journals Physical origin of the buckling inCuO2: Electron-phonon coupling and Raman spectra

1999 ◽  
Vol 60 (13) ◽  
pp. 9836-9844 ◽  
Author(s):  
M. Opel ◽  
R. Hackl ◽  
T. P. Devereaux ◽  
A. Virosztek ◽  
A. Zawadowski ◽  
...  
Keyword(s):  
Raman Spectra ◽  
Phonon Coupling ◽  
Physical Origin ◽  
Electron Phonon Coupling

scholarly journals Raman spectra and electron-phonon coupling in disordered graphene with gate-tunable doping

2014 ◽  
Vol 116 (23) ◽  
pp. 233101 ◽  
Author(s):  
Isaac Childres ◽  
Luis A. Jauregui ◽  
Yong P. Chen
Keyword(s):  
Raman Spectra ◽  
Phonon Coupling ◽  
Electron Phonon Coupling

Observation of Core Phonon in Electron–Phonon Coupling in Au25 Nanoclusters

2021 ◽  
Vol 12 (6) ◽  
pp. 1690-1695
Author(s):  
Zhongyu Liu ◽  
Yingwei Li ◽  
Wonyong Shin ◽  
Rongchao Jin
Keyword(s):  
Phonon Coupling ◽  
Electron Phonon Coupling

scholarly journals Electron-phonon coupling in the magnetic Weyl semimetal ZrCo2Sn

2021 ◽  
Vol 103 (2) ◽  
Author(s):  
I.Yu. Sklyadneva ◽  
R. Heid ◽  
P. M. Echenique ◽  
E. V. Chulkov
Keyword(s):  
Phonon Coupling ◽  
Weyl Semimetal ◽  
Electron Phonon Coupling

scholarly journals Dielectric screening in perovskite photovoltaics

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Rui Su ◽  
Zhaojian Xu ◽  
Jiang Wu ◽  
Deying Luo ◽  
Qin Hu ◽  
...  
Keyword(s):  
Open Circuit Voltage ◽  
Low Voltage ◽  
Power Conversion ◽  
Surface Recombination ◽  
Open Circuit ◽  
Phonon Coupling ◽  
Electron Phonon Coupling ◽  
Dielectric Screening ◽  
Perovskite Photovoltaic ◽  
Reduced Surface

AbstractThe performance of perovskite photovoltaics is fundamentally impeded by the presence of undesirable defects that contribute to non-radiative losses within the devices. Although mitigating these losses has been extensively reported by numerous passivation strategies, a detailed understanding of loss origins within the devices remains elusive. Here, we demonstrate that the defect capturing probability estimated by the capture cross-section is decreased by varying the dielectric response, producing the dielectric screening effect in the perovskite. The resulting perovskites also show reduced surface recombination and a weaker electron-phonon coupling. All of these boost the power conversion efficiency to 22.3% for an inverted perovskite photovoltaic device with a high open-circuit voltage of 1.25 V and a low voltage deficit of 0.37 V (a bandgap ~1.62 eV). Our results provide not only an in-depth understanding of the carrier capture processes in perovskites, but also a promising pathway for realizing highly efficient devices via dielectric regulation.

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