Dinuclear Complexes of Copper(I) with Crown Ether-containing N-Thiophosphorylated Bis-thioureas and 2,2′-Bipyridine or 1,10-Phenanthroline: Synthesis, Characterization, and Picrate Extraction Properties

2010 ◽  
Vol 636 (15) ◽  
pp. 2626-2632 ◽  
Author(s):  
Maria G. Babashkina ◽  
Elmira R. Shakirova ◽  
Damir A. Safin ◽  
Felix D. Sokolov ◽  
Axel Klein ◽  
...  
Keyword(s):  
Crown Ether ◽  
Dinuclear Complexes ◽  
Extraction Properties ◽  
Picrate Extraction

1,10-Diaza-18-crown-ether, Modified by Phosphonate Pendant Arms - Synthesis, Structure, and Picrate Extraction Properties

2008 ◽  
Vol 634 (11) ◽  
pp. 1836-1838 ◽  
Author(s):  
Narkis G. Khusainova ◽  
Sergey M. Rybakov ◽  
Damir A. Safin ◽  
Dmitriy B. Krivolapov ◽  
Igor A. Litvinov
Keyword(s):  
Crown Ether ◽  
Extraction Properties ◽  
Picrate Extraction ◽  
Pendant Arms

Synthesis, structure, and solvent-extraction properties of tridentate oxime ligands and their cobalt(II), nickel(II), copper(II), zinc(II) complexes

2010 ◽  
Vol 64 (1) ◽  
Author(s):  
Bülent Dede ◽  
Fatma Karipcin ◽  
Filiz Arabalı ◽  
Mustafa Cengiz
Keyword(s):  
Magnetic Susceptibility ◽  
Solvent Extraction ◽  
Transition Metal ◽  
Elemental Analysis ◽  
Dinuclear Complexes ◽  
Icp Oes ◽  
Binding Ability ◽  
Different Types ◽  
Extraction Properties ◽  
Ft Ir

AbstractSynthesis of four different types of ligands Ar[COC(NOH)R]n (Ar = biphenyl, n = 1, HL1; Ar = biphenyl, n = 2, H2L2; Ar = diphenylmethane, n = 1, HL3; Ar = diphenylmethane, n = 2, H2L4; R = furfurylamine in all ligands) and their dinuclear Co2+, Ni2+, Cu2+, and Zn2+ complexes is reported herein. These compounds were characterized by elemental analysis, ICP-OES, FT-IR spectra, and magnetic susceptibility measurements. The ligands were further characterized by 1H NMR. The results suggest that dinuclear complexes of HL1 and HL3 have a metal to ligand mole ratio of 2: 2 and dinuclear complexes H2L2 and H2L4 have a metal to ligand mole ratio of 2: 1. Square pyramidal or octahedral structures are proposed for complexes of oxime ligands. Furthermore, extraction abilities of the four ligands were also evaluated in chloroform using selected transition metal picrates such as Mn2+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+. The ligands show strong binding ability towards Hg2+ and Cu2+ ions.

DV-Xα calculations on some metallacyclopentadienyl dinuclear complexes

1989 ◽  
Vol 86 ◽  
pp. 841-846 ◽  
Author(s):  
Maurizio Casarin ◽  
Gaetano Granozzi
Keyword(s):  
Dinuclear Complexes

Preparation and Gas Sensitivity of Crown Ether Metal Complex Film Gas Sensor

2020 ◽  
Vol 2 (1) ◽  
pp. 1-12
Author(s):  
Gulgina Mamtimin ◽  
Halisa Arkin ◽  
Patima Nizamidin ◽  
Erkin Tursun ◽  
Abliz Yimit
Keyword(s):  
Crown Ether ◽  
Metal Complex ◽  
Gas Sensor ◽  
Gas Sensitivity ◽  
Complex Film

Anthocyanins: Chemical Properties and Health Benefits: A Review

2021 ◽  
Vol 17 ◽  
Author(s):  
Siraj Salman Mohammad ◽  
Renata Oliveira Santos ◽  
Maria Ivone Barbosa ◽  
José Lucena Barbosa Junior
Keyword(s):  
Raw Materials ◽  
Health Benefits ◽  
Chemical Properties ◽  
Extraction Methods ◽  
The Body ◽  
Raw Material ◽  
Extraction Properties ◽  
Therapeutic Properties ◽  
Food Processes ◽  
Shed Light

: Anthocyanins are widely spread in different kinds of food, especially fruits and floral tissues, there is an extensive range of anthocyanin compounds reach more than 600 exist in nature. Anthocyanins can be used as antioxidants and raw material for several applications in food and pharmaceutical industry. Consequently, a plenty of studies about anthocyanins sources and extraction methods were reported. Furthermore, many studies about their stability, bioactive and therapeutic properties have been done. According to the body of work, we firstly worked to shed light on anthocyanin properties including chemical, antioxidant and extraction properties. Secondly, we reported the applications and health benefits of anthocyanin including the applications in food processes and anthocyanin characteristics as therapeutic and prophylactic compounds. We reviewed anticancer, anti-diabetic, anti-fatness, oxidative Stress and lipid decreasing and vasoprotective effects of anthocyanins. In conclusion, because the importance of phytochemicals and bioactive compounds the research is still continuing to find new anthocyanins from natural sources and invest them as raw materials in the pharmaceutical and nutrition applications.

PEO-based electrolytes blended with star polymers with precisely imprinted polymeric pseudo-crown ether cavities for alkali metal ion batteries

2019 ◽  
Vol 576 ◽  
pp. 182-189 ◽  
Author(s):  
Zhuliu Xiao ◽  
Binghua Zhou ◽  
Jirong Wang ◽  
Cai Zuo ◽  
Dan He ◽  
...  
Keyword(s):  
Crown Ether ◽  
Alkali Metal ◽  
Metal Ion ◽  
Star Polymers ◽  
Alkali Metal Ion

Electrochemiluminescence of Ruthenium(II) Complexes Functionalized with Crown Ether Pendants and Effects of Cation Binding

2008 ◽  
Vol 47 (3) ◽  
pp. 1218-1223 ◽  
Author(s):  
Mei-Jin Li ◽  
Zuofeng Chen ◽  
Nianyong Zhu ◽  
Vivian Wing-Wah Yam ◽  
Yanbing Zu
Keyword(s):  
Crown Ether ◽  
Cation Binding

Crown ethers in hydrogenated graphene

2021 ◽  
Author(s):  
Kai Guo ◽  
Sitong Liu ◽  
Haoming Tu ◽  
Zhikun Wang ◽  
Liang Chen ◽  
...  
Keyword(s):  
Crown Ether ◽  
Crown Ethers ◽  
Hydrogenated Graphene ◽  
High Flexibility

Crown ethers could serve as hosts to selectively incorporate various guest atoms or molecules within the macrocycles. However, the high flexibility of crown ether molecules limits their applications in areas...

Sign in / Sign up

Export Citation Format

Share Document