{Sn10[Si(SiMe3)3]5}- : An Anionic Metalloid Tin Cluster from an Isolable SnI Halide Solution

2011 ◽  
Vol 638 (3-4) ◽  
pp. 589-593 ◽  
Author(s):  
Claudio Schrenk ◽  
Jens Helmlinger ◽  
Andreas Schnepf
Keyword(s):  
Halide Solution

Fusing of Silver Nanoparticles at Room Temperature Using Halide Solutions for Conductive Inks

2020 ◽  
Vol 833 ◽  
pp. 181-185 ◽  
Author(s):  
Bethel Faith Y. Rezaga ◽  
Mary Donnabelle L. Balela
Keyword(s):  
Particle Size ◽  
Ag Nanoparticles ◽  
Room Temperature ◽  
Average Diameter ◽  
Aqueous System ◽  
Ag Nanoparticle ◽  
Nacl Solution ◽  
Halide Solution ◽  
Sintered Ag ◽  
Nanoparticle Ink

Fusing of silver (Ag) nanoparticles synthesized in an aqueous system was observed at room temperature using halide solutions. The as-synthesized Ag nanoparticles have an average diameter of about 24 nm. After dispersing the Ag nanoparticles in a halide solution, a significant increase in particle size to about 188-197 nm was observed. The enlargement of particle size was accompanied by the increase in conductivity of the Ag nanoparticle ink. The resistance was reduced from 110 kiloohms to 35 and 9.3 ohms for the as-prepared and sintered Ag nanoparticles using NaBr and NaCl solution, respectively.

scholarly journals Facile all-dip-coating deposition of highly efficient (CH3)3NPbI3−xClx perovskite materials from aqueous non-halide lead precursor

RSC Advances ◽  
2020 ◽  
Vol 10 (48) ◽  
pp. 29010-29017 ◽  
Author(s):  
Muhammad Adnan ◽  
Zobia Irshad ◽  
Jae Kwan Lee
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Precursor Solution ◽  
Dip Coating ◽  
Coating Deposition ◽  
Highly Efficient ◽  
Perovskite Materials ◽  
Halide Solution

Sequential all-dip-coating processed perovskite materials was conducted in an aqueous non-halide lead precursor solution, which was followed by that in a mixed halide solution for high-efficiency perovskite solar cells.

scholarly journals Ion Partitioning at the Liquid/Vapor Interface of a Multicomponent Alkali Halide Solution: A Model for Aqueous Sea Salt Aerosols

2008 ◽  
Vol 112 (48) ◽  
pp. 12378-12384 ◽  
Author(s):  
Sutapa Ghosal ◽  
Matthew A. Brown ◽  
Hendrik Bluhm ◽  
Maria J. Krisch ◽  
Miquel Salmeron ◽  
...  
Keyword(s):  
Alkali Halide ◽  
Sea Salt ◽  
Vapor Interface ◽  
Sea Salt Aerosols ◽  
Ion Partitioning ◽  
Halide Solution ◽  
Liquid Vapor

Formation and Characteristic of Room Temperature Electrolytic Sulfidized Coating on Hard Steel Substrate

2007 ◽  
Vol 539-543 ◽  
pp. 1236-1241
Author(s):  
Jing Hua Jiang ◽  
Jian Qing Jiang ◽  
Ai Bin Ma ◽  
Ping Hua Lin
Keyword(s):  
Lamellar Structure ◽  
Room Temperature ◽  
Solid Lubricant ◽  
Steel Substrate ◽  
Low Cost ◽  
Low Friction ◽  
Ferrous Sulfide ◽  
Geometrical Shapes ◽  
Halide Solution ◽  
Low Temperature Process

An electrolytic sulfurization at room temperature has been introduced in the present work, which process parameters are optimized to the quenched Cr12 substrate. Morphology and microstructure of the sulfide layers are investigated deeply, and their formation mechanism is discussed in detailed. According to optimum parameter of sulfurizing process ( assistant current density of 1.8A/dm2, the saturated rare-earth-halide solution containing 300g Na2S2O3, 60g KHSO3 and 1000ml H2O, 298K/20~40min), the ferrous sulfide coating was easily obtained on the quenched Cr12 substrate with a uniform thickness of above 10μm, no matter about the treated parts with the complex geometrical shapes. The tribological experiment results of a block-on-ring tribometer indicate that the sulfide coatings on hard substrate have a very low friction coefficient and could obviously reduce the wear extent of its counterpart. Compared with the traditional low-temperature process, this sulfurizing technology has such virtues as simple process, heatless, low cost, little deformation, without pollution question, etc., which could be employed for industrial solid lubricant due to the good friction-reducing characteristic of lamellar-structure FeS phase.

HIGH-FREQUENCY TITRATIONS: I. ARGENTIMETRIC DETERMINATION OF HALIDES AND THIOCYANATE IN METHANOL

1964 ◽  
Vol 42 (4) ◽  
pp. 770-780 ◽  
Author(s):  
Peter Grey ◽  
G. C. B. Cave
Keyword(s):  
Alkali Metal ◽  
High Frequency ◽  
Metal Halides ◽  
End Points ◽  
Closed Type ◽  
Alkali Metal Halides ◽  
Standard Solution ◽  
Halide Solution ◽  
Indifferent Electrolyte

A new method is proposed for the determination of milligram amounts of each halide present in a mixture of alkali-metal halides. In some mixtures, thiocyanate also may be determined. A methanol solution of the sample is titrated in a closed-type cell, with a standard solution of silver nitrate in methanol. By using high-frequency titrimetry, and an appropriate concentration of the halide solution, sharp end points were obtained for each halide. Because of solid solutions, the accuracy of the determination of individual halides in mixtures depended on the mole ratios of the halides; the errors found in the titration of various binary, ternary, and quaternary mixtures are reported. For some binary mixtures, the total amount of halide titrated in 120 ml of methanol was varied from 0.5 to 500 micromoles. At the lower concentrations, addition of a small amount of sodium nitrate sharpened the end point. At all concentrations of halide, an excessive amount of indifferent electrolyte essentially eliminated the end points. The alkali-metal halides gave more satisfactory titration graphs than did some other metal halides. The effects of variation in temperature, and of solvent evaporation were noted.

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