Comment on “Dehydrogenation of Cyclohexanol on Copper Containing Catalysts. I. The Influence of the Oxidation State of Copper on the Activity of Copper Sites” by V. Z. Fridman and A. A. Davydov (J. Catal.195, 20 (2000))

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AbstractSmall copper-oxide cluster cations, namely, CuOAr+ and Cu2O2+, are studied by mass spectrometry and X-ray absorption spectroscopy (XAS) to investigate the oxidation state of copper atoms. The XAS in Cu L3-region revealed that the oxidation number of Cu is almost +2.1 and +2.3 for CuOAr+ and Cu2O2+, respectively, which are consistent with the natural charges obtained by quantum chemical calculation. It was also revealed that the binding energy of Ar to CuO+ is unexpectedly high to form CuOAr+ dominantly as a result of a significant amount of charge transfer to the Ar atom.


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