Methylene Blue Photosensitized Oxidation of Cysteine Sulfinic Acid and Other Sulfinates: The Involvement of Singlet Oxygen and the Azide Paradox

2000 ◽  
Vol 270 (3) ◽  
pp. 782-786 ◽  
Author(s):  
Laura Pecci ◽  
Mara Costa ◽  
Antonio Antonucci ◽  
Gabriella Montefoschi ◽  
Doriano Cavallini
Keyword(s):  
Methylene Blue ◽  
Singlet Oxygen ◽  
Sulfinic Acid ◽  
Cysteine Sulfinic Acid ◽  
Photosensitized Oxidation

REACTIVITIES IN PHOTOSENSITIZED OLEFIN OXIDATIONS

1965 ◽  
Vol 43 (8) ◽  
pp. 2265-2270 ◽  
Author(s):  
Karl R. Kopecky ◽  
Hans J. Reich
Keyword(s):  
Methylene Blue ◽  
Singlet Oxygen ◽  
Reactive Intermediate ◽  
Photosensitized Oxidation ◽  
Photo Oxidation ◽  
Oxidation Of Olefins

The rate of the methylene blue photosensitized oxidation of olefins increases in the order: 1-nonene < 4-methylcyclohexene < cyclohexene < 2,3-dimethyl-1-butene < 2-hexene < cyclopentene < 1-methylcyclohexene < 2,3-dimethylcyclohexene < 1-methylcyclopentene < 1,2-dimethylcyclohexene < 2,3-dimethyl-2-butene. The last compound is oxidized 5 500 times as fast as cyclohexene. Comparison of this reactivity sequence with those obtained in other reactions confirms that the reactive intermediate in the photosensitized oxidations is electrophilic. The relative rates (kA/kB) of photo-oxidation of 1-methylcyclopentene (A) and of 1-methylcyclohexene (B) are 10 and do not vary significantly with five different sensitizers. Thus the same reactive intermediate, presumably singlet oxygen, is formed using each of the five sensitizers.

Singlet-Oxygen Sensitization by Associates of Methylene Blue with Colloidal Ag2S Quantum Dots Passivated by Thioglycolic Acid

2018 ◽  
Vol 125 (1) ◽  
pp. 107-112 ◽  
Author(s):  
O. V. Ovchinnikov ◽  
M. S. Smirnov ◽  
T. S. Kondratenko ◽  
A. S. Perepelitsa ◽  
I. G. Grevtseva ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Quantum Dots ◽  
Singlet Oxygen ◽  
Thioglycolic Acid ◽  
Ag2s Quantum Dots

scholarly journals MOLECULAR MECHANISM OF THE REDUCTION OF CYSTEINE SULFINIC ACID OF PEROXIREDOXIN TO CYSTEINE BY MAMMALIAN SULFIREDOXIN

2006 ◽  
Vol 20 (4) ◽  
Author(s):  
Sue Goo Rhee ◽  
Woojin Jeong ◽  
Sung Jun Park ◽  
Tong‐Shin Chang ◽  
Duck Yeon Lee
Keyword(s):  
Molecular Mechanism ◽  
Sulfinic Acid ◽  
Cysteine Sulfinic Acid

scholarly journals The generation of the singlet oxygen in methylene blue solution and its effect to the tissue

1987 ◽  
Vol 8 (3) ◽  
pp. 59-60
Author(s):  
Ichiro TANABE ◽  
Hiroshi FUJIMURA ◽  
Tatsuo OTANI ◽  
Yukinori OKAZAKI ◽  
Tadayoshi TAKEMOTO ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Singlet Oxygen ◽  
Methylene Blue Solution ◽  
Blue Solution

Microassay of cysteine sulfinic acid by an enzymatic cycling method

1980 ◽  
Vol 101 (2) ◽  
pp. 288-293 ◽  
Author(s):  
Akemichi Basa ◽  
Satoru Yamagami ◽  
Hiroyuki Mizuo ◽  
Heitaroh Iwata
Keyword(s):  
Sulfinic Acid ◽  
Cysteine Sulfinic Acid ◽  
Enzymatic Cycling

scholarly journals Chemical proteomics reveals new targets of cysteine sulfinic acid reductase

2018 ◽  
Vol 14 (11) ◽  
pp. 995-1004 ◽  
Author(s):  
Salma Akter ◽  
Ling Fu ◽  
Youngeun Jung ◽  
Mauro Lo Conte ◽  
J. Reed Lawson ◽  
...  
Keyword(s):  
Sulfinic Acid ◽  
Cysteine Sulfinic Acid ◽  
Chemical Proteomics ◽  
New Targets
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