Ca5Ni17Ge8- A Complex Intermetallic Compound Combining Various Structure Motifs of Alkaline-Earth Nickel Germanides

Viktor Hlukhyy; Lisa Siggelkow; Thomas F. Fässler

doi:10.1002/zaac.201200118

ChemInform Abstract: Ca5Ni17Ge8- A Complex Intermetallic Compound Combining Various Structure Motifs of Alkaline-Earth Nickel Germanides.

ChemInform ◽

10.1002/chin.201303005 ◽

2013 ◽

Vol 44 (3) ◽

pp. no-no

Author(s):

Viktor Hlukhyy ◽

Lisa Siggelkow ◽

Thomas F. Faessler

Keyword(s):

Intermetallic Compound ◽

Alkaline Earth ◽

Nickel Germanides

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Dislocation Substructures Produced During Tensile, Creep, and Fatigue Deformation of Ti3Al at 700°C

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100078882 ◽

1977 ◽

Vol 35 ◽

pp. 272-273

Author(s):

S. M. L. Sastry

Keyword(s):

Intermetallic Compound ◽

Strain Rate ◽

Tensile Creep ◽

Slip Systems ◽

Slip Vector ◽

Superlattice Structure ◽

Slip Activity ◽

Dislocation Arrangement ◽

Ordered Intermetallic ◽

Tangled Dislocation

Ti3Al is an ordered intermetallic compound having the DO19-type superlattice structure. The compound exhibits very limited ductility in tension below 700°C because of a pronounced planarity of slip and the absence of a sufficient number of independent slip systems. Significant differences in slip behavior in the compound as a result of differences in strain rate and mode of deformation are reported here.Figure 1 is a comparison of dislocation substructures in polycrystalline Ti3Al specimens deformed in tension, creep, and fatigue. Slip activity on both the basal and prism planes is observed for each mode of deformation. The dominant slip vector in unidirectional deformation is the a-type (b) = <1120>) (Fig. la). The dislocations are straight, occur for the most part in a screw orientation, and are arranged in planar bands. In contrast, the dislocation distribution in specimens crept at 700°C (Fig. lb) is characterized by a much reduced planarity of slip, a tangled dislocation arrangement instead of planar bands, and an increased incidence of nonbasal slip vectors.

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Atomic structure of interface of intermetallic compound TiAl and nitride Ti2AIN using HREM and image processing

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100087161 ◽

1991 ◽

Vol 49 ◽

pp. 570-571

Author(s):

E. Sukedai ◽

H. Mabuchi ◽

H. Hashimoto ◽

Y. Nakayama

Keyword(s):

Mechanical Properties ◽

Image Processing ◽

Composite Material ◽

Intermetallic Compound ◽

Side Surface ◽

High Resolution Electron Microscopy ◽

Hexagonal Structure ◽

Second Phase ◽

Resolution Electron ◽

Compound Tial

In order to improve the mechanical properties of an intermetal1ic compound TiAl, a composite material of TiAl involving a second phase Ti2AIN was prepared by a new combustion reaction method. It is found that Ti2AIN (hexagonal structure) is a rod shape as shown in Fig.1 and its side surface is almost parallel to the basal plane, and this composite material has distinguished strength at elevated temperature and considerable toughness at room temperature comparing with TiAl single phase material. Since the property of the interface of composite materials has strong influences to their mechanical properties, the structure of the interface of intermetallic compound and nitride on the areas corresponding to 2, 3 and 4 as shown in Fig.1 was investigated using high resolution electron microscopy and image processing.

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Direct observation of Fe-Al-Zn ternary intermetallic compound and its transformation during the early stage of hot-dip galvanizing

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100151416 ◽

1993 ◽

Vol 51 ◽

pp. 1116-1117

Author(s):

C. S. Lin ◽

W. A. Chiou ◽

M. Meshii

Keyword(s):

Intermetallic Compound ◽

Reaction Rate ◽

Diffusion Rate ◽

Early Stage ◽

Zinc Bath ◽

Steel Sheets ◽

Direct Observations ◽

Solid Iron ◽

Iron And Zinc ◽

Ternary Intermetallic Compound

The galvannealed steel sheets have received ever increased attention because of their excellent post-painting corrosion resistance and good weldability. However, its powdering and flaking tendency during press forming processes strongly impairs its performance. In order to optimize the properties of galvanneal coatings, it is critical to control the reaction rate between solid iron and molten zinc.In commercial galvannealing line, aluminum is added to zinc bath to retard the diffusion rate between iron and zinc by the formation of a thin layer of Al intermetallic compound on the surface of steel at initial hot-dip galvanizing. However, the form of this compound and its transformation are still speculated. In this paper, we report the direct observations of this compound and its transformation.The specimens were prepared in a hot-dip simulator in which the steel was galvanized in the zinc bath containing 0.14 wt% of Al at a temperature of 480 °C for 5 seconds and was quenched by liquid nitrogen.

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Direct imaging of order-disorder and antiphase domain structures in Ti3Al intermetallic compound

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100175533 ◽

1990 ◽

Vol 48 (4) ◽

pp. 480-481

Author(s):

H. Q. Ye ◽

T.S. Xie ◽

D. Li

Keyword(s):

Intermetallic Compound ◽

Volume Fraction ◽

Fundamental Problem ◽

Antiphase Domain ◽

Atomic Scale ◽

Orientation Relationships ◽

Domain Structures ◽

Α Phase ◽

Diffraction Patterns ◽

Two Phases

The Ti3Al intermetallic compound has long been recognized as potentially useful structural materials. It offers attractive strength to weight and elastic modulus to weight ratios. Recent work has established that the addition of Nb to Ti3Al ductilized this compound. In this work the fundamental problem of this alloy, i.e. order-disorder and antiphase domain structures was investigated at the atomic scale.The Ti3Al+10at%Nb alloys used in this study were treated at 1060°C and then aged at 700°C for 2 hours. The specimens suitable for TEM were prepared by standard jet electrolytic-polishing technique. A JEM-200CX electron microscope with an interpretable resolution of about 0.25 nm was used for HREM.The [100] and [001] projections of the α2 phase were shown in Fig.l.The alloy obtained consist of at least two phases-α2(Ti3Al) and β0 structures. Moreover, a disorder α phase with small volume fraction was also observed. Fig.2 gives [100] and [001] diffraction patterns of the α2 phase. Since lattice parameters of the ordered α2 (a=0.579, c=0.466 nm) and disorder α phase (a0=0.294≈a/2, c0=0.468 nm) are almost the same, their diffraction patterns are difficult to be distinguished when they are overlapped with epitaxial orientation relationships.

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