Electrochemical Promotion of the Catalytic Reduction of NO by CO on Palladium

1997 ◽  
Vol 170 (2) ◽  
pp. 275-285 ◽  
Author(s):  
M. Marwood ◽  
C.G. Vayenas
Author(s):  
Anja Z. Friedberg ◽  
Kent Kammer Hansen

<p class="PaperAbstract"><span lang="EN-US">The catalytic electrochemical reduction of NO with propene was investigated on La<sub>0.85</sub>Sr<sub>0.15</sub>MnO<sub>3+d</sub>/Ce<sub>0.9</sub>Gd<sub>0.1</sub>O<sub>1.95</sub> symmetrical cells. The electrodes were infiltrated with BaO and Pt. The cells were catalytically active towards the selective catalytic reduction of NO<sub>x</sub> with propene, but BaO infiltration lowered the NO conversion, probably because of active-site blocking on La<sub>0.85</sub>Sr<sub>0.15</sub>MnO<sub>3+d</sub>. Pt infiltration enhanced the reduction of NOx with propene. When a voltage was applied to the cell with BaO infiltrated electrodes, the NO conversion increased in absence and presence of propene in the feed gas and presence of 10</span><span lang="EN-US">% O<sub>2</sub>. The addition of propene into the feed gas did not enhance the conversion of NO when the electrodes were infiltrated with BaO. When platinum was co-infiltrated with BaO, the catalytic activity towards the reduction of NO with propene was enhanced. However, almost no effect was observed when a voltage was applied. Additionally, when the cells were infiltrated with Pt, an electrochemical promotion was observed with respect to CO<sub>2</sub> formation.</span></p>


2012 ◽  
Vol 27 (5) ◽  
pp. 495-500 ◽  
Author(s):  
Da-Wang WU ◽  
Qiu-Lin ZHANG ◽  
Tao LIN ◽  
Mao-Chu GONG ◽  
Yao-Qiang CHEN

2019 ◽  
Vol 9 (3) ◽  
pp. 718-730 ◽  
Author(s):  
Jian-Wen Shi ◽  
Yao Wang ◽  
Ruibin Duan ◽  
Chen Gao ◽  
Baorui Wang ◽  
...  

Non-manganese-based metal oxides are promising catalysts for the NH3-SCR (selective catalytic reduction) of NOx at low temperatures.


Author(s):  
Pei Zhao ◽  
Bundet Boekfa ◽  
Ken-ichi Shimizu ◽  
Masaru Ogura ◽  
Masahiro Ehara

Density functional theory calculations have been applied to study the selectivity caused by the cage size during the selective catalytic reduction of NO by NH3 over the Cu-exchanged zeolites with cha, gme, and aft cages.


Author(s):  
Liping Sheng ◽  
Songda Li ◽  
Zhaoxia Ma ◽  
Fei Wang ◽  
Hu He ◽  
...  

O2 greatly affected the pathway for NO reduction over the Pd/CeO2 catalyst and resulted in a temperature-dependent NH3-SCR performance and formation of N2O.


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