Nonhalogenated Solvent‐Processed Thick‐Film Ternary Nonfullerene Organic Solar Cells with Power Conversion Efficiency >13% Enabled by a New Wide‐Bandgap Polymer

Solar RRL ◽  
2021 ◽  
pp. 2000787
Author(s):  
Thavamani Gokulnath ◽  
Saripally Sudhaker Reddy ◽  
Ho-Yeol Park ◽  
Junyoung Kim ◽  
Jehan Kim ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Thick Film ◽  
Conversion Efficiency ◽  
Organic Solar Cells ◽  
Power Conversion ◽  
Wide Bandgap ◽  
Wide Bandgap Polymer

The Effect of Donor Molecular Structure on Power Conversion Efficiency of Small-Molecule-Based Organic Solar Cells

2019 ◽  
Vol 16 (3) ◽  
pp. 236-243 ◽  
Author(s):  
Hui Zhang ◽  
Yibing Ma ◽  
Youyi Sun ◽  
Jialei Liu ◽  
Yaqing Liu ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Molecular Design ◽  
Power Conversion ◽  
The Relationship

In this review, small-molecule donors for application in organic solar cells reported in the last three years are highlighted. Especially, the effect of donor molecular structure on power conversion efficiency of organic solar cells is reported in detail. Furthermore, the mechanism is proposed and discussed for explaining the relationship between structure and power conversion efficiency. These results and discussions draw some rules for rational donor molecular design, which is very important for further improving the power conversion efficiency of organic solar cells based on the small-molecule donor.

scholarly journals High performance tandem organic solar cells via a strongly infrared-absorbing narrow bandgap acceptor

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhenrong Jia ◽  
Shucheng Qin ◽  
Lei Meng ◽  
Qing Ma ◽  
Indunil Angunawela ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Organic Solar Cells ◽  
High Performance ◽  
Short Circuit ◽  
Power Conversion ◽  
High Power Conversion Efficiency ◽  
Device Structure ◽  
Narrow Bandgap

AbstractTandem organic solar cells are based on the device structure monolithically connecting two solar cells to broaden overall absorption spectrum and utilize the photon energy more efficiently. Herein, we demonstrate a simple strategy of inserting a double bond between the central core and end groups of the small molecule acceptor Y6 to extend its conjugation length and absorption range. As a result, a new narrow bandgap acceptor BTPV-4F was synthesized with an optical bandgap of 1.21 eV. The single-junction devices based on BTPV-4F as acceptor achieved a power conversion efficiency of over 13.4% with a high short-circuit current density of 28.9 mA cm−2. With adopting BTPV-4F as the rear cell acceptor material, the resulting tandem devices reached a high power conversion efficiency of over 16.4% with good photostability. The results indicate that BTPV-4F is an efficient infrared-absorbing narrow bandgap acceptor and has great potential to be applied into tandem organic solar cells.

scholarly journals Digital printing of a novel electrode for stable flexible organic solar cells with a power conversion efficiency of 8.5%

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
S. Wageh ◽  
Mahfoudh Raïssi ◽  
Thomas Berthelot ◽  
Matthieu Laurent ◽  
Didier Rousseau ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Organic Solar Cells ◽  
Power Conversion ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Solution Processed ◽  
Transparent Conducting

AbstractPoly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) mixed with single-wall nanotubes (SWNTs) (10:1) and doped with (0.1 M) perchloric acid (HClO4) in a solution-processed film, working as an excellent thin transparent conducting film (TCF) in organic solar cells, was investigated. This new electrode structure can be an outstanding substitute for conventional indium tin oxide (ITO) for applications in flexible solar cells due to the potential of attaining high transparency with enhanced conductivity, good flexibility, and good durability via a low-cost process over a large area. In addition, solution-processed vanadium oxide (VOx) doped with a small amount of PEDOT-PSS(PH1000) can be applied as a hole transport layer (HTL) for achieving high efficiency and stability. From these viewpoints, we investigate the benefit of using printed SWNTs-PEDOT-PSS doped with HClO4 as a transparent conducting electrode in a flexible organic solar cell. Additionally, we applied a VOx-PEDOT-PSS thin film as a hole transporting layer and a blend of PTB7 (polythieno[3,4-b] thiophene/benzodithiophene): PC71BM (phenyl-C71-butyric acid methyl ester) as an active layer in devices. Zinc oxide (ZnO) nanoparticles were applied as an electron transport layer and Ag was used as the top electrode. The proposed solar cell structure showed an enhancement in short-circuit current, power conversion efficiency, and stability relative to a conventional cell based on ITO. This result suggests a great carrier injection throughout the interfacial layer, high conductivity and transparency, as well as firm adherence for the new electrode.

Organic cathode interfacial materials for non-fullerene organic solar cells

2021 ◽  
Author(s):  
Minkyu Kyeong ◽  
Jinho Lee ◽  
Matyas Daboczi ◽  
Katherine Stewart ◽  
Huifeng Yao ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
High Power ◽  
Organic Solar Cells ◽  
Power Conversion ◽  
High Power Conversion Efficiency ◽  
Amine Groups

Functionalized polyethyleneimines that are compatible with non-fullerene acceptors have been developed by protecting the reactive amine groups, leading to non-fullerene solar cells with high power conversion efficiency and enhanced thermal stability.

Effect of temperature on organic Schottky barrier cells

1981 ◽  
Vol 59 (6) ◽  
pp. 727-732 ◽  
Author(s):  
Rafik O. Loutfy ◽  
Cheng-Kuo Hsiao
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Schottky Barrier ◽  
Conversion Efficiency ◽  
Organic Solar Cells ◽  
Short Circuit ◽  
Power Conversion ◽  
Open Circuit ◽  
Effect Of Temperature ◽  
Photovoltaic Properties

The effect of temperature on the photovoltaic properties of indium/metal-free phthalocyanine Schottky barrier solar cells was investigated in the range 260–350 K. In general, the short circuit photocurrent, Jsc, and fill factor, ff, increased with increasing temperature (in contrast to inorganic photocells). The device series resistance and open circuit photovoltage, Voc, decreased (similar to inorganic photocells) as temperature was raised. An increase in the overall power conversion efficiency, η, has been observed with increase of temperature. In the case of x-H2Pc, the power conversion efficiency increased by 2.5 times due to a temperature rise of 60 °C above ambient. Thus, for operation at temperatures above ambient, organic solar cells may offer a significant advantage over inorganic cells.Analysis of the variation of the photovoltage with temperature showed that the decrease in Voc is mainly due to variation injunction impedance, which is controlled by thermionic current at high temperature and ionized impurity at low temperature.

Wide-Bandgap Organic-Inorganic Hybrid and All-Inorganic Perovskite Solar Cells and their Application in All-Perovskite Tandem Solar Cells

2021 ◽  
Author(s):  
Rui He ◽  
Shengqiang Ren ◽  
Cong Chen ◽  
Zongjin Yi ◽  
Yi Luo ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Rapid Development ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Wide Bandgap ◽  
Tandem Solar Cells ◽  
Inorganic Hybrid ◽  
The Past

The past decade has witnessed rapid development of perovskite solar cells (PSCs), the record power conversion efficiency (PCE) of which has been rapidly boosted from the initial 3.8% to a...

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