Different types of V amylose–lipid inclusion complexes in maize extrudates revealed by DSC analysis

The tripod molecule tris(5-acetyl-3-thienyl)methane (TATM) is a flexile molecule, i.e. one that can occur in many conformationally isomeric states (conformers), which forms host–guest inclusion complexes with a large variety of guests (solvents). Some 40-odd different types of guest have been reported to form inclusion complexes. Five different types of crystal structure (all racemic), with nine different guests, have been reported in the literature and structural information is available for 17 crystallographically independent TATM molecules; most of the guests are disordered. Our analysis of this (substantial but, nevertheless, incomplete) database shows that each group of crystallographically isomorphous structures contains a particular TATM conformer with characteristic torsion angles about the bonds between methane carbon and the three thienyl rings (τ1, τ2 and τ3); the range of torsion angles in a particular structural group does not exceed 10°. Conformers are in addition distinguished via the stereochemistry of the acetyl group; there are approximately equal numbers of examples with carbonyl oxygen syn or anti to ring sulfur, intermediate conformations not being found. So far three different types of conformer have been encountered for the TATM molecule considered as an entity. A necessary condition for the occurrence of a particular conformer type is that the torsion angles τ1, τ2 and τ3 are such that ring H atoms should not approach more closely than (say) 2.4 Å, but this is not sufficient as considerably larger distances are found in some conformer types. Crystallization of the inclusion complex from a particular solvent can be envisaged to occur as follows. The TATM solution will contain a Boltzmann distribution of host conformers, the distribution depending on temperature but not on the nature of the solvent. Under suitable temperature and solubility conditions, the solvent will crystallize together with the appropriate conformer to form the inclusion complex-nuclei formed at this recognition stage, then grow into crystallites of the inclusion complex. The perturbed Boltzmann distribution (depleted in appropriate conformer) will continuously revert to its equilibrium form by conversion of the non-appropriate into the appropriate conformer as the crystallization proceeds.

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Comparative Morphological Investigation between Natural Photo-Aged of Two Different Low Density Polyethylene Green House Covers

SOJ Materials Science & Engineering ◽

10.15226/sojmse.2021.00167 ◽

2021 ◽

Vol 8 (1) ◽

pp. 1-4

Author(s):

BabaghayouMeriam Imane ◽

AbdelHamid Ismail Mourad

Keyword(s):

Degree Of Crystallinity ◽

Low Density Polyethylene ◽

Low Density ◽

Natural Ageing ◽

Dsc Analysis ◽

Polyethylene Films ◽

Extruded Films ◽

Different Types ◽

Degradation Behaviors ◽

Better Than

This work studies and compares the degradation performance of two different types of blown extruded films of low density polyethylene films used as greenhouse covers. The first one is LDPE (B24/2) supplied by ENIP Skikda and the other one is LDPE (2100 T N00W) supplied by SABIC, Saudi Arabia. Both films are commonly used in Algeria as greenhouse covers. The films were exposed outdoors over a period of 8 months for natural ageing. XRD and DSC analysis were conducted to characterize the thermal properties of the materials and compare between their degradation behaviors. The results revealed that the degradation resistance of LDPE (B24/2) is better than LDPE (2100T N00W) in term of their degree of crystallinity. Keywords: Natural Ageing, LDPE (B24/2); LDPE (2100 T N00W); Degree of Crystallinity, XRD; DSC.

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The extinction time of a general birth and death process with catastrophes

Journal of Applied Probability ◽

10.1017/s0021900200116031 ◽

1986 ◽

Vol 23 (04) ◽

pp. 851-858 ◽

Cited By ~ 1

Author(s):

P. J. Brockwell

Keyword(s):

Laplace Transform ◽

Size Distribution ◽

Sufficient Conditions ◽

Necessary And Sufficient Conditions ◽

Death Process ◽

Extinction Time ◽

Birth And Death Process ◽

Different Types ◽

The Laplace Transform ◽

Necessary And Sufficient

The Laplace transform of the extinction time is determined for a general birth and death process with arbitrary catastrophe rate and catastrophe size distribution. It is assumed only that the birth rates satisfyλ0= 0,λj> 0 for eachj> 0, and. Necessary and sufficient conditions for certain extinction of the population are derived. The results are applied to the linear birth and death process (λj=jλ, µj=jμ) with catastrophes of several different types.

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Differentiating between different forms of moral obligations

Behavioral and Brain Sciences ◽

10.1017/s0140525x19002589 ◽

2020 ◽

Vol 43 ◽

Author(s):

Rajen A. Anderson ◽

Benjamin C. Ruisch ◽

David A. Pizarro

Keyword(s):

Moral Character ◽

Moral Obligations ◽

Different Types

Abstract We argue that Tomasello's account overlooks important psychological distinctions between how humans judge different types of moral obligations, such as prescriptive obligations (i.e., what one should do) and proscriptive obligations (i.e., what one should not do). Specifically, evaluating these different types of obligations rests on different psychological inputs and has distinct downstream consequences for judgments of moral character.

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Ultrastructural Investigations of the Contractile Filaments of Amoebae

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100050950 ◽

1974 ◽

Vol 32 ◽

pp. 188-189

Author(s):

P.L. Moore

Keyword(s):

Cytoplasmic Streaming ◽

Three Dimensional ◽

Freeze Fracture ◽

Amoeboid Movement ◽

Different Types ◽

Chemical Conditions ◽

Complete Interpretation

Previous freeze fracture results on the intact giant, amoeba Chaos carolinensis indicated the presence of a fibrillar arrangement of filaments within the cytoplasm. A complete interpretation of the three dimensional ultrastructure of these structures, and their possible role in amoeboid movement was not possible, since comparable results could not be obtained with conventional fixation of intact amoebae. Progress in interpreting the freeze fracture images of amoebae required a more thorough understanding of the different types of filaments present in amoebae, and of the ways in which they could be organized while remaining functional.The recent development of a calcium sensitive, demembranated, amoeboid model of Chaos carolinensis has made it possible to achieve a better understanding of such functional arrangements of amoeboid filaments. In these models the motility of demembranated cytoplasm can be controlled in vitro, and the chemical conditions necessary for contractility, and cytoplasmic streaming can be investigated. It is clear from these studies that “fibrils” exist in amoeboid models, and that they are capable of contracting along their length under conditions similar to those which cause contraction in vertebrate muscles.

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Study of the Molecular Architecture of Keratin Filaments by Electron Microscopy

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100053310 ◽

1982 ◽

Vol 40 ◽

pp. 118-119

Author(s):

U. Aebi ◽

P. Rew ◽

T.-T. Sun

Keyword(s):

Electron Microscopy ◽

Structural Organization ◽

Cell Types ◽

Structural Features ◽

Molecular Architecture ◽

The Past ◽

Keratin Filaments ◽

Different Types ◽

10 Nm Filaments ◽

Different Cell Types

Various types of intermediate-sized (10-nm) filaments have been found and described in many different cell types during the past few years. Despite the differences in the chemical composition among the different types of filaments, they all yield common structural features: they are usually up to several microns long and have a diameter of 7 to 10 nm; there is evidence that they are made of several 2 to 3.5 nm wide protofilaments which are helically wound around each other; the secondary structure of the polypeptides constituting the filaments is rich in ∞-helix. However a detailed description of their structural organization is lacking to date.

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A New Defect in Polyethylene Single Crystals

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100070795 ◽

1973 ◽

Vol 31 ◽

pp. 70-71

Author(s):

E. L. Thomas ◽

S. L. Sass

Keyword(s):

Single Crystals ◽

Screw Dislocation ◽

Small Distance ◽

Dipole Model ◽

Dislocation Dipole ◽

Chain Folding ◽

Black And White ◽

Polymer Crystal ◽

Different Types

In polyethylene single crystals pairs of black and white lines spaced 700-3,000Å apart, parallel to the [100] and [010] directions, have been identified as microsector boundaries. A microsector is formed when the plane of chain folding changes over a small distance within a polymer crystal. In order for the different types of folds to accommodate at the boundary between the 2 fold domains, a staggering along the chain direction and a rotation of the chains in the plane of the boundary occurs. The black-white contrast from a microsector boundary can be explained in terms of these chain rotations. We demonstrate that microsectors can terminate within the crystal and interpret the observed terminal strain contrast in terms of a screw dislocation dipole model.

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Methionine-Specific Staining of Collagen

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010005408x ◽

1982 ◽

Vol 40 ◽

pp. 294-295

Author(s):

E.M. Kuhn ◽

K.D. Marenus ◽

M. Beer

Keyword(s):

Amino Acids ◽

Collagen Fibers ◽

Type Iii Collagen ◽

Type I ◽

Electron Microscopic ◽

Good Correspondence ◽

Specific Staining ◽

Type Iii ◽

Different Types ◽

Sulfur Containing

Fibers composed of different types of collagen cannot be differentiated by conventional electron microscopic stains. We are developing staining procedures aimed at identifying collagen fibers of different types.Pt(Gly-L-Met)Cl binds specifically to sulfur-containing amino acids. Different collagens have methionine (met) residues at somewhat different positions. A good correspondence has been reported between known met positions and Pt(GLM) bands in rat Type I SLS (collagen aggregates in which molecules lie adjacent to each other in exact register). We have confirmed this relationship in Type III collagen SLS (Fig. 1).

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Identification of Asbestos Fibres in a Water Sample by X-Ray Microanalysis

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100114992 ◽

1975 ◽

Vol 33 ◽

pp. 274-275

Author(s):

K. A. Brookes ◽

D. Finbow ◽

Madeleine Samuel

Keyword(s):

Water Sample ◽

Background Radiation ◽

X Ray ◽

Left Hand ◽

Transmission Imaging ◽

Different Types ◽

Normal Specimen ◽

Liquid Nitrogen Cooling ◽

Normal Transmission ◽

Additional Port

Investigation of the particulate matter contained in the water sample, revealed the presence of a number of different types and certain of these were selected for analysis.An A.E.I. Corinth electron microscope was modified to accept a Kevex Si (Li) detector. To allow for existing instruments to be readily modified, this was kept to a minimum. An additional port is machined in the specimen region to accept the detector, with the liquid nitrogen cooling dewar conveniently housed in the left hand cupboard adjacent to the microscope column. Since background radiation leads to loss in the sensitivity of the instrument, great care has been taken to reduce this effect by screening and manufacturing components that are near the specimen from material of low atomic number. To change from normal transmission imaging to X-ray analysis, the special 4-position specimen rod is inserted through the normal specimen airlock.

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Backscattered Electron Imaging of GaAs/AlGaAs Super Lattice Structures with an Ultra-High- Resolution SEM

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100103103 ◽

1988 ◽

Vol 46 ◽

pp. 204-205

Author(s):

Kazumichi Ogura ◽

Michael M. Kersker

Keyword(s):

High Resolution ◽

Layer Structure ◽

High Sensitivity ◽

Beam Current ◽

Electron Beam Current ◽

Lattice Structures ◽

Super Lattice ◽

Different Types ◽

Backscattered Electron ◽

Electron Imaging

Backscattered electron (BE) images of GaAs/AlGaAs super lattice structures were observed with an ultra high resolution (UHR) SEM JSM-890 with an ultra high sensitivity BE detector. Three different types of super lattice structures of GaAs/AlGaAs were examined. Each GaAs/AlGaAs wafer was cleaved by a razor after it was heated for approximately 1 minute and its crosssectional plane was observed.First, a multi-layer structure of GaAs (100nm)/AlGaAs (lOOnm) where A1 content was successively changed from 0.4 to 0.03 was observed. Figures 1 (a) and (b) are BE images taken at an accelerating voltage of 15kV with an electron beam current of 20pA. Figure 1 (c) is a sketch of this multi-layer structure corresponding to the BE images. The various layers are clearly observed. The differences in A1 content between A1 0.35 Ga 0.65 As, A1 0.4 Ga 0.6 As, and A1 0.31 Ga 0.69 As were clearly observed in the contrast of the BE image.

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