scholarly journals Silver Nitrate/Oligo(ethylene Oxide) Surfactant/Mesoporous Silica Nanocomposite Films and Monoliths

2001 ◽  
Vol 238 (1) ◽  
pp. 203-207 ◽  
Author(s):  
Olga Samarskaya ◽  
Ömer Dag
2018 ◽  
Vol 82 ◽  
pp. 106-115 ◽  
Author(s):  
Iñigo Fernandez-Bats ◽  
Prospero Di Pierro ◽  
Reynaldo Villalonga-Santana ◽  
Blanca Garcia-Almendarez ◽  
Raffaele Porta

2003 ◽  
Vol 68 (10) ◽  
pp. 2019-2031 ◽  
Author(s):  
Markéta Zukalová ◽  
Jiří Rathouský ◽  
Arnošt Zukal

A new procedure has been developed, which is based on homogeneous precipitation of organized mesoporous silica from an aqueous solution of sodium metasilicate and a nonionic poly(ethylene oxide) surfactant serving as a structure-directing agent. The decrease in pH, which induces the polycondensation of silica, is achieved by hydrolysis of ethyl acetate. Owing to the complexation of Na+ cations by poly(ethylene oxide) segments, assembling of the mesostructure appears to occur under electrostatic control by the S0Na+I- pathway, where S0 and I- are surfactant and inorganic species, respectively. As the complexation of Na+ cations causes extended conformation of poly(ethylene oxide) segments, the pore size and pore volume of organized mesoporous silica increase in comparison with materials prepared under neutral or acidic conditions. The assembling of particles can be fully separated from their solidification, which results in the formation of highly regular spherical particles of mesoporous silica.


2014 ◽  
Vol 131 (23) ◽  
pp. n/a-n/a ◽  
Author(s):  
Xiangyuan Ye ◽  
Jinqing Wang ◽  
Ye Xu ◽  
Lengyuan Niu ◽  
Zengjie Fan ◽  
...  

2019 ◽  
Vol 43 (39) ◽  
pp. 15777-15784 ◽  
Author(s):  
Bo Peng ◽  
Yu-Xin Zong ◽  
Meng-Zhen Nie ◽  
Bing-Qian Shan ◽  
Tai-Qun Yang ◽  
...  

A unique ethylene oxide (EO) layer coated core–shell structured spherical micelle was used as a building unit to synthesize dendritic mesoporous silica nanospheres (DMSNs) by a dual-templating approach.


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