Atomistic Insight Into Donor/Acceptor Interfaces in High-Efficiency Nonfullerene Organic Solar Cells

Solar RRL ◽  
2018 ◽  
Vol 2 (11) ◽  
pp. 1800190 ◽  
Author(s):  
Guangchao Han ◽  
Yuan Guo ◽  
Xiaoyi Ma ◽  
Yuanping Yi
2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ruimin Zhou ◽  
Zhaoyan Jiang ◽  
Chen Yang ◽  
Jianwei Yu ◽  
Jirui Feng ◽  
...  

AbstractThe high efficiency all-small-molecule organic solar cells (OSCs) normally require optimized morphology in their bulk heterojunction active layers. Herein, a small-molecule donor is designed and synthesized, and single-crystal structural analyses reveal its explicit molecular planarity and compact intermolecular packing. A promising narrow bandgap small-molecule with absorption edge of more than 930 nm along with our home-designed small molecule is selected as electron acceptors. To the best of our knowledge, the binary all-small-molecule OSCs achieve the highest efficiency of 14.34% by optimizing their hierarchical morphologies, in which the donor or acceptor rich domains with size up to ca. 70 nm, and the donor crystals of tens of nanometers, together with the donor-acceptor blending, are proved coexisting in the hierarchical large domain. All-small-molecule photovoltaic system shows its promising for high performance OSCs, and our study is likely to lead to insights in relations between bulk heterojunction structure and photovoltaic performance.


2017 ◽  
Vol 29 (5) ◽  
pp. 2135-2140 ◽  
Author(s):  
Jaeyoung Hwang ◽  
Jeonghun Park ◽  
Yu Jin Kim ◽  
Yeon Hee Ha ◽  
Chan Eon Park ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jing Wang ◽  
Xudong Jiang ◽  
Hongbo Wu ◽  
Guitao Feng ◽  
Hanyu Wu ◽  
...  

AbstractThe high voltage losses ($${V}_{{loss}}$$ V l o s s ), originating from inevitable electron-phonon coupling in organic materials, limit the power conversion efficiency of organic solar cells to lower values than that of inorganic or perovskite solar cells. In this work, we demonstrate that this $${V}_{{loss}}$$ V l o s s can in fact be suppressed by controlling the spacing between the donor (D) and the acceptor (A) materials (DA spacing). We show that in typical organic solar cells, the DA spacing is generally too small, being the origin of the too-fast non-radiative decay of charge carriers ($${k}_{{nr}}$$ k n r ), and it can be increased by engineering the non-conjugated groups, i.e., alkyl chain spacers in single component DA systems and side chains in high-efficiency bulk-heterojunction systems. Increasing DA spacing allows us to realize significantly reduced $${k}_{{nr}}$$ k n r and improved device voltage. This points out a new research direction for breaking the performance bottleneck of organic solar cells.


2014 ◽  
Vol 15 (10) ◽  
pp. 2270-2276 ◽  
Author(s):  
Pei Cheng ◽  
Xingang Zhao ◽  
Weiyi Zhou ◽  
Jianhui Hou ◽  
Yongfang Li ◽  
...  

2019 ◽  
Vol 7 (4) ◽  
pp. 835-842 ◽  
Author(s):  
Helin Wang ◽  
Lingcheng Chen ◽  
Yi Xiao

Th-4PDI, a new donor–acceptor-type non-fullerene electron acceptor material, was designed and synthesized for high efficiency organic solar cells.


ChemSusChem ◽  
2016 ◽  
Vol 9 (12) ◽  
pp. 1433-1441 ◽  
Author(s):  
Hao-Chun Ting ◽  
Ya-Ting Yang ◽  
Chia-Hsun Chen ◽  
Jiun-Haw Lee ◽  
Jung-Hung Chang ◽  
...  

2020 ◽  
Vol 4 (12) ◽  
pp. 3594-3601
Author(s):  
Xin Ke ◽  
Lingxian Meng ◽  
Xiangjian Wan ◽  
Yanna Sun ◽  
Ziqi Guo ◽  
...  

A new acceptor–donor–acceptor (A–D–A) small molecule acceptor, named FCO-2F, is designed and synthesized based on the previous acceptor F-H.


Solar RRL ◽  
2020 ◽  
Vol 4 (10) ◽  
pp. 2000241
Author(s):  
Geedhika K. Poduval ◽  
Leiping Duan ◽  
Md. Anower Hossain ◽  
Borong Sang ◽  
Yu Zhang ◽  
...  

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