Boron (B) ionization energies of shallow energy levels, beta-rhombohedral boron

Author(s):  
1999 ◽  
Vol 64 (11) ◽  
pp. 673-680 ◽  
Author(s):  
Ivan Gutman ◽  
Viktorija Gineityte ◽  
Mirko Lepovic ◽  
Miroslav Petrovic

In the model for the ionization energies of the C2s-electrons in saturated hydrocarbons, put forward by Heilbronner et al., the energy levels are calculated as eigenvalues of the line graph of the hydrogen-filled molecular graph. It is now shown that in the case of alkanes, these energy levels are related to the Laplacian eigenvalues of the molecular graph. A few rules are formulated, relating these ionization energies with molecular structure.


1978 ◽  
Vol 33 (9) ◽  
pp. 1006-1012 ◽  
Author(s):  
B. Ruščić ◽  
B. Kovač ◽  
L. Klasinc ◽  
H. Güsten

The He(I) photoelectron spectra of fluorene and its analogues, biphenyl, dibenzofuran, carbazole, dibenzothiophene, and phenanthrene were measured and analyzed. The assignment of the π-electron ionizations using orbital interaction and symmetry arguments for the constituent parts of the molecules indicates that the energy levels of the fluorene analogues can be reproduced within a few percent of error. A close linear correlation between the π-ionization energies and the eigenvalues of the corresponding HMO-orbitals is obtained as well.


2006 ◽  
Vol 84 (2) ◽  
pp. 83-105 ◽  
Author(s):  
Donald C Morton ◽  
Qixue Wu ◽  
G WF Drake

We calculate very accurate ab initio ionization energies for both 4He I and 3He I as well as the isotope shifts for n = 1 to 10, L = 0 to 7 and combined these with precise laboratory data to produce a new table of levels for 4He I and the first table for 3He I. We adopted an experimental ionization potential of 5945 204 290 ± 33 MHz for 4He I and derived 5944 890 770 ± 33 MHz for 3He I. Additional calculations of the magnetic perturbations of 3He I provide the hyperfine levels, which compare favourably with the available measurements.PACS Nos.: 31.30.Gs, 31.30.Jv


2021 ◽  
Vol 2090 (1) ◽  
pp. 012039
Author(s):  
Nikolai Magnitskii

Abstract Previously, the basic laws and equations of electrodynamics, atomic nuclei, elementary particles theory and gravitation theory were derived from the equations of compressible oscillating ether. In this work, the theory of atomic structure for all chemical elements is constructed. A formula for the values of the energy levels of the electrons of an atom, which are the values of the energies of binding of electrons with the nucleus of an atom in the ground unexcited state, is derived from the equations of the ether. Based on experimental data on the ionization energies of atoms and ions, it is shown that the sequence of values of the energy levels of electrons has jumps, exactly corresponding to the periods of the table of chemical elements. It is concluded that it is precisely these jumps, and not quantum-mechanical rules, prohibitions and postulates that determine the periodicity of the properties of chemical elements. Ethereal correction of the table of chemical elements is presented which returns it to the form proposed by D.I. Mendeleev.


2002 ◽  
Vol 80 (11) ◽  
pp. 1255-1261 ◽  
Author(s):  
V G Pal'chikov ◽  
I Yu. Skobelev ◽  
A Ya. Faenov

The paper examines the 1/Z expansion method in calculating the energy levels, ionization energies, and wavelengths of the resonant Rydberg states 1snp 1P1 for atoms belonging to the helium isoelectronic sequence. The interactions of the bound electrons are treated as a perturbation that results in the electron–electron Breit interaction, relativistic corrections, and quantum electrodynamic (QED) contributions. By comparing the calculated wavelengths with a number of observed wavelengths, the QED contributions to the ground state are analyzed. PACS Nos.: 31.20Di, 31.20Tz, 31.30Jv, 31.50+W


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