Processability and characterization of poly(vinyl chloride)-b-poly(n-butyl acrylate)-b-poly(vinyl chloride) prepared by living radical polymerization of vinyl chloride. Comparison with a flexible commercial resin formulation prepared with PVC and dioctyl phthalate

2006 ◽  
Vol 12 (4) ◽  
pp. 156-165 ◽  
Author(s):  
Jorge F.J. Coelho ◽  
Mafalda Carreira ◽  
Pedro M.O.F. Gonçalves ◽  
Anatoliy V. Popov ◽  
Maria H. Gil
Keyword(s):  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Butyl Acrylate ◽  
Dioctyl Phthalate ◽  
Living Radical Polymerization ◽  
Commercial Resin ◽  
Poly Vinyl Chloride ◽  
Resin Formulation

Scale-up of Poly[(Vinyl Chloride)-b-(n-Butyl Acrylate)-b-(Vinyl Chloride)] prepared by Living Radical Polymerization

2006 ◽  
Vol 514-516 ◽  
pp. 975-979 ◽  
Author(s):  
Jorge F.J. Coelho ◽  
Patricia Alves ◽  
Joana Monteiro ◽  
M. Margarida C.A. Castro ◽  
Mariana Abreu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Scale Up ◽  
Living Radical Polymerization ◽  
Poly Vinyl Chloride

Vinyl Chloride (VCM) based copolymers were synthesised by using Living Radical Polymerization. The obtained materials were characterized by determining their molecular weight, glass transition temperature and mechanical properties after processing in industrial equipments. Their chemical composition was evaluated by using NMR.

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