Aqueous solutions of the alkaline-earth metal chlorides at elevated temperatures. Isopiestic molalities and thermodynamic properties

1996 ◽  
Vol 28 (12) ◽  
pp. 1325-1358 ◽  
Author(s):  
H.F. Holmes ◽  
R.E. Mesmer
Keyword(s):  
Thermodynamic Properties ◽  
Aqueous Solutions ◽  
Alkaline Earth ◽  
Elevated Temperatures ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Chlorides

scholarly journals Die Kristallstrukturen von Strontium- und Bariumhexacyanoferrat(III)-Hexamethylentetramin-Hydraten. Strukturmodell für Additionsverbindungen der Alkali- und Erdalkalimetallhexacyanoferrate mit Hexamethylentetramin / The Crystal Structures of Hydrates of Strontium and Barium Hexacyanoferrate(III) with Hexamethylenetetramine. Structural Model for Adducts of the Hexacyanoferrates of Alkaline and Alkaline Earth Metals with Hexamethylenetetramine

1989 ◽  
Vol 44 (5) ◽  
pp. 519-525 ◽  
Author(s):  
Hans-Jürgen Meyer ◽  
Joachim Pickardt
Keyword(s):  
Aqueous Solutions ◽  
Crystal Structures ◽  
General Formula ◽  
Alkaline Earth ◽  
Structural Model ◽  
Earth Metal ◽  
Alkaline Earth Metals ◽  
Alkaline Earth Metal ◽  
Monoclinic Space Group ◽  
Space Group

By reaction of methanolic solutions of hexamethylenetetramine with aqueous solutions of hexacyanoferrates(III) of strontium and barium resp., crystals of the compounds were obtained. Sr3[Fe(CN)6]2 · 3 C6H12N4 · 18 H2O, tetragonal, space group P42/nmc, Z = 4, a = 1931.8(4), c = 1579.9(4) pm, 1358 reflections. R = 0.066. Ba3[Fe(CN)6]2 · 2 C6H12N4 · 11 Η2Ο. monoclinic. space group P21/n, Ζ = 2, a = 1148.0(4), b = 1369.7(4), c = 1584.5(4) pm, γ = 95.79(3)°, 2583 reflections, R = 0.057. The crystal structures of these adducts are compared with those of other hexamethylenetetramine adducts of alkaline and alkaline earth metal hexacyanoferrates of the general formula M,[Fe(CN)6]y · zC6H12N4 · vH2O recently investigated by us. A structural model for the adducts is presented.

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