Dynamic viscosities of the binary mixtures (methyl acetate or methanol + 2-methyl-2-butanol) and the ternary mixtures (methyl acetate + methanol+ 2-propanol, or 2-butanol, or 2-methyl-2-butanol) atT= 298.15 K

2000 ◽  
Vol 32 (4) ◽  
pp. 551-565 ◽  
Author(s):  
J. Canosa ◽  
A. Rodríguez ◽  
J. Tojo
Keyword(s):  
Binary Mixtures ◽  
Methyl Acetate ◽  
Ternary Mixtures

Catalytic hydrogenation of binary and ternary mixtures of unsaturated substances in the liquid phase on platinum

1979 ◽  
Vol 44 (8) ◽  
pp. 2378-2383 ◽  
Author(s):  
Libor Červený ◽  
Radka Junová ◽  
Vlastimil Růžička
Keyword(s):  
Liquid Phase ◽  
Binary Mixtures ◽  
Silica Gel ◽  
Catalytic Hydrogenation ◽  
Ternary Systems ◽  
Ternary Mixtures ◽  
Unsaturated Alcohol ◽  
Solvent Concentration ◽  
Binary And Ternary Mixtures ◽  
Hydrogenation Selectivity

Hydrogenation of olefinic substrates in binary and ternary mixtures using 5% Pt on silica gel as the catalyst was studied in normal conditions in the liquid phase with methanol or cyclohexane or in solvent-free systems. The effect of the solvent concentration on the selectivity of hydrogenation of the unsaturated alcohol-olefin binary mixtures was investigated. In ternary systems of unsaturated substrates, the effect of each of the substrates on the selectivity of hydrogenation of the remaining two substances was examined. Another system was found in which a jump change of the hydrogenation selectivity occurred on the vanishing of the fastest reacting substance.

Solvation of ions by dipolar aprotic solvents and water. A CNDO/2 study

1985 ◽  
Vol 50 (11) ◽  
pp. 2493-2508 ◽  
Author(s):  
Petr Kyselka ◽  
Zdeněk Havlas ◽  
Ivo Sláma
Keyword(s):  
Binary Mixtures ◽  
Quantum Chemical ◽  
Chemical Method ◽  
Molecular Structures ◽  
Dimethyl Sulphoxide ◽  
Ternary Mixtures ◽  
Aprotic Solvents ◽  
Quantum Chemical Method ◽  
Solvation Of Ions ◽  
Dipolar Aprotic Solvents

Solvation of Li+, Be2+, Na+, Mg2+, and Al3+ ions has been studied in binary mixtures with dimethyl sulphoxide, dimethylformamide, acetonitrile and water, and in ternary mixtures of the organic solvents with water. The CNDO/2 quantum chemical method was used to calculate the energies of solvation, molecular structures and charge distributions for the complexes acetonitrile...ion (1:1, 2:1, 4:1), dimethyl sulphoxide...ion (1:1), dimethylformamide...ion (1:1), and acetonitrile (dimethyl sulphoxide, dimethylformamide)...ion...water (1:1:1).

Phase equilibria of binary mixtures containing methyl acetate, water, methanol or ethanol at 101.3 kPa

2011 ◽  
Vol 49 (1) ◽  
pp. 52-71 ◽  
Author(s):  
V.H. Álvarez ◽  
S. Mattedi ◽  
M. Iglesias ◽  
R. Gonzalez-Olmos ◽  
J.M. Resa
Keyword(s):  
Phase Equilibria ◽  
Binary Mixtures ◽  
Methyl Acetate

Enthalpies of Mixing of Multicomponent Alkane Mixtures

1988 ◽  
Vol 41 (11) ◽  
pp. 1763 ◽  
Author(s):  
TJ Brady ◽  
S Weiguo ◽  
AG Williamson
Keyword(s):  
Chain Length ◽  
Binary Mixtures ◽  
Ternary Mixtures ◽  
Enthalpies Of Mixing

Enthalpies of mixing are reported for ternary n-alkane mixtures prepared from binary mixtures with large chain-length differences and at temperatures where the enthalpies of mixing of simple binary mixtures show changes of sign. In neither case does the behaviour of the ternary mixtures deviate significantly from that of the congruent binaries.

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