The effect of polypropylene maleic anhydride on polypropylene/(recycled acrylonitrile butadiene rubber)/(sugarcane bagasse) composite

2015 ◽  
Vol 23 (3) ◽  
pp. 228-233 ◽  
Author(s):  
Santiagoo Ragunathan ◽  
Zainal Mustaffa ◽  
Hussin Kamarudin ◽  
Sung Ting Sam ◽  
Hanafi Ismail
Keyword(s):  
Maleic Anhydride ◽  
Sugarcane Bagasse ◽  
Butadiene Rubber ◽  
Acrylonitrile Butadiene Rubber

Improvement of Poly(Lactic Acid) Properties by Using Acrylonitrile-Butadiene Rubber and Polyethylene-g-Maleic Anhydride

2019 ◽  
Vol 972 ◽  
pp. 178-184
Author(s):  
Sirirat Wacharawichanant ◽  
Chawisa Wisuttrakarn ◽  
Kasana Chomphunoi ◽  
Manop Phankokkruad
Keyword(s):  
Lactic Acid ◽  
Thermal Properties ◽  
Maleic Anhydride ◽  
Thermal Degradation ◽  
Impact Strength ◽  
Mass Loss ◽  
Poly Lactic Acid ◽  
Butadiene Rubber ◽  
Acrylonitrile Butadiene Rubber ◽  
The Impact

This research prepared poly(lactic acid) (PLA) and PLA/acrylonitrile-butadiene rubber (NBR) blends before and after adding polyethylene-g-maleic anhydride with 3 wt% of maleic anhydride (PE-g-MA3) 3 phr. The effects of NBR and PE-g-MA3 on morphological, mechanical and thermal properties of PLA and PLA blends were discussed. The morphological analysis observed the two-phase morphology of PLA/NBR blends, and it was observed the cavities generated due to NBR phase detachment during sample fracture, and droplets of NBR phase at higher NBR content. The PE-g-MA3 addition could improve adhesion between PLA and NBR phases due to the decrease of cavities in PLA matrix and droplet size of NBR. The mechanical properties showed the impact strength and strain at break of PLA/NBR blends dramatically increased when the amount of NBR increasing. The addition of PE-g-MA3 significantly improved the impact strength of PLA/NBR blends. The thermal properties showed the NBR addition had effect slightly on the melting temperature of PLA/NBR blends. The filling of NBR and PE-g-MA3 greatly decreased the percent crystallinity of PLA more than two times. The thermal degradation of pure PLA and NBR proceeds by one step, while the thermal degradation process of PLA/NBR and PLA/PE-g-MA3 proceeds by two steps. Which the first step showed a large mass loss of PLA degradation and the second step showed a small mass loss of PE-g-MA and NBR degradation.

Thermal and mechanical properties of chemical modification on sugarcane bagasse mixed with polypropylene and recycle acrylonitrile butadiene rubber composite

2019 ◽  
Vol 33 (11) ◽  
pp. 1533-1554 ◽  
Author(s):  
Mustaffa Zainal ◽  
Ragunathan Santiagoo ◽  
Afizah Ayob ◽  
Azlinda Abdul Ghani ◽  
Wan Azani Mustafa ◽  
...  
Keyword(s):  
Chemical Modification ◽  
Tensile Properties ◽  
Sugarcane Bagasse ◽  
Chemical Properties ◽  
Infrared Analysis ◽  
Butadiene Rubber ◽  
Acrylonitrile Butadiene Rubber ◽  
Degradation Temperature ◽  
Roll Mill ◽  
Rubber Composite

The goal of this research is to investigate the thermal, chemical, and tensile properties of chemical modification of sugarcane bagasse (SCB)-filled polypropylene (PP) and recycled acrylonitrile butadiene rubber (NBRr). The composites with different SCB loading (5, 15, and 30 per hundred resin) were prepared using a heated two-roll mill at temperature of 180°C.Thermal and the tensile properties of the modified SCB composite have shown improvement. The silane-treated composites have higher thermal stability compared to treated NaOH. The degradation temperature at 70% weight ( T 70%) of NaOH and silane composite increase by 6% and 15%, respectively. Meanwhile, the tensile strength and Young’s modulus for the both treatment showed an improvement of 20% and 25% for NaOH and 30% and 32% for silane compared to untreated composites, respectively. The chemical properties were investigated using Fourier transform infrared analysis. The modification SCB fiber has improved the adhesion and interfacial bonding between SCB fiber and PP/NBRr matrices.

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