Room Temperature Synthesis and Crystal Structure ofmer-[MoBr3Py3], the Vibrational Spectra ofmer-[MoBr3Py3],mer-[MoI3Py3] andtrans,trans-[MoBr2Py4][MoBr4Py2]

2013 ◽  
Vol 639 (6) ◽  
pp. 939-942 ◽  
Author(s):  
Gleb Veryasov ◽  
Evgeny Goreshnik ◽  
Adolf Jesih
Keyword(s):  
Crystal Structure ◽  
Vibrational Spectra ◽  
Room Temperature ◽  
Temperature Synthesis ◽  
Synthesis And Crystal Structure ◽  
Room Temperature Synthesis

Room temperature synthesis, crystal structure and selected properties of the new compound [Mn2(bipy)4SbS4](ClO4)

2016 ◽  
Vol 71 (5) ◽  
pp. 395-401 ◽  
Author(s):  
Carolin Anderer ◽  
Christian Näther ◽  
Wolfgang Bensch
Keyword(s):  
Crystal Structure ◽  
Aqueous Solutions ◽  
Room Temperature ◽  
Magnetic Measurements ◽  
Exchange Interactions ◽  
Antiferromagnetic Exchange ◽  
Synthetic Route ◽  
Pure Compound ◽  
Temperature Synthesis ◽  
Room Temperature Synthesis

AbstractThe new compound [Mn2(bipy)4SbS4](ClO4) was prepared by a new synthetic route for the preparation of thioantimonates(V) that can be used even at room temperature. Mixing aqueous solutions of [Mn(bipy)3](ClO4)2 and Na3SbS4 · 9H2O leads to immediate crystallization of the pure compound. In the structure an SbS43– anion acts as a tetradentate bridge connecting two Mn2+ cations of [Mn(bipy)3]2+ complexes (bipy = 2,2′-bipyridine). The compound features a hitherto unknown [Mn2(bipy)4SbS4]+ cation. Bipy ligands of adjacent cations are arranged parallel to each other leading to weak off-center parallel π-π interactions stabilizing the crystals. Magnetic measurements indicate weak antiferromagnetic exchange interactions between the Mn2+ centers.

Room-temperature synthesis, growth mechanisms and opto-electronic properties of organic–inorganic halide perovskite CH3NH3PbX3 (X = I, Br, and Cl) single crystals

CrystEngComm ◽  
2021 ◽  
Author(s):  
Maryam Bari ◽  
Hua Wu ◽  
Alexei A. Bokov ◽  
Rana Faryad Ali ◽  
Hamel N. Tailor ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Single Crystals ◽  
Room Temperature ◽  
Solubility Curve ◽  
Inverse Temperature ◽  
Growth Mechanisms ◽  
Temperature Synthesis ◽  
Room Temperature Synthesis ◽  
Halide Perovskite ◽  
Temperature Crystallization

Growth of MAPbX3 (X = I, Br, and Cl) single crystals by room temperature crystallization (RTC) method, and the crystallization pathway illustrated by the solubility curve of MAPbCl3 in DMSO, compared with inverse temperature crystallization (ITC) method.

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