Single‐Atom Catalysts Derived from Metal–Organic Frameworks for Electrochemical Applications

Small ◽  
2021 ◽  
pp. 2004809
Author(s):  
Lianli Zou ◽  
Yong‐Sheng Wei ◽  
Chun‐Chao Hou ◽  
Caixia Li ◽  
Qiang Xu
Keyword(s):  
Metal Organic Frameworks ◽  
Single Atom ◽  
Electrochemical Applications ◽  
Metal Organic

scholarly journals Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yamei Sun ◽  
Ziqian Xue ◽  
Qinglin Liu ◽  
Yaling Jia ◽  
Yinle Li ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Metal Organic Frameworks ◽  
Catalyst Design ◽  
Single Atom ◽  
Hydrogen Energy ◽  
Structure Of Metal ◽  
Metal Organic

AbstractDeveloping high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction electrocatalyst (NiRu0.13-BDC) by introducing atomically dispersed Ru. Significantly, the obtained NiRu0.13-BDC exhibits outstanding hydrogen evolution activity in all pH, especially with a low overpotential of 36 mV at a current density of 10 mA cm−2 in 1 M phosphate buffered saline solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H2O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design.

Metal-organic frameworks for direct electrochemical applications

2018 ◽  
Vol 376 ◽  
pp. 292-318 ◽  
Author(s):  
Yuxia Xu ◽  
Qing Li ◽  
Huaiguo Xue ◽  
Huan Pang
Keyword(s):  
Metal Organic Frameworks ◽  
Electrochemical Applications ◽  
Metal Organic

Two-dimensional metal-organic frameworks Mo3(C2O)12 as promising single-atom catalysts for selective nitrogen-to-ammonia

2022 ◽  
Author(s):  
Zhen Feng ◽  
Zelin Yang ◽  
Xiaowen Meng ◽  
Fachuang Li ◽  
Zhanyong Guo ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Metal Organic Frameworks ◽  
Density Functional Theory Calculations ◽  
Reduction Reaction ◽  
Single Atom ◽  
Two Dimensional ◽  
Functional Theory ◽  
New Family ◽  
Metal Organic

The development of single-atom catalysts (SACs) for electrocatalytic nitrogen reduction reaction (NRR) remains a great challenge. Using density functional theory calculations, we design a new family of two-dimensional metal-organic frameworks...

scholarly journals Single‐Atom Electrocatalysts from Multivariate Metal–Organic Frameworks for Highly Selective Reduction of CO 2 at Low Pressures

2020 ◽  
Vol 59 (46) ◽  
pp. 20589-20595 ◽  
Author(s):  
Long Jiao ◽  
Weijie Yang ◽  
Gang Wan ◽  
Rui Zhang ◽  
Xusheng Zheng ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Selective Reduction ◽  
Single Atom ◽  
Metal Organic ◽  
Low Pressures

Synthesis of micro/nanoscaled metal–organic frameworks and their direct electrochemical applications

2020 ◽  
Vol 49 (1) ◽  
pp. 301-331 ◽  
Author(s):  
Xiao Xiao ◽  
Lianli Zou ◽  
Huan Pang ◽  
Qiang Xu
Keyword(s):  
Metal Organic Frameworks ◽  
Electrochemical Applications ◽  
Metal Organic ◽  
Developing Strategies

Developing strategies to control the morphology and size of MOFs is important for their applications in batteries, supercapacitors and electrocatalysis. This review focuses on the design and fabrication of MOFs at the micro/nanoscale.

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