Nano‐metal oxide fillers in thermo‐responsive polycaprolactone‐based polymer nanocomposites smart materials: Impact on thermo‐mechanical, and shape memory properties

Author(s):  
Sithara Gopinath ◽  
Nayarassery N Adarsh ◽  
Pankajakshan Nair ◽  
Suresh Mathew
2013 ◽  
Vol 23 (1) ◽  
pp. 120-127 ◽  
Author(s):  
Xi-li LU ◽  
Xiu-qian LÜ ◽  
Jian-yong WANG ◽  
Zhi-jie SUN ◽  
Yun-xiang TONG

Author(s):  
Jing Zhao ◽  
Muyue Han ◽  
Lin Li

Abstract The emergence of smart materials coupled with additive manufacturing technology has provided competitive advantages over traditional manufacturing systems in terms of manufacturing flexibility, product functionality, and the ability to switch between multiple phases under given external stimuli. Although the fabricability of shape memory materials has been widely explored in stereolithography systems, the shape memory performance of printed smart structures has not been extensively studied. More specifically, in current literature, the printing process is mainly considered independent of material characteristics, and a lack of information is reported on how the printing parameters affect the shape fixity and free recovery performance of the printed parts. Therefore, this work is dedicated to experimentally investigating the influences of parameters from both the stereolithography printing process and thermomechanical process (i.e., shape programming and free recovery) on the shape memory properties. Five parameters, including layer thickness, scan speed, maximum programmed angle, hold time, and recovery time, are experimentally analyzed for their impacts on the shape morphing capabilities. According to the results of this study, a variation of 14.33% on the free recovery ratio can be observed when the scan speed is altered. In addition, the printing process parameters exhibit high levels of dominance in affecting the shape memory performance over parameters involved in the thermomechanical process, such as hold time and maximum programmed angle.


2021 ◽  
pp. 51000
Author(s):  
Fathin Hani Azizul Rahim ◽  
Abdul Aziz Saleh ◽  
Raa Khimi Shuib ◽  
Ku Marsilla Ku Ishak ◽  
Zuratul Ain Abdul Hamid ◽  
...  

2013 ◽  
Vol 80 ◽  
pp. 92-97 ◽  
Author(s):  
Semra Ergen ◽  
Orhan Uzun ◽  
Fikret Yilmaz ◽  
M. Fatih Kiliçaslan

2011 ◽  
Vol 674 ◽  
pp. 171-175
Author(s):  
Katarzyna Bałdys ◽  
Grzegorz Dercz ◽  
Łukasz Madej

The ferromagnetic shape memory alloys (FSMA) are relatively the brand new smart materials group. The most interesting issue connected with FSMA is magnetic shape memory, which gives a possibility to achieve relatively high strain (over 8%) caused by magnetic field. In this paper the effect of annealing on the microstructure and martensitic transition on Ni-Mn-Co-In ferromagnetic shape memory alloy has been studied. The alloy was prepared by melting of 99,98% pure Ni, 99,98% pure Mn, 99,98% pure Co, 99,99% pure In. The chemical composition, its homogeneity and the alloy microstructure were characterized using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The phase composition was also studied by X-ray analysis. The transformation course and characteristic temperatures were determined by the use of differential scanning calorimetry (DSC) and magnetic balance techniques. The results show that Tc of the annealed sample was found to decrease with increasing the annealing temperature. The Ms and Af increases with increasing annealing temperatures and showed best results in 1173K. The studied alloy exhibits a martensitic transformation from a L21 austenite to a martensite phase with a 7-layer (14M) and 5-layer (10M) modulated structure. The lattice constants of the L21 (a0) structure determined by TEM and X-ray analysis in this alloy were a0=0,4866. The TEM observation exhibit that the studied alloy in initial state has bigger accumulations of 10M and 14M structures as opposed from the annealed state.


2015 ◽  
Vol 13 ◽  
pp. 83-90 ◽  
Author(s):  
Cristiana Diana Cristea ◽  
Magdalena Lungu ◽  
Alexander M. Balagurov ◽  
Virgil Marinescu ◽  
Otilia Culicov ◽  
...  

The addition of Cu to near equiatomic NiTi shape memory alloys (SMAs) can provide some modifications of their shape memory properties by affecting their transformation behavior. The same effect was obtained in the case of Ni3Ti2 and Ni4Ti3 precipitates presence in the microstructure of NiTi. Also the substitution of Cu to NiTi alloys increases the hardness of the materials. This paper presents the microstructural and mechanical investigations of NiTi and NiTiCu alloys obtained by spark plasma sintering (SPS) process that represents a great potential for researchers as a new process for the fabrication of intermetallic compounds.


2013 ◽  
Vol 585 ◽  
pp. 86-93 ◽  
Author(s):  
R. Arockiakumar ◽  
M. Takahashi ◽  
S. Takahashi ◽  
Yoko Yamabe-Mitarai

2004 ◽  
Vol 36 (10) ◽  
pp. 929-940 ◽  
Author(s):  
Yiping Liu ◽  
Ken Gall ◽  
Martin L Dunn ◽  
Patrick McCluskey

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