Tuning the Photophysical Properties and Solid-State Organization of Perfluorophenyl-functionalized Dithieno[3,2-b:2′,3′-d]phospholes

2009 ◽  
Vol 635 (2) ◽  
pp. 238-244 ◽  
Author(s):  
Yvonne Dienes ◽  
Ulli Englert ◽  
Thomas Baumgartner
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
State Organization

scholarly journals Fluorinated azobenzenes as supramolecular halogen-bonding building blocks

2019 ◽  
Vol 15 ◽  
pp. 2013-2019 ◽  
Author(s):  
Esther Nieland ◽  
Oliver Weingart ◽  
Bernd M Schmidt
Keyword(s):  
Solid State ◽  
Dft Calculations ◽  
Visible Light ◽  
Half Life ◽  
Photophysical Properties ◽  
Bathochromic Shift ◽  
Halogen Bonding ◽  
Building Blocks ◽  
Partial Overlap

ortho-Fluoroazobenzenes are a remarkable example of bistable photoswitches, addressable by visible light. Symmetrical, highly fluorinated azobenzenes bearing an iodine substituent in para-position were shown to be suitable supramolecular building blocks both in solution and in the solid state in combination with neutral halogen bonding acceptors, such as lutidines. Therefore, we investigate the photochemistry of a series of azobenzene photoswitches. Upon introduction of iodoethynyl groups, the halogen bonding donor properties are significantly strengthened in solution. However, the bathochromic shift of the π→π* band leads to a partial overlap with the n→π* band, making it slightly more difficult to address. The introduction of iodine substituents is furthermore accompanied with a diminishing thermal half-life. A series of three azobenzenes with different halogen bonding donor properties are discussed in relation to their changing photophysical properties, rationalized by DFT calculations.

scholarly journals Indenopyrans – synthesis and photoluminescence properties

2016 ◽  
Vol 12 ◽  
pp. 825-834 ◽  
Author(s):  
Andreea Petronela Diac ◽  
Ana-Maria Ţepeş ◽  
Albert Soran ◽  
Ion Grosu ◽  
Anamaria Terec ◽  
...  
Keyword(s):  
Solid State ◽  
Emission Band ◽  
Fluorescence Spectra ◽  
Photophysical Properties ◽  
Quantum Yields ◽  
Band Broadening ◽  
Photoluminescence Properties ◽  
Fluorescence Quantum Yields ◽  
Blue Emitters ◽  
Solid State Fluorescence

New indeno[1,2-c]pyran-3-ones bearing different substituents at the pyran moiety were synthesized and their photophysical properties were investigated. In solution all compounds were found to be blue emitters and the trans isomers exhibited significantly higher fluorescence quantum yields (relative to 9,10-diphenylanthracene) as compared to the corresponding cis isomers. The solid-state fluorescence spectra revealed an important red shift of λmax due to intermolecular interactions in the lattice, along with an emission-band broadening, as compared to the solution fluorescence spectra.

Cationic Iridium Dendrimers: Synthesis and Photophysical Properties

2011 ◽  
Vol 64 (9) ◽  
pp. 1211 ◽  
Author(s):  
Bin Du ◽  
Si-Chun Yuan ◽  
Jian Pei
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
Dendritic Structure ◽  
Benzimidazole Derivatives ◽  
Iridium Complex ◽  
Iridium Complexes ◽  
Efficient Energy Transfer ◽  
Ancillary Ligands ◽  
Synthetic Strategy ◽  
Yellow Orange

Two dendrimers, D1 and D2, containing the cationic iridium complexes (C1 and C2) as cores and truxene-functionalized chromophores as the branches, have been developed by a convergent synthetic strategy. The cationic complexes employ 3-(pyridin-2-yl)-1H-1,2,4-triazole and 2-(pyridin-2-yl)-benzimidazole derivatives as the ancillary ligands. To avoid the change in emission colour arising from the iridium complex, the conjugation between the dendron and the ligand is decoupled by separating them using the alkyl chain. An investigation of their photoluminescent features reveals that efficient energy transfer happens from the dendrons to the core in the solid state. Likewise, the charged dendritic structure is demonstrated to be an efficient method to improve the compatibility between the polar charged iridium complexes and typical hydrophobic hosts with the additional benefit of excellent solution processability. Both dendrimers exhibit strong solvatochromic behaviours in solvents and exclusive green and yellow-orange light in the solid state.

Synthesis, Characterization and Photophysical Properties of Rhenium(I) Complexe with 2-(naphthalen-2-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline

2014 ◽  
Vol 988 ◽  
pp. 66-69
Author(s):  
Qiang Li ◽  
Le Li ◽  
Rong Feng Zhong ◽  
Hai Di Cai ◽  
Feng Zhao
Keyword(s):  
Experimental Data ◽  
Solid State ◽  
Photophysical Properties ◽  
Broad Band ◽  
High Energy ◽  
H Nmr ◽  
Emission Maximum ◽  
Broad Band Emission ◽  
Band Emission

In this paper, a Re(I) complex [Re(CO)3(E2)Cl], where E2 = 2-(naphthalen-2-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline(E2), was synthesized and characterized by 1H NMR successfully. Experimental data confirm that Re(I) complex [Re(CO)3(E2)Cl] is high-energy-emitting one. The broad band emission upon excitation at λ = 400 nm with the emission maximum locates at λ = 581 nm in solid state and 614nm in CH2Cl2 solution were observed.

Photophysical properties of poly(phenylene- co -fluorene) synthesized via solid-state oxidative coupling polymerization

2018 ◽  
Vol 148 ◽  
pp. 359-367 ◽  
Author(s):  
Weibin Bai ◽  
Meiqin Guan ◽  
Xianhuo Shang ◽  
Rijin Yao ◽  
Ningshan Lai ◽  
...  
Keyword(s):  
Solid State ◽  
Oxidative Coupling ◽  
Photophysical Properties ◽  
Coupling Polymerization
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