Fabrication of hydrotalcite containing N/P/S and its ternary synergistic efficiency on thermostability and fire resistance of ethylene vinyl acetate (EVA)

2018 ◽  
Vol 25 (3) ◽  
pp. 255-261 ◽  
Author(s):  
Xiaoyu Gu ◽  
Wenxiang Sun ◽  
Jia Guo ◽  
Xiangxing Bu ◽  
Hongfei Li ◽  
...  
Keyword(s):  
Vinyl Acetate ◽  
Fire Resistance ◽  
Ethylene Vinyl Acetate

scholarly journals Comparing the effect of nanoclays on the water-resistance of intumescent fire-retardant coatings

2021 ◽  
Vol 3 (6 (111)) ◽  
pp. 59-70
Author(s):  
Liubov Vakhitova ◽  
Kostyantyn Kalafat ◽  
Viktoriia Plavan ◽  
Volodymyr Bessarabov ◽  
Nadezhda Тaran ◽  
...  
Keyword(s):  
Vinyl Acetate ◽  
Fire Resistance ◽  
Water Resistance ◽  
Fire Retardant ◽  
Ethylene Vinyl Acetate ◽  
Ammonium Polyphosphate ◽  
Properties Of Coatings ◽  
Decay Period ◽  
Intumescent Coatings ◽  
Organically Modified

This paper reports a study into the effect of nanoclays on the water-resistance of the intumescent system ammonium polyphosphate/melamine/pentaerythritol/titanium dioxide/polymer (ethylene vinyl acetate (EVA) or styrene acrylate (SA). It has been established that adding nanoclay to a coating based on ethylene vinyl acetate increases the fire resistance limit of a metal plate by 30 %, and to a coating based on styrene acrylate – by 50 %. At the same time, coatings that include the EVA polymer are characterized by greater fire-retardant efficiency and less water resistance than coatings containing the SA polymer. It has been shown that intumescent coatings, regardless of the nature of the polymer, under the conditions of 80 % humidity over 800 days their reduce fire-protective properties by an average of 10 %. The loss of coating fire resistance occurs due to the leaching of pentaerythritol, ammonium polyphosphate, and polymer degradation by hydrolysis. The admixtures of nanoclays with a high degree of exfoliation to the studied system create a barrier effect and maximize the chemical formulation of the intumescent coating. The fireproof properties of coatings with organically-modified montmorillonite admixtures are maintained or reduced to 5 % under the conditions of 80 % humidity over 800 days. It has been determined that the direct effect of water on the coating over a period of more than 2 days leads to a significant decrease in the swelling coefficient of intumescent coatings, regardless of the content of a nanoclay admixture in their composition. At the same time, the half-decay period of coatings without nanoclay, calculated on the basis of solubility constant in water, is 0.5 days. For coatings, which include the admixtures of organically-modified nanoclays, the half-decay period increases to 2 days. The results reported in this paper could be recommended for designing water-proof fire-resistant reactive-type nano-coatings with prolonged service life.

COMPARATIVE STUDIES OF ETHYLENE VINYL ACETATE FILMS WITH VARIOUS SILICATE NANOCOMPOSITES

2019 ◽  
Vol 12 (04) ◽  
pp. 1803-1809
Author(s):  
A. Kaviarasi ◽  
M.V.L. Kumari ◽  
A.R. Prabakaran ◽  
A. Anandavadivel
Keyword(s):  
Vinyl Acetate ◽  
Comparative Studies ◽  
Ethylene Vinyl Acetate ◽  
Silicate Nanocomposites

Study of Ethylene Vinyl Acetate (EVA) Films used in Photovoltaic Modules

2018 ◽  
Vol 10 (5) ◽  
pp. 05043-1-05043-3 ◽  
Author(s):  
Rahul Kumar ◽  
◽  
Shashwata Chattopadhyay ◽  
Chetan Singh Solanki ◽  
Sarita Zele ◽  
...  
Keyword(s):  
Vinyl Acetate ◽  
Ethylene Vinyl Acetate ◽  
Photovoltaic Modules

scholarly journals Wastes from Agricultural Silage Film Recycling Line as a Potential Polymer Materials

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1383
Author(s):  
Jerzy Korol ◽  
Aleksander Hejna ◽  
Klaudiusz Wypiór ◽  
Krzysztof Mijalski ◽  
Ewelina Chmielnicka
Keyword(s):  
Vinyl Acetate ◽  
Thermal Performance ◽  
Mechanical Performance ◽  
Ethylene Vinyl Acetate ◽  
Tensile Tests ◽  
Solid Particles ◽  
Polymer Materials ◽  
Slight Reduction ◽  
Scanning Calorimetry ◽  
Crystallinity Degree

The recycling of plastics is currently one of the most significant industrial challenges. Due to the enormous amounts of plastic wastes generated by various industry branches, it is essential to look for potential methods for their utilization. In the presented work, we investigated the recycling potential of wastes originated from the agricultural films recycling line. Their structure and properties were analyzed, and they were modified with 2.5 wt % of commercially available compatibilizers. The mechanical and thermal performance of modified wastes were evaluated by tensile tests, thermogravimetric analysis, and differential scanning calorimetry. It was found that incorporation of such a small amount of modifiers may overcome the drawbacks caused by the presence of impurities. The incorporation of maleic anhydride-grafted compounds enhanced the tensile strength of wastes by 13–25%. The use of more ductile compatibilizers—ethylene-vinyl acetate and paraffin increased the elongation at break by 55–64%. The presence of compatibilizers also reduced the stiffness of materials resulting from the presence of solid particles. It was particularly emphasized for styrene-ethylene-butadiene-styrene and ethylene-vinyl acetate copolymers, which caused up to a 20% drop of Young’s modulus. Such effects may facilitate the further applications of analyzed wastes, e.g., in polymer film production. Thermal performance was only slightly affected by compatibilization. It caused a slight reduction in polyethylene melting temperatures (up to 2.8 °C) and crystallinity degree (up to 16%). For more contaminated materials, the addition of compatibilizers caused a minor reduction in the decomposition onset (up to 6 °C). At the same time, for the waste after three washing cycles, thermal stability was improved. Moreover, depending on the desired properties and application, materials do not have to go through the whole recycling line, simplifying the process, reducing energy and water consumption. The presented results indicate that it is possible to efficiently use the materials, which do not have to undergo the whole recycling process. Despite the presence of impurities, they could be applied in the manufacturing of products which do not require exceptional mechanical performance.

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