Stabilization of Co3- Oxoclusters in apcuNet: Synthesis, Structure, Solvent Exchange (Single Crystal to Single Crystal) and Magnetic Studies

2014 ◽  
Vol 640 (14) ◽  
pp. 2922-2930 ◽  
Author(s):  
Saurav Bhattacharya ◽  
Srinivasan Natarajan
Keyword(s):  
Single Crystal ◽  
Solvent Exchange ◽  
Magnetic Studies

Single crystal magnetic studies on CuCl2⋅TMSO, a Heisenberg 1‐d ferromagnet

1982 ◽  
Vol 53 (3) ◽  
pp. 1888-1890 ◽  
Author(s):  
C. P. Landee ◽  
R. D. Willett ◽  
F. Waldner
Keyword(s):  
Single Crystal ◽  
Magnetic Studies

Single-crystal magnetic studies of cylindrite (FePb3Sn4Sb2S14)

2000 ◽  
Vol 87 (9) ◽  
pp. 6025-6027 ◽  
Author(s):  
Pamela A. Salyer ◽  
Leonard W. ter Haar
Keyword(s):  
Single Crystal ◽  
Magnetic Studies

Synthesis, crystal structures and magnetic and electrochemiluminescence properties of three manganese(II) complexes

2020 ◽  
Vol 76 (3) ◽  
pp. 236-243 ◽  
Author(s):  
Yating Chen ◽  
Shaonan Zhang ◽  
Yu Xiao ◽  
Shuhua Zhang
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Elemental Analysis ◽  
X Ray Diffraction ◽  
Magnetic Studies ◽  
One Dimensional ◽  
X Ray ◽  
Manganese Clusters ◽  
Dimensional Network ◽  
Solvothermal Methods

Three novel complexes, namely, penta-μ-acetato-bis(μ2-2-{[2-(6-chloropyridin-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)-μ-formato-tetramanganese(II), [Mn4(C13H11ClN3O2)2(C2H3O2)5.168(CHO2)0.832], 1, hexa-μ2-acetato-bis(μ2-2-{[2-(6-bromopyridin-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)tetramanganese(II), [Mn4(C13H11BrN3O2)2(C2H3O2)6], 2, and catena-poly[[μ2-acetato-acetatoaqua(μ2-2-{[2-(6-chloropyridin-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)dimanganese(II)]-μ2-acetato], [Mn2(C13H11ClN3O2)(C2H3O2)3(H2O)] n , 3, have been synthesized using solvothermal methods. Complexes 1–3 were characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. Complexes 1 and 2 are tetranuclear manganese clusters, while complex 3 has a one-dimensional network based on tetranuclear Mn4(L 1)2(CH3COO)6(H2O)2 building units (L 1 is 2-{[2-(6-chloropyridin-2-yl)hydrazinylidene]methyl}-6-methoxyphenolate). Magnetic studies reveal that complexes 1–3 display dominant antiferromagnetic interactions between MnII ions through μ2-O bridges. In addition, 1–3 also display favourable electrochemiluminescence (ECL) properties.

Syntheses, structures and magnetic properties of two CoII/NiII isostructural coordination polymers based on an asymmetric semirigid tricarboxylate ligand

2022 ◽  
Vol 78 (1) ◽  
Author(s):  
Shao-Dong Li ◽  
Feng Su ◽  
Cheng-Yong Zhou ◽  
Qi-Long Hu ◽  
Ya-Qi Li ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Ir Spectroscopy ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Magnetic Studies ◽  
Thermogravimetric Analyses ◽  
X Ray ◽  
Elemental Analyses

Two new isostructural complexes, namely, poly[aqua[μ3-2-(4-carboxyphenoxy)terephthalato-κ3 O 1:O 4:O 4′](1,10-phenanthroline-κ2 N,N′)cobalt(II)], [Co(C15H8O7)(C12H8N2)(H2O)] n or [Co(μ3-Hcpota)(phen)(H2O)] n , I, and poly[aqua[μ3-2-(4-carboxyphenoxy)terephthalato-κ3 O 1:O 4:O 4′](1,10-phenanthroline-κ2 N,N′)nickel(II)], [Ni(C15H8O7)(C12H8N2)(H2O)] n or [Ni(μ3-Hcpota)(phen)(H2O)] n , II, have been synthesized by solvothermal reactions. Complexes I and II were fully characterized by IR spectroscopy, elemental analyses, thermogravimetric analyses, and powder and single-crystal X-ray diffraction. They both present two-dimensional structures based on [M 2(μ-COO)2]2+ (M = CoII or NiII) dinuclear metal units with a fes topology and a vertex symbol (4·82). Interestingly, the positions of the two dimeric metal motifs and the two partially deprotonated Hcpota2− ligands reproduce regular flying butterfly arrangements flipped upside down and sharing wings in the ab plane. Magnetic studies indicate antiferromagnetic interactions (J = −5.21 cm−1 for I and −11.53 cm−1 for II) in the dimeric units, with Co...Co and Ni...Ni distances of 4.397 (1) and 4.358 (1) Å, respectively, that are related to double syn–anti carboxylate bridges.

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