Comparative study on tensile properties and microstructure development in elastomer-modified cyclic olefin copolymer

2014 ◽  
Vol 22 (3) ◽  
pp. 222-230 ◽  
Author(s):  
Seyed Hassan Jafari ◽  
Hossein Ali Khonakdar ◽  
Mohammad Tarameshlou ◽  
Mohammad Reza Saeb
2017 ◽  
Vol 2017 ◽  
pp. 1-10 ◽  
Author(s):  
Mario H. Gutiérrez-Villarreal ◽  
Sara A. Zavala-Betancourt

A series of commercial cyclic olefin copolymers (COC), namely, ethylene-norbornene (E-NB) and ethylene-tetracyclododecene (E-TD), were processed as thin films with thicknesses of 25 μm by an extrusion process. The photodegradation of neat and formulated films with different metal stearates (Fe, Co, and Mn) was investigated using an ultraviolet (UV) light lamp (340 nm) for a period of 30 days in an accelerated weathering tester model QUV from Q-LAB according to the ASTM D 5208-01 standard practice. Changes in carbonyl index (CI) and tensile properties were used to evaluate the photodegradation of the films and other properties, such as Tg variation by DSC, were also analyzed. The present study reveals that (E-NB) copolymers show higher sensitivity to photodegradation than (E-TD) resins, in the absence and presence of metal stearates. We also find that the Fe salt shows the highest oxidative activity.


2019 ◽  
Vol 10 (41) ◽  
pp. 5578-5583 ◽  
Author(s):  
Takumitsu Kida ◽  
Ryo Tanaka ◽  
Koh-hei Nitta ◽  
Takeshi Shiono

The increase of aggregation number in a star-shaped cyclic olefin copolymer was succeeded by using a triazine-based secondary amine, which caused a drastic change in physical properties without changing the thermal properties.


2009 ◽  
Vol 210 (9) ◽  
pp. 728-735 ◽  
Author(s):  
Filippo Donati ◽  
Andrea Pucci ◽  
Laura Boggioni ◽  
Incoronata Tritto ◽  
Giacomo Ruggeri

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2305
Author(s):  
Fadi Dawaymeh ◽  
Yawar Abbas ◽  
Maryam Khaleel ◽  
Anas Alazzam ◽  
Nahla Alamoodi

Selective altering of surface wettability in microfluidic channels provides a suitable platform for a large range of processes, such as the phase separation of multiphase systems, synthesis of reaction controlled, nanoliter sized droplet reactors, and catalyst impregnation. Herein we study the feasibility to tune the wettability of a flexible cyclic olefin copolymer (COC). Two methods were considered for enhancing the surface hydrophilicity. The first is argon/oxygen plasma treatment, where the effect of treatment duration on water contact angle and COC surface morphology and chemistry were investigated, and the second is coating COC with GO dispersions of different concentrations. For enhancing the hydrophobicity of GO-coated COC surfaces, three reduction methods were considered: chemical reduction by Hydroiodic acid (HI), thermal reduction, and photo reduction by exposure of GO-coated COC to UV light. The results show that as the GO concentration and plasma treatment duration increased, a significant decrease in contact angle was observed, which confirmed the ability to enhance the wettability of the COC surface. The increase in hydrophilicity during plasma treatment was associated with the increase in surface roughness on the treated surfaces, while the increase during GO coating was associated with introducing oxygen-containing groups on the GO-coated COC surfaces. The results also show that the different reduction methods considered can increase the contact angle and improve the hydrophobicity of a GO-coated COC surface. It was found that the significant improvement in hydrophobicity was related to the reduction of oxygen-containing groups on the GO-coated COC modified surface.


2021 ◽  
Author(s):  
Hui Wang ◽  
◽  
Yan Li ◽  
Xiaolin Wang ◽  
Zhe Liu ◽  
...  

2019 ◽  
Vol 37 ◽  
pp. 168-176 ◽  
Author(s):  
Myeong Gu Gang ◽  
Ki Woon Chae ◽  
Wook-Bae Kim ◽  
Young Hun Jung ◽  
Martin B.G. Jun ◽  
...  

2018 ◽  
Vol 59 (3) ◽  
pp. 447-456 ◽  
Author(s):  
Ali Hosseinpour ◽  
Rasool Nasseri ◽  
Sina Ghiassinejad ◽  
Milad Mehranpour ◽  
Ali Asghar Katbab ◽  
...  

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