Effect of Dicarboxylato Ligands on the Self-Assembly of Two Cadmium(II) Coordination Polymers Containing Multidentate N-donor Ligands

2015 ◽  
Vol 641 (6) ◽  
pp. 1135-1140 ◽  
Author(s):  
Wei-Qiu Kan ◽  
Shi-Zheng Wen ◽  
Hua-You Hu ◽  
Li-Tao An ◽  
Yu-He Kan
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
The Self ◽  
Donor Ligands

Effect of organic anions on the self-assembly of Zn(ii)-containing coordination polymers based on trigonal N-donor ligands

CrystEngComm ◽  
2012 ◽  
Vol 14 (20) ◽  
pp. 6934 ◽  
Author(s):  
Wei-Qiu Kan ◽  
Jin Yang ◽  
Ying-Ying Liu ◽  
Jian-Fang Ma
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Organic Anions ◽  
The Self ◽  
Donor Ligands

A series of helical coordination polymers based on two racemic bis(pyridylmethylene) propane-1,2-diamine ligands: relationship of conformations, structures and properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (47) ◽  
pp. 7249-7259 ◽  
Author(s):  
Li-Na Zhu ◽  
Zhao-Peng Deng ◽  
Li-Hua Huo ◽  
Shan Gao
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
The Self ◽  
Metal Salts ◽  
Structures And Properties ◽  
Relationship Of ◽  
Diamine Ligands

The self-assembly of d10 metal salts and two racemic bis(pyridyl) diamine ligands generates ten complexes, showing diverse helical and wavelike chains, (4,4) layers, as well as 3D sqc and uog nets.

Copper(i) halide cluster-based coordination polymers modulated by chiral ditopic dithiodianthranilide ligands: synthesis, crystal structure and photoluminescence

CrystEngComm ◽  
2021 ◽  
Author(s):  
Jarosław Chojnacki ◽  
Michał Mońka ◽  
Illia E. Serdiuk ◽  
Piotr Bojarski ◽  
Tadeusz Połoński ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Spectroscopic Properties ◽  
The Self ◽  
Halide Cluster

The influence of ligand chirality on the self-assembly and spectroscopic properties of copper(i) halide coordination polymers was investigated.

Hydrothermal Syntheses, Crystal Structures, and Luminescent Properties of Two MnII Coordination Polymers: From Two-Fold Interpenetrated pcu Topological Net to Polycatenated 2D+2D→3D Framework

2015 ◽  
Vol 68 (2) ◽  
pp. 322 ◽  
Author(s):  
Wenlong Liu ◽  
Mengqiang Wu ◽  
Xueying Wang ◽  
Wei Wang ◽  
Dayu Liu ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Room Temperature ◽  
Luminescent Properties ◽  
The Self ◽  
X Ray Diffraction ◽  
X Ray ◽  
3D Framework ◽  
Dimethyl Benzene

Using a hydrothermal synthesis, the self-assembly of MnII ions and 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene with two dicarboxylate ligands, 2-nitrobenzene-1,4-dicarboxylic acid (2-H2ata) and 5-methylbenzene-1,3-dicarboxylic acid (5-CH3-H2ip) constructed two interesting coordination polymers: [Mn(2-ata)(bimb)]n (1) and {[Mn(5-CH3-ip)(bimb)1.5]·2H2O}n (2), where bimb refers to 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene. Their structures were determined by single-crystal X-ray diffraction, elemental analysis, and infrared spectroscopy. Complex 1 exhibits a 2-fold interpenetrated pcu net. Complex 2 shows an unusual polycatenated 2D+2D→3D framework. In addition, the solid-state photoluminescent properties of 1 and 2 were investigated at room temperature.

Solvothermal self-assembly of Cd2+ coordination polymers with supramolecular networks involving N-donor ligands and aromatic dicarboxylates: synthesis, crystal structure and photoluminescence studies

2017 ◽  
Vol 46 (11) ◽  
pp. 3623-3630 ◽  
Author(s):  
Yadagiri Rachuri ◽  
Bhavesh Parmar ◽  
Kamal Kumar Bisht ◽  
Eringathodi Suresh
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Luminescence Quenching ◽  
Donor Ligands ◽  
Supramolecular Networks ◽  
Photoluminescence Studies ◽  
State Luminescence

Structural, solid state luminescence of Cd(ii) coordination polymers and detection of acetone by CP1via luminescence quenching have been discussed.

Effect of Anions on the Self-Assembly of Cd(II)-Containing Coordination Polymers Based on a Novel Flexible Tetrakis(imidazole) Ligand

2010 ◽  
Vol 10 (2) ◽  
pp. 995-1016 ◽  
Author(s):  
Hong-Ye Bai ◽  
Jian-Fang Ma ◽  
Jin Yang ◽  
Ying-Ying Liu ◽  
Hua-Wu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
The Self ◽  
Imidazole Ligand

Influence of the central metal ion in controlling the self-assembly and magnetic properties of 2D coordination polymers derived from [(NiL)2M]2+ nodes (M = Ni, Zn and Cd) (H2L = salen-type di-Schiff base) and dicyanamide spacers

2015 ◽  
Vol 44 (3) ◽  
pp. 1292-1302 ◽  
Author(s):  
Lakshmi Kanta Das ◽  
Carlos J. Gómez-García ◽  
Ashutosh Ghosh
Keyword(s):  
Magnetic Properties ◽  
Schiff Base ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Significant Variation ◽  
Metal Ion ◽  
The Self ◽  
Central Metal

Three new 2D coordination polymers of different networks with significant variation in magnetic properties have been synthesized by changing the central metal in the trinuclear nodes.

scholarly journals Porphyrin-based metal coordination polymers with self-assembly pathway-dependent properties for photodynamic and photothermal therapy

2020 ◽  
Author(s):  
Yuyang Miao ◽  
Shibo Lv ◽  
Daoyuan Zheng ◽  
Yuhan Liu ◽  
Dapeng Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Photothermal Therapy ◽  
The Self ◽  
Metal Coordination ◽  
Great Promise ◽  
Assembly Process ◽  
Assembly Pathway ◽  
Metal Organic ◽  
Metal Coordination Polymers

Abstract Porphyrin-based metal coordination polymers (MCPs) have attracted numerous attention due to their great promise application in phototherapy including photodynamic therapy (PDT) and photothermal therapy (PTT). However, the detailed self-assembly process of porphyrin-based MCPs still remains poorly understood. This work provides a detailed study of the self-assembly process of MCPs constructed by Mn2+ and TCPP (TCPP: 4,4′,4′′,4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)) in aqueous solution. Unlike traditional nucleation and growth mechanism, we discover that there is a metastable metal-organic intermediate which is kinetically favored in the self-assembly process. And the metastable metal-organic intermediate nanotape structures could convert into thermodynamically favored nanosheets through disassembling into monomers followed by reassembling process. Moreover, the two structurally different assemblies exhibit distinct photophysical performances. The intermediate Mn-TCPP aggregates show good light-induced singlet oxygen 1O2 generation for PDT while the thermodynamic favored stable Mn-TCPP aggregates exhibit good photothermal conversion ability as photothermal agents (PTAs). This study could facilitate controlling self-assembly pathway to fabricate complex MCPs with desirable applications.

Deciphering supramolecular isomerization in coordination polymers: connected molecular squares vs fused hexagons

2021 ◽  
Author(s):  
Vijay Gupta ◽  
Biswajit Laha ◽  
Sadhika Khullar ◽  
Sanjay Mandal
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
The Self ◽  
Ambient Conditions ◽  
Tridentate Ligands ◽  
Molecular Squares

The self-assembly of Mn(II), bis(tridentate) ligands, and bent dicarboxylate linkers under ambient conditions has been exploited to generate a series of 1D coordination polymers in good yields. For a set...

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