Study of Cesium or Cesium-Transition Metal-Substituted Keggin-Type Phosphomolybdic Acid as Isobutane Oxidation Catalysts

1999 ◽  
Vol 181 (1) ◽  
pp. 80-90 ◽  
Author(s):  
M. Langpape ◽  
J.M.M. Millet ◽  
U.S. Ozkan ◽  
M. Boudeulle
Keyword(s):  
Transition Metal ◽  
Phosphomolybdic Acid ◽  
Oxidation Catalysts ◽  
Keggin Type

scholarly journals Speciation of Transition-Metal-Substituted Keggin-Type Silicotungstates Affected by the Co-crystallization Conditions with Proteinase K

2021 ◽  
Author(s):  
Joscha Breibeck ◽  
Elias Tanuhadi ◽  
Nadiia I. Gumerova ◽  
Gerald Giester ◽  
Alexander Prado-Roller ◽  
...  
Keyword(s):  
Transition Metal ◽  
Proteinase K ◽  
Keggin Type ◽  
Crystallization Conditions

Electrochemical tuning of olivine-type lithium transition-metal phosphates as efficient water oxidation catalysts

2015 ◽  
Vol 8 (6) ◽  
pp. 1719-1724 ◽  
Author(s):  
Yayuan Liu ◽  
Haotian Wang ◽  
Dingchang Lin ◽  
Chong Liu ◽  
Po-Chun Hsu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Oxygen Evolution ◽  
Water Oxidation ◽  
Oxidation Catalysts ◽  
Metal Phosphates ◽  
Electrochemical Tuning

Electrochemical lithium tuning of olivine-type lithium transition metal phosphates results in greatly enhanced oxygen evolution catalytic activity.

Activation of Oxidation Catalysts by Solvation

1996 ◽  
Vol 454 ◽  
Author(s):  
Annette D. Eddowes ◽  
Dana Stallings ◽  
Caprice L. Hightower ◽  
Susan A. Jansen
Keyword(s):  
Photochemical Reactions ◽  
Oxidation Reactions ◽  
Mechanistic Studies ◽  
Oxidation Catalysts ◽  
Keggin Ion ◽  
Solution State ◽  
Keggin Type ◽  
Activation Of Oxidation

AbstractThe versatility of heteropolyanions implies many different uses for Keggin type catalysts. However, new roles for these catalysts must first be preceeded by further understanding of the mechanisms by which they operate. It has been observed that the solvation and/or complexation of heteropolyanions promotes or limits activity in homogeneous chemistry. For this reason the solution state and the solvation characteristics of the catalyst were studied in oxidation and photochemical reactions. Simple oxidation reactions provide a system by which the solution state of the catalyst can be studied. The catalyst used for these mechanistic studies is the Keggin ion (PMo10V2O40)−5.

Mechanistic insights into the activation process in electrocatalytic ethanol oxidation by phosphomolybdic acid-stabilised palladium(0) nanoparticles (PdNPs@PMo12)

RSC Advances ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 5359-5366 ◽  
Author(s):  
Sara Khadempir ◽  
Ali Ahmadpour ◽  
Mohammad Taghi Hamed Mosavian ◽  
Narges Ashraf ◽  
Fatemeh F. Bamoharram ◽  
...  
Keyword(s):  
Ethanol Oxidation ◽  
Phosphomolybdic Acid ◽  
Activation Process ◽  
Keggin Type

A Keggin type polyoxometalate (POM), phosphomolybdic acid (PMo12), has been employed to encapsulate and stabilise pseudo-spherical Pd(0) nanoparticles (PdNPs).

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