Cluster Complexes with the Novel Heterometallic Cluster Core {Mo5NbI8}: Synthesis, Excision Reactions, and Crystal Structures

2010 ◽  
Vol 636 (3-4) ◽  
pp. 483-491 ◽  
Author(s):  
Sofia B. Artemkina ◽  
Nikolay G. Naumov ◽  
Konstantin N. Kondrakov ◽  
Alexander V. Virovets ◽  
Svetlana G. Kozlova ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Cluster Core ◽  
The Novel ◽  
Cluster Complexes ◽  
Heterometallic Cluster

ChemInform Abstract: Hydrothermal Synthesis, Crystal Structures and Characterization of New Vanadoborates: The Novel Decorated Cage Cluster [V6B22O44(OH)10].

ChemInform ◽  
2013 ◽  
Vol 44 (27) ◽  
pp. no-no
Author(s):  
Xing Liu ◽  
Jian Zhou ◽  
Litao An ◽  
Rong Chen ◽  
Feilong Hu ◽  
...  
Keyword(s):  
Hydrothermal Synthesis ◽  
Crystal Structures ◽  
The Novel

scholarly journals Synthesis, crystal structures and magnetic properties of two heterometallic {Ln8Cr4} (Ln = Gd3+ and Tb3+) complexes with one-dimensional wave chain structure

RSC Advances ◽  
2020 ◽  
Vol 10 (19) ◽  
pp. 11365-11370
Author(s):  
Ye-Min Han ◽  
Ning-Fang Li ◽  
Yan-Zhao Yu ◽  
Jia-Peng Cao ◽  
Mu-Xiu Yang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Chain Structure ◽  
Organic Ligands ◽  
One Dimensional ◽  
Heterometallic Cluster ◽  
Dimensional Wave

Two heterometallic cluster {Ln8Cr4} were constructed from two classical “drum-like” {Ln4Cr2} building units associated by organic ligands HIN, displaying 1D wave chain structure. The MCE values for {Gd8Cr4} at 3 K and 7 T is 23.40 J kg−1 K−1.

scholarly journals Synthesis, crystal structures and dielectric properties of the novel linear high k molecular materials

2005 ◽  
Vol 61 (a1) ◽  
pp. c328-c328
Author(s):  
A. Zakrassov ◽  
Y. Sheynin ◽  
S. Berger ◽  
M. Botoshansky ◽  
A. Keren ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
Crystal Structures ◽  
The Novel ◽  
Molecular Materials ◽  
High K

scholarly journals Synthesis, Superoxide Dismutase Mimetic and Anticancer Activities of Metal Complexes of 2,2-Dimethylpentanedioic Acid(2dmepdaH2) and 3,3-Dimethylpentanedioic acid(3dmepdaH2): X-Ray Crystal Structures of [Cu(3dmepda)(bipy)]2⋅6H2Oand [Cu(2dmepda)(bipy)(EtOH)]2⋅4EtOH(bipy=2,2′Bipyridine)

2006 ◽  
Vol 2006 ◽  
pp. 1-11 ◽  
Author(s):  
Michael Devereux ◽  
Malachy McCann ◽  
Denis O'Shea ◽  
Mark O'Connor ◽  
Eileen Kiely ◽  
...  
Keyword(s):  
Hepatocellular Carcinoma ◽  
Superoxide Dismutase ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Cell Lines ◽  
Copper Complexes ◽  
The Novel ◽  
Anticancer Activities ◽  
Adenocarcinoma Cell ◽  
X Ray

2,2-dimethylpentanedioic acid (2dmepdaH2) and 3,3-dimethylpentanedioic acid (3dmepdaH2) reacted with copper(II) acetate to give [Cu(2dmepda)(H2O)3]2(1) and [Cu(3dmepda)(H2O)3]2(2). Reaction of (1) and (2) with 1,10-phenanthroline and 2,2′-bipyridine yielded [Cu(2dmepda)(phen)(H2O)]20.5phen (3), [Cu(2dmepda)(bipy)(H2O)]2(4), [Cu(2dmepda)(bipy)(EtOH)]2⋅2EtOH(4A), [Cu(3dmepda)(phen)(H2O)]2(5), and [Cu(3dmepda)(bipy)(H2O)]2⋅(6). The structures of (4A) and (6) each consists of a [Cu(bipy)(dicarboxylate)(solvent)]2dimer. The superoxide dismutase (SOD) mimetic activity of the novel copper complexes and their manganese analogues was investigated. The dimethyl sulphoxide(DMSO) soluble complexes (1)–(4) and (6) were assessed for their cancer chemotherapeutic potential towards hepatocellular carcinoma and kidney adenocarcinoma cell lines. The 1,10-phenanthroline containing complex [Cu(2dmepda)(phen)(H2O)]20.5phen (3) was the most potent with activity that compares well to that ofcisplatin.

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