Synthesis, Crystal Structures, and Characterization of Two 3d-3d Heterometallic Coordination Frameworks: [ZnCo(Hcit)Cl] and [ZnCo(Hcit)Br]

2010 ◽  
pp. n/a-n/a
Author(s):  
Rui-Bin Liu ◽  
Jian-Jun Zhang ◽  
Bo Tong ◽  
Xin Liu ◽  
Yang Yang ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Coordination Frameworks

Distorted chiolite crystal structures of α-Na5M3F14 (M=Cr,Fe,Ga) studied by X-ray powder diffraction

2003 ◽  
Vol 18 (2) ◽  
pp. 128-134 ◽  
Author(s):  
A. Le Bail ◽  
A.-M. Mercier
Keyword(s):  
Crystal Structures ◽  
Powder Diffraction ◽  
Room Temperature ◽  
Rietveld Refinements ◽  
Space Group ◽  
X Ray ◽  
Precise Characterization

The crystal structures of the chiolite-related room temperature phases α-Na5M3F14 (MIII=Cr,Fe,Ga) are determined. For all of them, the space group is P21/n, Z=2; a=10.5096(3) Å, b=7.2253(2) Å, c=7.2713(2) Å, β=90.6753(7)° (M=Cr); a=10.4342(7) Å, b=7.3418(6) Å, c=7.4023(6) Å, β=90.799(5)° (M=Fe), and a=10.4052(1) Å, b=7.2251(1) Å, c=7.2689(1), β=90.6640(4)° (M=Ga). Rietveld refinements produce final RF factors 0.036, 0.033, and 0.035, and RWP factors, 0.125, 0.116, and 0.096, for MIII=Cr, Fe, and Ga, respectively. The MF6 polyhedra in the defective isolated perovskite-like layers deviate very few from perfect octahedra. Subtle octahedra tiltings lead to the symmetry decrease from the P4/mnc space group adopted by the Na5Al3F14 chiolite aristotype to the P21/n space group adopted by the title series. Facile twinning precluded till now the precise characterization of these compounds.

Synthesis of phenyl substituted bisphosphonates and crystal structures and characterization of Cd complexes of (dichloromethylene)bisphosphonic acid phenyl and alkyl ester derivatives

CrystEngComm ◽  
2009 ◽  
Vol 11 (11) ◽  
pp. 2431 ◽  
Author(s):  
Jonna Jokiniemi ◽  
Jouko Vepsäläinen ◽  
Harri Nätkinniemi ◽  
Sirpa Peräniemi ◽  
Markku Ahlgrén
Keyword(s):  
Crystal Structures ◽  
Alkyl Ester ◽  
Bisphosphonic Acid

Syntheses, crystal structures, and characterization of As(III) and As(V) thioarsenates, [Mn2(phen)(AsIII2S5)]n and [Mn3(phen)3(AsvS4)2]n·nH2O

2009 ◽  
Vol 182 (4) ◽  
pp. 913-919 ◽  
Author(s):  
Xin Wang ◽  
Tian-Lu Sheng ◽  
Sheng-Min Hu ◽  
Rui-Biao Fu ◽  
Jian-Shan Chen ◽  
...  
Keyword(s):  
Crystal Structures

Construction of two Novel 2D Coordination Frameworks with the Ligand H3nbtc: Synthesis, Crystal Structures, and Luminescence

2012 ◽  
Vol 638 (5) ◽  
pp. 832-837 ◽  
Author(s):  
Shi-Jie Li ◽  
Jian-She Liu ◽  
Jian Guo ◽  
Li-Li Ji ◽  
Wen-Dong Song ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Coordination Frameworks

ChemInform Abstract: Hydrothermal Synthesis, Crystal Structures and Characterization of New Vanadoborates: The Novel Decorated Cage Cluster [V6B22O44(OH)10].

ChemInform ◽  
2013 ◽  
Vol 44 (27) ◽  
pp. no-no
Author(s):  
Xing Liu ◽  
Jian Zhou ◽  
Litao An ◽  
Rong Chen ◽  
Feilong Hu ◽  
...  
Keyword(s):  
Hydrothermal Synthesis ◽  
Crystal Structures ◽  
The Novel
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