scholarly journals High‐Efficiency Organic Solar Cells with Wide Toleration of Active Layer Thickness

Solar RRL ◽  
2020 ◽  
Vol 4 (10) ◽  
pp. 2000476
Author(s):  
Kangkang Weng ◽  
Linglong Ye ◽  
Chao Li ◽  
Zichao Shen ◽  
Jinqiu Xu ◽  
...  
2021 ◽  
Author(s):  
Yanming Sun ◽  
Yunhao Cai ◽  
Qian Li ◽  
Guanyu Lu ◽  
Hwa Sook Ryu ◽  
...  

Abstract The development of high-performance organic solar cells (OSCs) with thick active layers is of crucial importance for the roll-to-roll printing of large-area solar panels. Unfortunately, increasing the active layer thickness usually results in a significant reduction in efficiency. Herein, we fabricated efficient thick-film OSCs with an active layer consisting of one polymer donor and two non-fullerene acceptors. The two acceptors were found to possess enlarged exciton diffusion length in the mixed phase, which is beneficial to exciton generation and dissociation. Additionally, layer by layer approach was employed to optimize the vertical phase separation. Benefiting from the synergetic effects of enlarged exciton diffusion length and graded vertical phase separation, a record high efficiency of 17.31% (certified value of 16.9%) was obtained for the 300 nm-thick OSC, with an unprecedented short-circuit current density of 28.36 mA cm−2, and a high fill factor of 73.0%. Moreover, the device with an active layer thickness of 500 nm also shows a record efficiency of 15.21%. This work provides new insights into the fabrication of high-efficiency OSCs with thick active layers.


2013 ◽  
Vol 14 (1) ◽  
pp. 74-79 ◽  
Author(s):  
Gon Namkoong ◽  
Jaemin Kong ◽  
Matthew Samson ◽  
In-Wook Hwang ◽  
Kwanghee Lee

2015 ◽  
Vol 3 (44) ◽  
pp. 22274-22279 ◽  
Author(s):  
Qian Zhang ◽  
Bin Kan ◽  
Xiangjian Wan ◽  
Hua Zhang ◽  
Feng Liu ◽  
...  

The thickness dependence of the photovoltaic performance for devices based on the small molecule DR3TSBDT:PC71BM was systematically investigated and the power conversion efficiencies are found to be relatively insensitive to the thickness.


2013 ◽  
Vol 1 (39) ◽  
pp. 12345 ◽  
Author(s):  
Antonio Guerrero ◽  
Núria F. Montcada ◽  
Jon Ajuria ◽  
Ikerne Etxebarria ◽  
Roberto Pacios ◽  
...  

2019 ◽  
Vol 9 (45) ◽  
pp. 1902688 ◽  
Author(s):  
Yamin Zhang ◽  
Huanran Feng ◽  
Lingxian Meng ◽  
Yanbo Wang ◽  
Meijia Chang ◽  
...  

2019 ◽  
Vol 6 (1-2) ◽  
pp. 23-28 ◽  
Author(s):  
Megha Grover ◽  
Monika Nehra ◽  
Deepak Kedia

Abstract Organic solar cells deal with small organic molecules for absorption of light at low cost and high efficiency. In this paper, we have analyzed the photovoltaic (PV) characteristics of double heterojunction solar cell that consists of copper phthalocyanine (CuPc) and 3,4,9,10-perylenetetracarboxylic bis-benzimidazole (PTCBI) thin films. Here, CuPc and PTCBI layers are combined by an interfacial layer consisting of nanoscale dots. Different plasmonic materials (i. e. Ag, Au, and graphene) are selected as alternative nanoscale dot layer to examine their effect on solar cell performance. Further, the solar cell performance is also examined via variation in active layer thickness. The choice of interfacial layer material and variation in active layer thickness offer grounds for future efficient PV cells.


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