2.1.3.4 Defect-solute interaction

2005 ◽  
pp. 98-100
Author(s):  
P. Ehrhart
Keyword(s):  
Solute Interaction

Studies on Cerium Electrochemistry in High Temperature Ionic Liquids

2018 ◽  
Vol 69 (1) ◽  
pp. 112-115
Author(s):  
Ana Maria Popescu ◽  
Virgil Constantin
Keyword(s):  
Molten Salts ◽  
Electrochemical Techniques ◽  
Active Species ◽  
Single Step ◽  
Cathodic Process ◽  
Molybdenum Electrode ◽  
Solute Interaction ◽  
Ohmic Drop ◽  
State Potential ◽  
Direct Discharge

The cathodic behavior of Ce3+ ions in LiF-NaF-BaF2, LiF-NaF-NaCl and NaCl-KCl molten salts at 730� C has been studied using different electrochemical techniques. The decomposition potential (Ed) and the cathodic overvoltage were determined by introducing NaCeF4 as electrochemical active species using steady-state potential-current curves recorded under galvanostatic conditions. The values of |Ed| were 1.85 V in LiF-NaF-BaF2, 2.114 V in LiF-NaF-NaCl and 2.538 V in NaCl-KCl, respectively. It was also found that the ohmic drop potential in melt is not dependent on NaCeF4 concentration and it rises as the current intensity increases. The Tafel slopes and other kinetic parameters were calculated on the assumption that the cathodic process consisted of direct discharge of Ce3+, with no solvent-solute interaction. In order to elucidate the mechanisn of cathodic process the cyclic voltammetry technique was finally used. From the evolution of the voltammograms we conclude that the electrochemical reduction of Ce3+ ion is actually a reversible process on the molybdenum electrode and cathodic reduction of Ce3+ takes place in one single step involving three electron exchange. Our study adds to the accumulating data and confirms available results of electrodeposition of metalic cerium from molten salts using NaCeF4 as solute.

Room-temperature NaI/H2O compression icing: solute–solute interactions

2017 ◽  
Vol 19 (39) ◽  
pp. 26645-26650 ◽  
Author(s):  
Qingxin Zeng ◽  
Chuang Yao ◽  
Kai Wang ◽  
Chang Q. Sun ◽  
Bo Zou
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Bond Energy ◽  
Room Temperature ◽  
Solute Concentration ◽  
Solute Interaction ◽  
Solute Interactions

H–O bond energy governs the PCx for Na/H2O liquid–VI–VII phase transition. Solute concentration affects the path of phase transitions differently with the solute type. Solute–solute interaction lessens the PC2 sensitivity to compression. The PC1 goes along the liquid–VI boundary till the triple phase joint.

Solution hardening in body-centered cubic quaternary alloys interpreted using Suzuki's kink-solute interaction model

2019 ◽  
Vol 165 ◽  
pp. 103-106 ◽  
Author(s):  
S.I. Rao ◽  
E. Antillon ◽  
C. Woodward ◽  
B. Akdim ◽  
T.A. Parthasarathy ◽  
...  
Keyword(s):  
Interaction Model ◽  
Body Centered Cubic ◽  
Quaternary Alloys ◽  
Solution Hardening ◽  
Solute Interaction

Retention of phenols and carboxylic acids by nanofiltration/reverse osmosis membranes: sieving and membrane-solute interaction effects

Desalination ◽  
2006 ◽  
Vol 200 (1-3) ◽  
pp. 731-733 ◽  
Author(s):  
Jesús M. Arsuaga ◽  
María J. López-Muñoz ◽  
Arcadio Sotto ◽  
Gilberto del Rosario
Keyword(s):  
Reverse Osmosis ◽  
Carboxylic Acids ◽  
Interaction Effects ◽  
Solute Interaction ◽  
Reverse Osmosis Membranes
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