DIELECTRIC EVIDENCE FOR ACETONE HYDRATE

1963 ◽  
Vol 41 (2) ◽  
pp. 264-273 ◽  
Author(s):  
G. J. Wilson ◽  
D. W. Davidson
Keyword(s):  
Activation Energy ◽  
Dielectric Constant ◽  
High Frequency ◽  
Water System ◽  
Low Frequency ◽  
Water Molecules ◽  
Incongruent Melting ◽  
High Frequency Dielectric Constant ◽  
System A ◽  
Acetone Water

The phase diagram of the acetone–water system shows that acetone hydrate decomposes at an incongruent melting point. The existence of acetone hydrate is confirmed by a study of the low-frequency dielectric properties of this system. A dispersion region, related to the relaxation of water molecules in the clathrate structure, is characterized by a "static" dielectric constant and an activation energy about half as large as the corresponding values for ice, and by a limiting high-frequency dielectric constant of about 7 at 200° K. The magnitude of the latter is attributed to orientation of acetone molecules within the larger cavities of the hydrate structure.

High-frequency dielectric constant of layered Fe, Co, and Ni dihalides

1984 ◽  
Vol 29 (6) ◽  
pp. 3617-3622 ◽  
Author(s):  
I. Pollini ◽  
G. Benedek ◽  
J. Thomas
Keyword(s):  
Dielectric Constant ◽  
High Frequency ◽  
High Frequency Dielectric Constant

Pool-Frenkel effect and high frequency dielectric constant determination of semiconducting P2O5-Li2MoO4-Li2O and P2O5-Na2MoO4-Na2O bulk glasses

Open Physics ◽  
2008 ◽  
Vol 6 (2) ◽  
Author(s):  
Dariush Souri ◽  
Mohammad Elahi ◽  
Mohammad Yazdanpanah
Keyword(s):  
Dielectric Constant ◽  
Electric Field ◽  
Electric Fields ◽  
Threshold Voltage ◽  
High Frequency ◽  
Strong Electric Field ◽  
Nonlinear Effects ◽  
High Frequency Dielectric Constant ◽  
Conduction State ◽  
Current Voltage

AbstractThe ternary 70P2O5-10Li2MoO4-20Li2O and 70P2O5-10Na2MoO4-20Na2O glasses, prepared by the press-melt quenching technique, were studied at temperatures between 298 and 418 K for their high dc electric field properties. For the above purpose, the effect of a strong electric field on the dc conduction of these amorphous bulk samples was investigated using the gap-type electrode configuration. At low electric fields, the current-voltage (I — V) characteristics have a linear shape, while at high electric fields (> 103 V/cm), bulk samples show nonlinear effects (nonohmic conduction). Current-voltage curves show increasing departure from Ohm’s law with increasing current density, leading to critical phenomena at a maximum voltage (threshold voltage), known as switching (switch from a low-conduction state to a higher-conduction state at threshold voltage). The Pool-Frenkel high-field effect was observed at electrical fields of about 103–104 V/cm; then the lowering factor of the potential barrier, the high frequency dielectric constant, and the refractive index of these glasses were determined.

Sign in / Sign up

Export Citation Format

Share Document