Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes

2017 ◽  
Vol 643 (14) ◽  
pp. 895-902 ◽  
Author(s):  
Igor D. Strelnik ◽  
Elvira I. Musina ◽  
Svetlana N. Ignatieva ◽  
Anna S. Balueva ◽  
Tatiana P. Gerasimova ◽  
...  
Keyword(s):  
Bridging Ligands ◽  
Dinuclear Copper

Synthesis and Properties of Dinuclear Copper(II) Complexes Containing Dinucleating Ligands with Imidazole Nitrogen and Two Exogenous Bridging Ligands

1994 ◽  
Vol 67 (9) ◽  
pp. 2586-2589 ◽  
Author(s):  
Yasuo Nakao ◽  
Makoto Oonishi ◽  
Tomoko Uzu ◽  
Hiroko Kashihara ◽  
Shinnichiro Suzuki ◽  
...  
Keyword(s):  
Bridging Ligands ◽  
Dinuclear Copper ◽  
Dinucleating Ligands

Dinuclear copper(II) complexes containing 6-(benzylamino)purines as bridging ligands: Synthesis, characterization, and in vitro and in vivo antioxidant activities

2009 ◽  
Vol 103 (3) ◽  
pp. 432-440 ◽  
Author(s):  
Pavel Štarha ◽  
Zdeněk Trávníček ◽  
Radovan Herchel ◽  
Igor Popa ◽  
Pavel Suchý ◽  
...  
Keyword(s):  
Antioxidant Activities ◽  
Bridging Ligands ◽  
Dinuclear Copper

Mono- and dinuclear copper(II) complexes with meta-phenylene-bridging ligands: Synthesis, structure and magnetic properties

Polyhedron ◽  
2009 ◽  
Vol 28 (9-10) ◽  
pp. 1982-1990 ◽  
Author(s):  
Daniel Plaul ◽  
Daniel Geibig ◽  
Helmar Görls ◽  
Winfried Plass
Keyword(s):  
Magnetic Properties ◽  
Bridging Ligands ◽  
Dinuclear Copper

Structure and Magnetism of Dinuclear Copper(II) Metallacyclophanes with Oligoacenebis(oxamate) Bridging Ligands:  Theoretical Predictions on Wirelike Magnetic Coupling

2008 ◽  
Vol 130 (2) ◽  
pp. 576-585 ◽  
Author(s):  
Emilio Pardo ◽  
Rosa Carrasco ◽  
Rafael Ruiz-García ◽  
Miguel Julve ◽  
Francesc Lloret ◽  
...  
Keyword(s):  
Magnetic Coupling ◽  
Bridging Ligands ◽  
Dinuclear Copper ◽  
Theoretical Predictions

Long-distance magnetic coupling in dinuclear copper(II) complexes with oligo-para-phenylenediamine bridging ligands

2010 ◽  
Vol 363 (8) ◽  
pp. 1666-1678 ◽  
Author(s):  
Jesús Ferrando-Soria ◽  
María Castellano ◽  
Consuelo Yuste ◽  
Francesc Lloret ◽  
Miguel Julve ◽  
...  
Keyword(s):  
Magnetic Coupling ◽  
Long Distance ◽  
Bridging Ligands ◽  
Dinuclear Copper

[1,2,4]Triazolo[4,3-a]Pyridines as Bridging Ligands—Magnetism of Azole-Bridged Dinuclear Copper(II) Complexes Influenced by the Trigonal Distortion Parameter τ

2014 ◽  
Vol 53 (11) ◽  
pp. 5546-5555 ◽  
Author(s):  
Dominic Kaase ◽  
Carla Gotzmann ◽  
Stephan Rein ◽  
Yanhua Lan ◽  
Sylwia Kacprzak ◽  
...  
Keyword(s):  
Distortion Parameter ◽  
Bridging Ligands ◽  
Dinuclear Copper ◽  
Trigonal Distortion

Dinuclear copper complexes with cyanamide derivatives as bridging ligands

Polyhedron ◽  
2008 ◽  
Vol 27 (6) ◽  
pp. 1809-1817 ◽  
Author(s):  
Hassan Hadadzadeh ◽  
Ali R. Rezvani ◽  
Hadi Esfandiari
Keyword(s):  
Copper Complexes ◽  
Bridging Ligands ◽  
Dinuclear Copper

Topological control of the spin coupling in dinuclear copper(II) complexes with meta- and para-phenylenediamine bridging ligands

2010 ◽  
Vol 363 (9) ◽  
pp. 1984-1994 ◽  
Author(s):  
Consuelo Yuste ◽  
Jesús Ferrando-Soria ◽  
Danielle Cangussu ◽  
Oscar Fabelo ◽  
Catalina Ruiz-Pérez ◽  
...  
Keyword(s):  
Spin Coupling ◽  
Bridging Ligands ◽  
Dinuclear Copper

Tuning the Redox Activity of Metal−Organic Frameworks for Enhanced, Selective O2 Binding

2019 ◽  
Author(s):  
Andrew Rosen ◽  
M. Rasel Mian ◽  
Timur Islamoglu ◽  
Haoyuan Chen ◽  
Omar Farha ◽  
...  
Keyword(s):  
Density Functional ◽  
Metal Organic Frameworks ◽  
Redox Activity ◽  
Screening Methods ◽  
Bridging Ligands ◽  
Metal Centers ◽  
Computational Screening ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Unsaturated Metal Sites

<p>Metal−organic frameworks (MOFs) with coordinatively unsaturated metal sites are appealing as adsorbent materials due to their tunable functionality and ability to selectively bind small molecules. Through the use of computational screening methods based on periodic density functional theory, we investigate O<sub>2</sub> and N<sub>2</sub> adsorption at the coordinatively unsaturated metal sites of several MOF families. A variety of design handles are identified that can be used to modify the redox activity of the metal centers, including changing the functionalization of the linkers (replacing oxido donors with sulfido donors), anion exchange of bridging ligands (considering μ-Br<sup>-</sup>, μ-Cl<sup>-</sup>, μ-F<sup>-</sup>, μ-SH<sup>-</sup>, or μ-OH<sup>-</sup> groups), and altering the formal oxidation state of the metal. As a result, we show that it is possible to tune the O<sub>2</sub> affinity at the open metal sites of MOFs for applications involving the strong and/or selective binding of O<sub>2</sub>. In contrast with O<sub>2</sub> adsorption, N<sub>2</sub> adsorption at open metal sites is predicted to be relatively weak across the MOF dataset, with the exception of MOFs containing synthetically elusive V<sup>2+</sup> open metal sites. As one example from the screening study, we predict that exchanging the μ-Cl<sup>-</sup> ligands of M<sub>2</sub>Cl<sub>2</sub>(BBTA) (H<sub>2</sub>BBTA = 1<i>H</i>,5<i>H</i>-benzo(1,2-d:4,5-d′)bistriazole) with μ-OH<sup>-</sup> groups would significantly enhance the strength of O<sub>2</sub> adsorption at the open metal sites without a corresponding increase in the N<sub>2</sub> affinity. Experimental investigation of Co<sub>2</sub>Cl<sub>2</sub>(BBTA) and Co<sub>2</sub>(OH)<sub>2</sub>(BBTA) confirms that the former exhibits only weak physisorption, whereas the latter is capable of chemisorbing O<sub>2</sub> at room temperature. The chemisorption behavior is attributed to the greater electron-donating character of the μ-OH<sup>-</sup><sub> </sub>ligands and the presence of H-bonding interactions between the μ-OH<sup>-</sup> bridging ligands and the O<sub>2</sub> adsorbate.</p>

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