Ti(n)O(2n-1) (n>=3): crystal structure of high-temperature phase (T > T(tr)) of Ti3O5

Author(s):  
Author(s):  
M. A. Zakharov ◽  
Sergej I. Troyanov ◽  
Erhard Kemnitz

AbstractThe crystal structure of the high temperature superprotonic phase of CsHSeO


RSC Advances ◽  
2014 ◽  
Vol 4 (25) ◽  
pp. 13195-13200 ◽  
Author(s):  
Xingwen Zhang ◽  
Hongwei Yu ◽  
Hongping Wu ◽  
Shilie Pan ◽  
Anqing Jiao ◽  
...  

A new high-temperature phase of Cd3B2O6 (β-Cd3B2O6) has been discovered and the phase transformation process between α- and β-Cd3B2O6 was investigated.


ChemInform ◽  
2007 ◽  
Vol 38 (17) ◽  
Author(s):  
Carsten L. Schmidt ◽  
Robert Dinnebier ◽  
Ulrich Wedig ◽  
Martin Jansen

2016 ◽  
Vol 55 (13) ◽  
pp. 6487-6495 ◽  
Author(s):  
Huan Yi ◽  
Li Wu ◽  
Liwei Wu ◽  
Lixia Zhao ◽  
Zhiguo Xia ◽  
...  

1990 ◽  
Vol 107 (1) ◽  
pp. 247-252 ◽  
Author(s):  
Kazuyuki Itoh ◽  
Kiyoshi Fujihara ◽  
Eiji Nakamura ◽  
Makoto Sakata

2013 ◽  
Vol 58 (1) ◽  
pp. 129-134 ◽  
Author(s):  
D. M. Novak ◽  
L. S. Smirnov ◽  
A. I. Kolesnikov ◽  
V. I. Voronin ◽  
I. F. Berger ◽  
...  

2000 ◽  
Vol 55 (6) ◽  
pp. 499-503 ◽  
Author(s):  
Kathrin Hofmann ◽  
Barbara Albert

The crystal structure of bis(triethylammonium)closo-decahydrodecaborate [bis(triethylammonium) decaboranate(10)], [(C2H5)3NH]2[B10H10], was determined and refined (space group Pmmn, no. 59, a = 989.7, b = 1333.7, c = 903.7 pm). The compound is a versatile starting material for many substances containing the [BioHio]2- entity and its derivatives. The closo-[B10H10]2- cluster is a bicapped square antiprism which is only slightly distorted. Its deviation from D4d symmetry is smaller than that of the B10 cages in every other compound containing this entity that have been structurally characterised. The presence of additional (N )H ---B3 interactions in form of multiple-centre bonds between the cations and the anions, which were postulated earlier and which should influence the cage symmetry, could not be confirmed. At 55 °C, the transition into a high temperature phase was investigated by X-ray powder diffraction. The high temperature phase crystallises in the tetragonal crystal system (a = 946.9, c = 1351.0 pm).


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