Effect of zinc oxide and testing rate on the adhesion property of styrene-butadiene rubber/standard Malaysian rubber blend adhesives

2014 ◽  
Vol 22 (1) ◽  
pp. 3-7 ◽  
Author(s):  
Beng Teik Poh ◽  
Yin Yin Teh
Keyword(s):  
Zinc Oxide ◽  
Adhesion Property ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Blend ◽  
Testing Rate ◽  
Styrene Butadiene

Studies on Dicumyl Peroxide Vulcanization of Styrene—Butadiene Rubber in Presence of Sulfur and 2-Mercaptobenzothiazole

1974 ◽  
Vol 47 (2) ◽  
pp. 266-281 ◽  
Author(s):  
C. K. Das ◽  
S. Banerjee
Keyword(s):  
Zinc Oxide ◽  
Stearic Acid ◽  
Crosslink Density ◽  
Addition Reaction ◽  
Styrene Butadiene Rubber ◽  
Methyl Groups ◽  
Butadiene Rubber ◽  
First Order ◽  
First Order Kinetics ◽  
Styrene Butadiene

Abstract The effect of sulfur, MBT, zinc oxide, and stearic acid on the DCP vulcanization of SBR has been studied. DCP decomposition obeys first order kinetics in all cases, but its rate constant is higher in presence of MBT. Sulfur and MBT reduce the crosslink density due to DCP. In the mixes containing sulfur, MBT, zinc oxide, and stearic acid in presence of DCP the crosslink density is initially additive. Here oxidation of some pendent vinyl groups are effected by DCP, and these groups also take part in thiol addition reaction with MBT. The thiazole accelerated sulfuration of SBR proceeds fundamentally by the same mechanism as reported for NR, but the details show slight difference chiefly due to the presence of pendent vinyl groups and styrene units in the chain and due to the absence of pendent methyl groups in SBR.

scholarly journals Organic Zinc Salts as Pro-Ecological Activators for Sulfur Vulcanization of Styrene–Butadiene Rubber

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1723 ◽  
Author(s):  
Magdalena Maciejewska ◽  
Anna Sowińska ◽  
Judyta Kucharska
Keyword(s):  
Zinc Oxide ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Zinc Ions ◽  
Organic Zinc ◽  
Rubber Compounds ◽  
Curing Characteristics ◽  
Sulfur Vulcanization ◽  
Zinc Salts ◽  
Styrene Butadiene

Organic zinc salts and complexes were applied as activators for sulfur vulcanization of styrene–butadiene elastomer (SBR) in order to reduce the content of zinc ions in rubber compounds as compared with conventionally used zinc oxide. In this article, the effects of different organic zinc activators on the curing characteristics, crosslink densities, and mechanical properties of SBR as well as the aging resistance and thermal behavior of vulcanizates are discussed. Organic zinc salts seem to be good substitutes for zinc oxide as activators for sulfur vulcanization of SBR rubber, without detrimental effects to the vulcanization time and temperature. Moreover, vulcanizates containing organic zinc salts exhibit higher tensile strength and better damping properties than vulcanizate crosslinked with zinc oxide. The application of organic zinc activators allows the amount of zinc ions in SBR compounds to be reduced by 70–90 wt % compared to vulcanizate with zinc oxide. This is very important for ecological reasons, since zinc oxide is classified as being toxic to aquatic species.

Rubber Blend of 80/20 NR/SBR Reinforced with Nanosilica and PS-Encapsulated Nanosilica

2011 ◽  
Vol 695 ◽  
pp. 332-335 ◽  
Author(s):  
Anyaporn Boonmahitthisud ◽  
Zheng Hua Song
Keyword(s):  
Sodium Dodecyl ◽  
Dry Weight ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Mechanical And Thermal Properties ◽  
Butadiene Rubber ◽  
Rubber Blends ◽  
Rubber Blend ◽  
Styrene Butadiene

In this study, rubber blend of natural rubber (NR) and styrene butadiene rubber (SBR) at 80/20 NR/SBR was reinforced with nanosilica (nSiO2) and polystyrene-encapsulated nanosilica (PS-nSiO2) in the latex state. The latex of PS-nSiO2 was synthesized by in situ differential microemulsion polymerization using sodium dodecyl sulfate and azobisisobutyronitrile as the surfactant and initiator, respectively. The nanoparticles at the amount of 0.1, 0.2, 0.3 and 0.4 parts per hundred of rubber (based on dry weight of nSiO2) were dispersed in the rubber blend compound and subsequently cured at 80°C for 3 h to prepare rubber nanocomposites. Using this technique, nanoparticles could be well dispersed in the rubber matrix. The influences of the nSiO2 and PS-nSiO2 on the mechanical and thermal properties of the resulting nanocomposites were quantified and compared. It is found that the tensile properties and thermal stability of the rubber blends were improved with the appropriate amounts of the nanofillers. However, the PS-nSiO2 exhibited reinforcing efficiency superior to nSiO2 with the same nSiO2 content due to the stronger rubber-filler interfacial adhesion.

On the properties and processing of polyethylene terephthalate/styrene-butadiene rubber blend

2000 ◽  
Vol 40 (5) ◽  
pp. 1216-1225 ◽  
Author(s):  
A. Sánchez-Solís ◽  
M. R. Estrada ◽  
J. Cruz ◽  
O. Manero
Keyword(s):  
Polyethylene Terephthalate ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Blend ◽  
Styrene Butadiene
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